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Effects of Green - Emitting Phosphor (La,Ce,Tb)PO4:Ce:Tb on Luminous Flux and Color Quality of White LED Lamps

Abstract

In this paper, we present and analyze the influence of (La,Ce,Tb)PO4:Ce:Tb green phosphor (LaTb) toward the performance of the multi-chip white LED (MCW-LEDs) lamps including color uniformity, lumen output, Color Rendering Index (CRI), and Color Quality Scale (CQS). By mixing the LaTb green phosphor and the YAG:Ce yellow phosphor compounding under condition of 7000 K MCW-LEDs, this new approach can produce a huge meaningful change in lumen output and the angular color distribution of MCWLEDs. We also study the interaction between the concentration and size of the LaTb particles with output flux, color uniformity, CRI, and CQS. The obtained results demonstrate that the higher lumen output, the higher color uniformity enhancement could be attained by adding the LaTb particles with a size range around 6-8 m and the concentration around 1.5 % in phosphor layer. Meanwhile, the decrease of the color rendering value (CRI) and the Color Quality Scale (CQS) tend to be stable and insignificant. In other words, the obtained results provide a prospective method which plays an important role in the development of MCWLED manufacturing technology.

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Effects of Green - Emitting Phosphor (La,Ce,Tb)PO4:Ce:Tb on Luminous Flux and Color Quality of White LED Lamps

Author: Thao, Nguyen Thi Phuong
Publisher: Vysoká škola báňská - Technická univerzita Ostrava
Year: 2017
DOI: 10.15598/aeee.v15i5.2111
Source: https://dspace.vsb.cz/bitstreams/bbf8d6b5-0f6d-401d-8e5c-ef692f8dcf08/download
APPLIED PHYSICS VOLUME: 15 |NUMBER: 5 |2017 |DECEMBER
E ec s o G een - Emi ing Phospho
(La,Ce,Tb)PO4:Ce:Tb on Luminous Flux and Colo
Quali y o Whi e LED Lamps
Nguyen Thi Phuong THAO1,4, Phan Xuan LE2, Le Van THO3,
Mi osla VOZNAK4, Nguyen Doan Quoc ANH5
1Facul y o Elec ical and Elec onics Enginee ing, Ton Duc Thang Uni e si y,
19 Nguyen Huu Tho S ee , 7 h Dis ic , Ho Chi Minh Ci y, Vie nam
2Facul y o Elec ical and Elec onics Enginee ing, HCMC Uni e si y o Food Indus y,
140 Le T ong Tan s ee , Tay Thanh Wa d, Tan Phu Dis ic , Ho Chi Minh ci y, Vie nam
3Ins i u e o T opical Biology, Vie nam Academy o Science and Technology,
85 T an Quoc Toan s ee , 3 h Dis ic , Ho Chi Minh Ci y, Vie nam
4Depa men o Telecommunica ions, Facul y o Elec ical Enginee ing and Compu e Science,
VSB–Technical Uni e si y o Os a a, 17. lis opadu 15/2172, 708 33 Os a a, Czech Republic
5Powe Sys em Op imiza ion Resea ch G oup, Facul y o Elec ical and Elec onics Enginee ing,
Ton Duc Thang Uni e si y, 19 Nguyen Huu Tho S ee , 7 h Dis ic , Ho Chi Minh Ci y, Vie nam
nguyen hiph[email p o ec ed], [email p o ec ed], [email p o ec ed],
mi osla . [email p o ec ed], nguyendoanquo[email p o ec ed]
DOI: 10.15598/aeee. 15i5.2111
Abs ac . In his pape , we p esen and analyze
he in luence o (La,Ce,Tb)PO4:Ce:Tb g een phospho
(LaTb) owa d he pe o mance o he mul i-chip whi e
LED (MCW-LEDs) lamps including colo uni o mi y,
lumen ou pu , Colo Rende ing Index (CRI), and Colo
Quali y Scale (CQS). By mixing he LaTb g een phos-
pho and he YAG:Ce yellow phospho compounding
unde condi ion o 7000 K MCW-LEDs, his new ap-
p oach can p oduce a huge meaning ul change in lu-
men ou pu and he angula colo dis ibu ion o MCW-
LEDs. We also s udy he in e ac ion be ween he con-
cen a ion and size o he LaTb pa icles wi h ou pu
lux, colo uni o mi y, CRI, and CQS. The ob ained
esul s demons a e ha he highe lumen ou pu , he
highe colo uni o mi y enhancemen could be a ained
by adding he LaTb pa icles wi h a size ange a ound
6-8 µm and he concen a ion a ound 1.5 % in phos-
pho laye . Meanwhile, he dec ease o he colo en-
de ing alue (CRI) and he Colo Quali y Scale (CQS)
end o be s able and insigni ican . In o he wo ds,
he ob ained esul s p o ide a p ospec i e me hod which
plays an impo an ole in he de elopmen o MCW-
LED manu ac u ing echnology.
Keywo ds
(La,Ce,Tb)PO4:Ce:Tb phospho , Colo Qual-
i y Scale, Colo Rende ing Index, colo uni-
o mi y, luminous lux, mul i-chip whi e LED
lamp.
1. In oduc ion
Recen ly, MCW-LED is becoming one o he mos
widely used ligh ing sou ces in illumina ion ap-
plica ions since i s cha ac e is ics such as high ligh
in ensi y, ene gy-e icien , low powe consump ion, as
esponse, and expended du abili y ou pe o m con en-
ional ligh ing sou ces (Michael Can o e e al. 2015
and Yu e al. 2016). Ne e heless, he e a e challenges
in imp o ing hose pe o mance indica o s. Tha leads
o u he esea ch and de elopmen . Two impo an
p ope ies o whi e LEDs ha a ac g ea a en ion
o esea che s a e lumen ou pu and colo uni o mi y
which ha e been s udied and published in p e ious
c
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APPLIED PHYSICS VOLUME: 15 |NUMBER: 5 |2017 |DECEMBER
pape s o Ying e al. (2016) and Chiang e al (2015).
To imp o e hese wo ea u es, hese pape s we e
mainly ocused on sca e ing enhancemen o he in-
ciden and he con e ed ligh o phospho pa icles in
MCW LED.
Whi e ligh , which is p oduced by whi e LED, is he
esul o mixing in he inciden blue ligh om he chips
and con e ed yellow ligh . YAG:Ce yellow phospho
pa icles a e he p e e ed ma e ial o whi e LEDs.
This phospho is used o abso b exci ing blue ligh om
he chips and o emi he yellow ligh (Liu e al. 2008,
Liu e al. 2011). Howe e , i is pe cei ed ha he blue
ligh in ensi y is no in balance wi h he yellow ligh
in ensi y due o he backsca e ing p oblems. Conse-
quen ly, he MCW-LEDs do no o e uni o m colo
dis ibu ion and hus a e no sui able o some appli-
ca ions (H-C Chen e al. 2013 and K-J Chen e al.
2012).
One o he al e na i e me hods o enhance he
colo uni o mi y and luminous lux o whi e LEDs is
o add g een Ce0.67Tb0.33 MgAl11 O19:Ce,Tb phos-
pho in o phospho compounding wi h he sui able
phospho concen a ion as p oposed by Anh e al.
(2016). In addi ion, Hakeem and Pa k (2015) in-
oduced Na(S 072Ca0.25)PO4:0.03Eu2+ phospho ha
showed s onge emission spec a in ensi y in whi e
LEDs and could be employed as a blue emi ing phos-
pho o LEDs. O he s udies ound ha he use
o app op ia e concen a ion and hickness as well as
sui able loca ion o phospho laye can help achie e
be e LED pe o mance (Shuai e al. 2011). Mo e-
o e , he e ec o LED lens on op ical quali ies ha e
also been s udied ecen ly. Fo example, Enguo Chen
(2014) demons a ed ha a s uc u e wi h a ee o m
mic olens a ay could imp o e he luminous lux o
whi e LEDs. The lens wi h he d ople e apo a ion
exhibi s a s onge ligh in ensi y (Xing Guo e al.
2016). Al hough he e we e di e en app oaches o in-
ensi y he e iciency o whi e LEDs, he angula colo
uni o mi y and he lumen ou pu o whi e LEDs a e
s ill no high enough and insu icien o sa is y equi e-
men s and inc easing demand o applica ions in he
comme cial LED ligh ing ma ke . The e o e, ad anced
esea ch should be conduc ed o achie e he desi ed
colo uni o mi y and highe lumen ou pu .
In his s udy, we p opose he inco po a ion o he
new g een LaTb pa icles in he phospho laye o he
MCW-LEDs o enhance he lumen ou pu and he co -
ela ed colo empe a u e uni o mi y. Th ough he ex-
amina ion o he e ec o g een (La,Ce,Tb)PO4:Ce:Tb
phospho on he whi e LED illumina ion in In-cup
Phospho Packages (IPP), we ound ha LaTb pa i-
cles can p o ide be e ligh dis ibu ion in he MCW-
LED package. The simula ion o his package is ca ied
ou on a ious weigh pe cen ages and di e en sizes
o LaTb phospho pa icles. The sca e ing p ope ies
o phospho laye a e in es iga ed by conside ing bo h
ligh abso p ion and ligh con e sion in LEDs when
LaTb pa icles a e injec ed in o phospho laye . In
o he wo ds, his wo k in es iga es how bo h concen-
a ion and size o LaTb g een phospho pa icles will
impac on luminous lux, angula colo dis ibu ion,
CRI, and CQS.
2. Simula ion and
Compu a ion
The main pu pose o his esea ch is o e eal he e ec
o g een LaTb phospho on he angula CCT uni o -
mi y and he lumen ou pu e iciency o he MCW-
LEDs, so we used a 7000 K MCW-LED wi h in-cup
phospho s uc u e o simula e. The MCW-LED mod-
els used in he simula ion p ocesses we e he comme -
cial MPBGA (Mul i-Package Ball G id A ay) p o-
ided by he Siliconwa e P ecision Indus ies Co. L d.,
Taiwan.
The model s uc u e, as shown in Fig. 1, was buil up
acco ding o he MCW-LED samples which consis s o
a blue chip, a e lec o cup, a phospho laye , and a sil-
icone laye . Each blue chip was designed wi h 1.16 W
adian powe , a peak wa eleng h o 453 nm, and a di-
mension o 1.14 mm ×0.15 mm. These chips we e
secu ely a ached o he e lec o which has a 2.07 mm
PHYSICS AND OPTICS VOLUME: XX | NUMBER: X | 2015 | MONTH
© 2015 ADVANCES IN ELECTRICAL AND ELECTRONIC ENGINEERING 2
op ical quali ies ha e also been s udied ecen ly. Fo
example, Enguo Chen (2014) demons a ed ha a
s uc u e wi h a ee o m mic olens a ay could imp o e
he luminous lux o whi e LEDs. The lens wi h he
d ople e apo a ion exhibi s a s onge ligh in ensi y
(Xing Guo e al. 2016). Al hough he e we e di e en
app oaches o in ensi y he e iciency o whi e LEDs, he
angula colo uni o mi y and he lumen ou pu o whi e
LEDs a e s ill no high enough and insu icien o sa is y
equi emen s and inc easing demand o applica ions in
he comme cial LED ligh ing ma ke . The e o e,
ad anced esea ch should be conduc ed o achie e he
desi ed colo uni o mi y and highe lumen ou pu .
In his s udy, we p opose he inco po a ion o he new
g een LaTb pa icles in he phospho laye o he MCW-
LEDs o enhance he lumen ou pu and he co ela ed
colo empe a u e uni o mi y. Th ough he examina ion o
he e ec o g een (La,Ce,Tb)PO4:Ce:Tb phospho on he
whi e LED illumina ion in in-cup phospho packages
(IPP), we ound ha LaTb pa icles can p o ide be e
ligh dis ibu ion in he MCW-LED package. The
simula ion o his package is ca ied ou on a ious
weigh pe cen ages and di e en sizes o LaTb phospho
pa icles. The sca e ing p ope ies o phospho laye a e
in es iga ed by conside ing bo h ligh abso p ion and
ligh con e sion in LEDs when LaTb pa icles a e
injec ed in o phospho laye . In o he wo ds, his wo k
in es iga es how bo h concen a ion and size o LaTb
g een phospho pa icles will impac on luminous lux,
angula colo dis ibu ion, CRI, and CQS.
2. Simula ion and Compu a ion
The main pu pose o his esea ch is o e eal he
e ec o g een LaTb phospho on he angula CCT
uni o mi y and he lumen ou pu e iciency o he MCW-
LEDs, so we used a 7000K MCW-LED wi h in-cup
phospho s uc u e o simula e. The MCW-LED models
used in he simula ion p ocesses we e he comme cial
MPBGA (Mul i-Package Ball G id A ay) p o ided by
he Siliconwa e P ecision Indus ies Co. L d., Taiwan.
The model s uc u e, as shown in Fig.1, was buil up
acco ding o he MCW-LED samples which consis s o a
blue chip, a e lec o cup, a phospho laye , and a silicone
laye . Each blue chip was designed wi h 1.16W adian
powe , a peak wa eleng h o 453nm, and a dimension o
1.14mm x 0.15mm. These chips we e secu ely a ached o
he e lec o which has a 2.07 mm dep h, 8 mm bo om
leng h, and 9.85mm su ace leng h. The chips we e
co e ed by a 0.08 mm hick phospho laye , as shown in
Fig. 1. In o de o be e unde s and he e ec o using
his g een phospho , he op ical simula ion p ocess is
conduc ed wi h a ia ion o LaTb pa icle concen a ion
and size. I is wo h no ing ha i he concen a ion o
g een LaTb phospho a ies, he YAG: Ce phospho
concen a ion needs o be sui ably adjus ed o main ain
he colo empe a u e o whi e LEDs a 7000K.
Fig. 1: Illus a ion o MCW-LEDs s uc u e: (a) he sample LED used
in his s udy (b) wi h in-cup phospho con igu a ion
Ligh Tools 8.1.0 op ical so wa e was used in his
simula ion p ocess o model he LED s uc u e and
analyze i s op ical pe o mance. The LaTb phospho
wi h he wa eleng h a 546 nm was added o he MCW-
LED wi h he se e al al e a ions in concen a ion and size
o op imize he op ical p ope ies o LEDs. The e o e,
hese MCW-LEDs con ain he g een phospho LaTb, he
yellow phospho YAG:Ce, and he silicone glues in hei
phospho laye . In his s uc u e, g een LaTb phospho
pa icle sizes we e anging om 1 µm o 10 µm, while
he adius o he YAG: Ce yellow phospho pa icle is se
o 7.25 µm.
The sca e ing o he LaTb phospho pa icles is
calcula ed and e i ied by ollowing he Mie- heo y (Lai
e al. 2016). The ela ionship among he angula
sca e ing ampli udes and he weigh as well as he size o
he LaTb pa icles is desc ibed by he ollowing
equa ions:
 
1
1
2 1
( , ) (cos ) ( , ) (cos )
( 1) n n n n
n
n
S a x m b x m
n n
   



 


 
2
1
2 1
( , ) (cos ) ( , ) (cos )
( 1) n n n n
n
n
S a x m b x m
n n
   



 


whe e S1, S2 a e he sca e ing in ensi y unc ions, x is he
pa icle size pa ame e , m is he phospho pa icle
e ac i e index. Thei alues a e de e mined by he
angula unc ions
(cos )
n
 
and
(cos )
n
 
, he pa ame e s
m, x, and he expansion coe icien s an, bn. The e ac i e
index o phospho pa icle is se o be 1.85 and 1.83 o
LaTb and YAG: Ce. The sca e ing in ensi y S1, S2 o
MCW-LEDs a e simula ed and compu ed a he peak o
555 nm o yellow YAG: Ce phospho and he wa eleng h
o 453nm o blue chips. Figu e 2 depic s he angula
sca e ing in ensi y o LaTb and YAG: Ce pa icles on he
Ca esian coo dina e sys em. The Ma lab simula ion
esul s in Fig. 2 exp ess ha he angula sca e ing
in ensi y o LaTb di use pa icle is simila o he yellow
(1)
(2)
(a) (b)
(a) he sample LED used in his
s udy
YAG:Ce LaTb
Silicone lens
(b) wi h in-cup phospho con igu a ion
Fig. 1: Illus a ion o MCW-LEDs s uc u e.
c
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APPLIED PHYSICS VOLUME: 15 |NUMBER: 5 |2017 |DECEMBER
dep h, 8 mm bo om leng h, and 9.85 mm su ace
leng h. The chips we e co e ed by a 0.08 mm hick
phospho laye , as shown in Fig. 1. In o de o be e
unde s and he e ec o using his g een phospho , he
op ical simula ion p ocess is conduc ed wi h a ia ion
o LaTb pa icle concen a ion and size. I is wo h
no ing ha i he concen a ion o g een LaTb phos-
pho a ies, he YAG:Ce phospho concen a ion needs
o be sui ably adjus ed o main ain he colo empe -
a u e o whi e LEDs a 7000 K.
Ligh Tools 8.1.0 op ical so wa e was used in his
simula ion p ocess o model he LED s uc u e and
analyze i s op ical pe o mance. The LaTb phospho
wi h he wa eleng h a 546 nm was added o he MCW-
LED wi h he se e al al e a ions in concen a ion and
size o op imize he op ical p ope ies o LEDs. The e-
o e, hese MCW-LEDs con ain he g een phospho
LaTb, he yellow phospho YAG:Ce, and he silicone
glues in hei phospho laye . In his s uc u e, g een
LaTb phospho pa icle sizes we e anging om 1 µm
o 10 µm, while he adius o he YAG:Ce yellow phos-
pho pa icle is se o 7.25 µm.
The sca e ing o he LaTb phospho pa icles is cal-
cula ed and e i ied by ollowing he Mie- heo y (Lai e
al. 2016). The ela ionship among he angula sca e -
ing ampli udes and he weigh as well as he size o he
LaTb pa icles is desc ibed by he ollowing equa ions:
S1=
∞
X
n=1
2n+ 1
n(n+ 1) [an(x, m)πn(cos θ)
+bn(x, m)τn(cos θ)] ,
(1)
S2=
∞
X
n=1
2n+ 1
n(n+ 1) [an(x, m)τn(cos θ)
+bn(x, m)πn(cos θ)] ,
(2)
Angle (deg ee)
0 50 100 150
Rela i e In ensi y (a.u.)
#10-3
0
1
2
3
4
5
6
7LaTb
YAG:Ce
Fig. 2: The angula sca e ing diag am o LaTb and YAG:Ce
pa icles in he phospho laye o MCW-LEDs o
546 nm and 555 nm.
whe e S1,S2a e he sca e ing in ensi y unc ions, xis
he pa icle size pa ame e , mis he phospho pa icle
e ac i e index. Thei alues a e de e mined by he
angula unc ions πn(cos θ)and τn(cos θ), he pa ame-
e s m,x, and he expansion coe icien s an,bn. The
e ac i e index o phospho pa icle is se o be 1.85
and 1.83 o LaTb and YAG:Ce. The sca e ing in en-
si y S1,S2o MCW-LEDs a e simula ed and compu ed
a he peak o 555 nm o yellow YAG:Ce phospho and
he wa eleng h o 453 nm o blue chips.
Figu e 2 depic s he angula sca e ing in ensi y o
LaTb and YAG:Ce pa icles on he Ca esian coo di-
na e sys em. The Ma lab simula ion esul s in Fig. 2
exp ess ha he angula sca e ing in ensi y o LaTb
di use pa icle is simila o he yellow YAG:Ce phos-
pho pa icle. Hence, he combina ion o he LaTb
pa icles and he YAG:Ce phospho laye will p o-
duce a sca e ing enhancemen o he inciden ligh in
MCW-LED.
3. Resul s and Discussion
To de e mine he colo uni o mi y quali y o LEDs,
we use he Co ela ed Colo Tempe a u e de ia ion
(4CCT) which is he di e ence be ween he maximum
CCT alue and he minimum CCT alue. This pa am-
e e was also cha ac e izes he angula CCT uni o mi y
o LEDs. Thus, lowe 4CCT alue co esponds o he
be e ligh quali y o LEDs (K-C Huang e al. 2013).
Figu e 3 shows he ela ionship among 4CCT, he
concen a ion, and size o LaTb pa icles. When he
LaTb pa icle concen a ion inc eases, he CCT de ia-
ion ema kably dec eases all LaTb pa icles wi h di -
e en sizes. I he concen a ion o LaTb phospho
inc eases om 0 o 1.4 % o small LaTb pa icles and
om 0 up o 1.8 % o bigge sizes, LED shows an ex-
Concen a ion (%)
0 0.5 1 1.5
"CCT (K)
0
1000
2000
3000
4000
5000
1 2 3 4 5 6 7 8 9 10
Fig. 3: The CCT de ia ion (4CCT) o MCW-LEDs is a a e -
age CCT 7000 K wi h di e en LaTb pa icle sizes and
concen a ions.
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cellen colo uni o mi y in i s op ical p ope y. In some
cases, 4CCT signi ican ly educes om 4000 K o less
han 500 K. The lowes CCT de ia ion alue can be
achie ed o less han 450 K a he LaTb pa icle con-
cen a ion o 0.4 % and pa icle size o 1 µm. Hence,
LaTb phospho could p o ide g ea sca e ing capabil-
i y o LEDs and i makes he spa ial colo dis ibu ion
much la e han hose wi hou LaTb. In o he wo ds,
he sca e ed ligh is able o mo e in many di e en di-
ec ions as he concen a ion o LaTb pa icles pumped
in o yellow YAG:Ce phospho inc eases.
Besides inspec ing he in luence o LaTb concen a-
ion, his s udy also ocuses on in es iga ing he impac
o LaTb pa icle adius on he colo uni o mi y o he
in-cup package MCW-LEDs. The LaTb pa icle a-
dius anging om 1 o 10 µm is su eyed and analyzed
o di e en concen a ion o LaTb pa icles. Wi h he
small pa icle sizes om 1 µm o 4 µm, he CCT de i-
a ion o whi e LEDs, which is shown in Fig. 3, apidly
dec eases a a ound 500 K as he LaTb pa icle con-
cen a ion inc eases. Conside ing hese ac s, i can
be deduced ha he small pa icles could sca e mo e
ligh wi hin he wide iewing angle. As o he g ea e
size ange 5–10 µm, he endency o cu es exp essed
by he colo uni o mi y is simila o he small pa icle
case.
This is associa ed wi h he ac ha he inciden
ligh ends o be sca e ed, and hence, he decay le el
o CCT de ia ion o hese la ge pa icles is slowe
han hose o small pa icles. Gene ally, a e adding
he new phospho LaTb in o YAG:Ce phospho , he
colo uni o mi y can inc ease signi ican ly. In pa icu-
la , LaTb pa icles can imp o e he colo uni o mi y o
LEDs o all pa icle sizes wi h ange wi hin 1–10 µm,
e en i he la ge pa icles a e employed as seen in Fig. 3.
Concen a ion (%)
0 0.5 1 1.5
Luminous Flux (lm)
600
800
1000
1200
1400
1600
1800
1 2 3 4 5 6 7 8 9 10
Fig. 4: The luminous lux o MCW-LEDs is a a e age CCT
7000 K wi h di e en LaTb pa icle sizes and concen-
a ions.
Fu he mo e, he simula ion esul s shown in Fig. 4
also demons a e ha LaTb pa icle size and weigh
pe cen age ha e a s ong impac on he lumen ou -
pu . The highe weigh pe cen age o he g een LaTb
phospho , he be e quali y o he g een ligh s, and
he highe luminous lux o whi e LED. To s udy o
he in luence o he LaTb weigh pe cen age on lumen
ou pu , we con inuously a ied he LaTb concen a ion
om 0 o 1.8 % o each ixed size in he simula ion p o-
cess. As shown in Fig. 4, as o 1–4 µm LaTb pa icles,
luminous lux signi ican ly ises wi h LaTb weigh pe -
cen om 0 % o 1.5 %. Ob iously, when he LaTb
pa icle size is small, he lumen ou pu will dec ease
because he unwan ed backwa d sca e ing has been
demons a ed in many p e ious pape s. I means ha
he e is mo e ligh apped inside a package and he
lumen ou pu escaping om ha . Howe e , mixing
he new LaTb phospho in o phospho laye , lumen
ou pu could o e come he es ic ion wi h he small
size o phospho pa icles and is apidly imp o ed o
achie e he bes luminous lux. Wi h his no el ea-
u e, he u iliza ion o LaTb phospho becomes one o
he mos p omising me hods o imp o ing he op i-
cal p ope ies o LEDs. Wi h pa icle sizes la ge han
5µm, he ligh ends o p opaga e s onge in he o -
wa d di ec ion and es ic s backwa d ligh abso p ion
o LED chips, he eby he luminous lux a la ge size
pa icles will be highe . Hence, a mix u e o LaTb
pa icles wi h di e en sizes and YAG:Ce phospho s
emendously imp o es he lumen ou pu o he in-cup
phospho package MCW-LEDs.
Acco dingly, LaTb g een phospho can be used o
yield highe lumen ou pu due o a supplemen o g een
ligh in MCW-LEDs. Howe e , he CRI alues can de-
c ease as inc easing LaTb concen a ion. I can be ob-
se ed ha wi h he inc easing luminous lux, he CRI
alue insigni ican ly dec eases in size anging om 6 o
8µm as shown in Fig. 5. The eason is ha in o de o
Concen a ion (%)
0 0.5 1 1.5
Colo Rende ing Index
45
50
55
60
65
70
1 2 3 4 5 6 7 8 9 10
Fig. 5: The Colo Rende ing Index (CRI) alue o MCW-LEDs
is a a e age CCT 7000 K wi h di e en LaTb pa icle
sizes and concen a ions.
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achie e be e CRI alues, LEDs mus ha e a b oade
sou ce spec um o espond, and hus, he e iciency o
whi e LED would be educed. In addi ion, one o he
mos impo an ac o s used o e alua e he colo qual-
i y o whi e LEDs is he CQS ac o , which is also in-
es iga ed in his s udy. This ac o is cha ac e ized by
he colo ideli y le el o MCW-LEDs and i is assessed
by some e ms o colo quali y including CRI, ch o-
ma ic disc imina ion, and obse e p e e ences (Da is
and Ohno 2010). In he simula ion esul s (see Fig. 6),
he e is a sligh lessening in CQS alues wi h concen-
a ion a ound 1.5 % and he pa icle 6–8 µm.
We ound ha he 1–4 µm LaTb pa icles show
g ea e pe o mance capabili y o lumen ou pu and
colo uni o mi y a e adop ing LaTb pa icles in o
phospho laye . Howe e , we conclude ha he mos
app op ia e a e phospho pa icles ha ing a size ange
om 6 o 8 µm and he concen a ion a ound 1.5 %.
The eason is ha colo uni o mi y and op imal lumen
ou pu can be achie ed o he low CRI, CQS alues in
he same size and concen a ion ange.
Concen a ion (%)
0 0.5 1 1.5
Colo Quali y Scale
50
55
60
65
70
1 2 3 4 5 6 7 8 9 10
Fig. 6: The Colo Quali y Scale (CQS) alue o MCW-LEDs
is a a e age CCT 7000 K wi h di e en LaTb pa icle
sizes and concen a ions.
4. Conclusion
In his a icle, a esea ch was conduc ed o ind ou he
impac o g een (La,Ce,Tb)PO4:Ce:Tb phospho pa -
icles wi h he a ious concen a ions and sizes on he
MCW-LED pe o mance including he 4CCT, lumi-
nous lux, CRI, and CQS. The ob ained esul s indi-
ca e ha he g een LaTb phospho can imp o e bo h
he colo uni o mi y and he lumen ou pu . The op-
imum LaTb concen a ion and size a e de e mined
o ob ain he lowes alue o he CCT de ia ion as
well as he highes luminous lux accompanying wi h
a negligible dec ease in CRI, CQS alues. In ac , he
ob ained CRI and CQS alues can insigni ican ly de-
c ease when applying a ound 1.5 % LaTb concen a-
ion and 6-8 µm pa icles. I could be concluded ha
by pumping a small amoun o LaTb phospho has he
concen a ion anging om 0–1.8 % and he pa icle
sizes om 6–8 µm, we can ob ain be e pe o mance
o whi e LEDs. The e o e, LaTb pa icles should be
a p io i ized solu ion o be chosen o imp o ing he
op ical p ope ies o MCW-LEDs.
Acknowledgmen
This esea ch is unded by Founda ion o Science and
Technology De elopmen o Ton Duc Thang Uni e -
si y (FOSTECT), websi e: h p:// os ec . d .
edu. n, unde G an FOSTECT.2017.BR.06.
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Abou Au ho s
Nguyen Thi Phuong THAO was bo n in Quang
Ngai p o ince, Vie nam. She g adua ed om he
Uni e si y o Technology, Ho Chi Minh ci y, Vie
Nam. She ecei ed he B.Eng. and M.Eng. deg ees
in au oma ic con ol Enginee ing in 2006 and 2009,
espec i ely. She eaches a he depa men o elec-
ical and elec onics enginee ing, Ton Duc Thang
uni e si y, Ho Chi Minh ci y, Vie nam. He esea ch
in e es s include au oma ic con ol sys em, in elligen
con ol sys em, adap i e con ol sys em, op imiza ion
o powe sys em, powe sys em ope a ion and con ol
and Renewable Ene gy.
Phan Xuan LE was bo n in Binh Dinh p o ince,
Vie nam. He has been wo king a he Facul y o
Elec ical and Elec onics Enginee ing, HCMC Uni-
e si y o Food Indus y. He ecei ed his Ph.D. deg ee
om Kunming Uni e si y o Science and Technology,
China in 2015. His esea ch in e es is powe sys em;
op oelec onics.
Le Van THO was bo n in Thanh Hoa p o ince,
Vie nam. He has been wo king a he Ins i u e o
T opical Biology, Vie nam Academy o Science and
Technology. He ecei ed his mas e deg ee om Ho
Chi Minh Ci y Uni e si y o Science, Vie nam in
2017. His esea ch in e es is ecological enginee ing,
op oelec onics.
Mi osla VOZNAK (bo n in 1971) is an Associa e
P o esso wi h he Depa men o Telecommunica-
ions, Technical Uni e si y o Os a a, Czech Republic
and o eign p o esso wi h Ton Duc Thang Uni e si y
in Ho Chi Minh Ci y, Vie nam. He ecei ed his Ph.D.
deg ee in elecommunica ions in 2002 a he Technical
Uni e si y o Os a a. He is a senio esea che in he
c
2017 ADVANCES IN ELECTRICAL AND ELECTRONIC ENGINEERING 895
APPLIED PHYSICS VOLUME: 15 |NUMBER: 5 |2017 |DECEMBER
Supe compu ing cen e IT4Inno a ions in Os a a,
Czech Republic, a membe o he Scien i ic Boa d o
Facul y o Elec ical Enginee ing and Compu e Sci-
ence, VSB–Technical Uni e si y o Os a a, edi o ial
boa ds o se e al jou nals and boa ds o in e na ional
con e ences. Topics o his esea ch in e es s a e IP
elephony, wi eless ne wo ks, speech quali y and
ne wo k secu i y.
Nguyen Doan Quoc ANH was bo n in Khanh
Hoa p o ince, Vie nam. He has been wo king a he
Facul y o Elec ical and Elec onics Enginee ing, Ton
Duc Thang Uni e si y. Quoc Anh ecei ed his PhD
deg ee om Na ional Kaohsiung Uni e si y o Applied
Sciences, Taiwan in 2014. His esea ch in e es is
op oelec onics (such as Mul i-chip whi e ligh LEDs,
ee- o m lens, op ical ma e ial).
c
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