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Susceptibility of halobacteria to heavy metals

Abstract

Sixty-eight halobacteria, including both culture coUection strains and fresh isolates from widely dift'ering geographical areas, were tested for susceptibility to arsenate, cadmium, chromium, cobalt, copper, lead, mercury, nickel, silver, and zinc ions by an agar dilution technique. The culture collection strains showed dift'erent susceptibilities, clustering into five groups. Halobacterium medilerranei and Halobacterium volcanii were the most metal tolerant, whereas Haloarcula californiae and Haloarcula sinaiiensis had the highest susceptibilities of the culture collection strains. Dift'erent patterns of metal susceptibility were found for all the halobacteria tested, and there was a uniform susceptibility to mercury and silver. All strains tested were multiply metal tolerant.

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Susceptibility of halobacteria to heavy metals

Author: Nieto Gutiérrez, Joaquín José; Ventosa Ucero, Antonio; Ruiz Berraquero, Francisco
Publisher: American Society for Microbiology
Year: 1987
Source: https://idus.us.es/bitstreams/cf202553-4275-4e98-84f9-80c809401f2e/download
APPLIED
AND
ENVIRONMENTAL
MICROBIOLOGY,
May
1987,
p.
1199-1202
0099-2240/87/051199-04$02.00/0
Copy igh
©
1987,
Ame ican
Socie y
o
Mic obiology
Vol.
53,
No.
5
Suscep ibili y
o
Halobac e ia
o
Hea y
Me als
J.
J.
NIETO,*
A.
VENTOSA,
AND
F.
RUIZ-BERRAQUERO
Depa men
o
Mic obiology,
Facul y
o
Pha macy,
Uni e si y
o
Se ille,
Se ille,
Spain
Recei ed
8
Decembe
1986/Accep ed
18
Feb ua y
1987
Six y-eigh
halobac e ia,
including
bo h
cul u e
collec ion
s ains
and
esh
isola es
om
widely
di e ing
geog aphical
a eas,
we e
es ed
o
suscep ibili y
o
a sena e,
cadmium,
ch omium,
cobal ,
coppe ,
lead,
me cu y,
nickel,
sil e ,
and
zinc
ions
by
an
aga
dilu ion
echnique.
The
cul u e
collec ion
s ains
showed
di e en
suscep ibili ies,
clus e ing
in o
i e
g oups.
Halobac e ium
medi e anei
and
Halobac e ium
olcanii
we e
he
mos
me al
ole an ,
whe eas
Haloa cula
cali o niae
and
Haloa cula
sinaiiensis
had
he
highes
suscep ibili ies
o
he
cul u e
collec ion
s ains.
Di e en
pa e ns
o
me al
suscep ibili y
we e
ound
o
all
he
halobac e ia
es ed,
and
he e
was
a
uni o m
suscep ibili y
o
me cu y
and
sil e .
All
s ains
es ed
we e
mul iply
me al
ole an .
Halobac e ia
a e
ae obic
mic oo ganisms
which
equi e
high
NaCI
concen a ions
in
a
medium
o
g ow
and
su i e
(9)
and
which
a e
included,
oge he
wi h
me hanogens
and
he moacidophiles,
in
he
a chaebac e ia
(22).
This
mic obial
g oup
has
been
ex ensi ely
s udied
wi h
ega d
o
hei
physiology, biochemis y,
ecology
and,
ecen ly,
gene ics
(2,
9,
10).
Al hough
he
suscep ibili y
o
an ibio ics
and,
in
some
ins ances,
he
mechanisms
o
ac ion
o
some
an imi-
c obial
agen s
ha e
been
s udied
in
halobac e ia
(3,
4,
12),
o
da e
he e
a e
no
epo s
conce ning
hei
na u al
suscep i-
bili y
o
hea y
me als
and
o ganome allic
compounds,
le
alone
hei
abili y
o
de elop
hea y
me al
esis ances.
The
la e
subjec
migh
p o ide
use ul
in o ma ion
abou
ways
o
de eloping
an ibio ic
esis ance,
since
in
nonhalophilic
bac-
e ia
genes
de e mining
esis ance
o
an ibio ics
and
ce ain
me als
a e
o en
ca ied
on
he
same
plasmids
(20).
I
was
ound
ecen ly
ha
megaplasmids
o
unknown
unc ion
a e
ha bo ed
by
he
majo i y
o
halobac e ia
(6).
A
knowledge
o
me al
ole ance
may
e eal
some
unc ions
o
some
o
hese
plasmids
and,
in
addi ion,
he
possible
hea y
me al
esis-
ances
could
be used
in
halobac e ia
as
gene ic
ma ke s.
On
he
o he
hand,
me al
ole ance
could
be
ele an
o
he
ecology
and
physiology
o
halobac e ia,
since
hey
usually
g ow
in
habi a s
such
as
sola
sal e ns
o
hype saline
lakes
con aining
some
wa e s
which
ha e
ecen ly
been
ound
o
be
pollu ed
wi h
hea y
me als
(unpublished
da a).
The
aim
o
he
p esen
s udy
was
o
examine
he
suscep-
ibili y
o
a
la ge
numbe
o
halobac e ia,
including
bo h
cul u e
collec ion
s ains
and
eshly
isola ed
s ains,
o
se e al
hea y
me als.
A
o al
o
68
halobac e ial
s ains
we e
selec ed
o
his
s udy.
The
13
cul u e
collec ion
s ains
a e
lis ed
in
Table
1,
and
he
o he
55
s ains
ha e
been
cha ac-
e ized
in
a
p e ious
axonomic
s udy
and
iden i ied
as
membe s
o
he
genus
Halobac e ium
(19).
These
la e
s ains
ep esen
a
e y
he e ogeneous
g oup
o
halobac e ia
ha
can
be
commonly
isola ed
om
hype saline
habi a s
in
Spain.
The
cul u es
we e
g own
in
a
medium
( e e ed
o
as
SWYE)
con aining
a
inal
o al
sal s
concen a ion
o
ca.
25%
(w / ol)
and
0.5%
(w / ol)
yeas
ex ac
(Di co
Labo a o ies,
*
Co esponding
au ho .
De oi ,
Mich.).
The
composi ion
o
he
sal s
solu ion
was
as
ollows
(pe cen
[weigh / olume]):
NaCl,
19.4;
MgC92,
1.6;
MgSO4,
2.4;
CaCl2,
0.1;
KCl,
0.5;
NaHCO3,
0.02;
and
NaB ,
0.05
(6).
The
pH
was
adjus ed
o
7.2.
Incuba ion
was
done
a
37°C
in
an
o bi al
shake
(Lab-Line
Ins umen s,
Inc.,
Mel ose
Pa k,
Ill.)
a
200
s okes
pe
min.
The
10
hea y
me als
es ed
we e
p o ided
om
s anda d
comme cial
sou ces
as
Na2HAsO4,
AgNO3,
CdCI2,
CoC12,
CuSO4,
K2C O4,
HgCl2,
NiSO4,
Pb(NO3)2,
and
ZnSO4.
S ock
solu ions
we e
made
in
dis illed
wa e ,
s e ilized
by
il a ion
h ough
0.22-,um-po e
memb ane
il e s
(Millipo e
Co p.,
Bed o d,
Mass.),
and
kep
a
4°C
o
no
longe
han
1
day.
Suscep ibili y
was
de e mined
by
an
aga
dilu ion
me hod
(21)
wi h
a
S ee s
eplica o
(17).
Pla es
con aining
20
ml
o
SWYE
medium
solidi ied
wi h
2%
(w / ol)
Bac o-Aga
(Di co)
and
se e al
di e en
concen a ions
o
he
me al
inhibi o s
we e
p epa ed
on
he
days
o
he
expe imen s.
The
concen a ions
o
all
he
me als
we e
as
ollows
(millimola ):
0.005,
0.01,
0.05,
0.1,
0.5,
1,
2.5,
5,
10,
20,
40,
and
80.
This
ange
co e ed
hose
concen a ions
usually
used
in
s udies
o
me al
esis ance
in
eubac e ia
(7,
20).
Be o e
use,
he
pla es
we e
d ied
a
37°C
o
30
min;
hey
we e
hen
inocula ed
wi h
104
o
105
mic oo ganisms
om
exponen-
ially
g owing
cul u es
pe
spo .
Twen y-one
spo s
(each
om
a
di e en
bac e ial
s ain)
could
be
con enien ly
es ed
pe
pla e.
The
pla es
we e
hen
incuba ed
a
37°C
o
10
days.
Aga
pla es
wi hou
he
an imic obial
agen s
and
inocula ed
wi h
he
co esponding
es
mic oo ganisms
we e
used
as
con ols.
Simila
expe imen s,
in
which
he
sal
concen a ion
in
he
es
medium
was
15,
20,
o
30%
(w / ol),
we e
also
ca ied
ou .
A e
incuba ion,
he
MIC
was
de e mined
as
he
lowes
concen a ion
o
me al
which
p e en ed
g ow h.
The
MICs
o
all
he
s ains
we e
he
same
when
he
s ains
we e
es ed
in
a
leas
h ee
di e en
expe imen s.
Fo
he
pu pose
o
de ining
me al
ole ance,
hose
s ains
which
we e
no
inhibi ed
by
10
mM
As;
1
mM
Ag,
Cd,
Co,
C ,
Cu,
Ni,
Pb,
and
Zn;
and
0.1
mM
Hg
we e
ega ded
as
ole an .
These
concen a ions
ha e
been
used
o
his
pu pose
in
he
majo i y
o
s udies
ca ied
ou
wi h
eubac e ia
(11,
14,
20).
I
is
impo an
o
poin
ou
ha
he
a ailabili y
o
he
espec i e
me als
can
be
in luenced
by
chlo ides
o
o he
kinds
o
sal s
con ained
in
he
cul u e
1199
APPL.
ENVIRON.
MICROBIOL.
TABLE
1.
MICs
o
10
me al
ions
es ed
agains
13
halobac e ial
cul u e
collec ion
s ains
MIC
(mM)
o ':
As
Ag
Ni
Co
Pb
Cd
C
Hg
Zn
Cu
H.
medi e anei
ATCC
33500
20
0.5
2.5
1
20
2.5
5 0.01
0.5
1
H.
olcanii
DS2
20
0.5
2.5
1
20
0.5
5 0.01
0.5
1
H.
hispanicum
ATCC
33960
10
0.5
2.5
1
10
0.5
5
0.01
0.5
1
H.
allismo is
ATCC
29715
10
0.5
2.5
1
10
0.5
5
0.01
0.5
1
H.
gibbonsii
ATCC
33959
10
0.5
2.5
1
10
0.5
5
0.01
0.5
1
H.
saccha o o um
ATCC
2952
10
0.05
1
0.5
20
0.5
2.5
0.01
0.5
2.5
H.
halobium
CCM
2090
10
0.05
1
0.5
20
0.5 2.5
0.01
0.5
2.5
H.
apanicum
NCMB
767
10
0.05
1
0.5
5
0.5
2.5
0.01
0.5
2.5
H.
salina ium
CCM
2084
20
0.05
1
0.5
5
0.1
2.5
0.01
0.05
1
Haloa cula
sp.
s ain
WS-1
10
0.05
0.1
1
5 0.05
2.5
0.05
0.05
2.5
Haloa cula
sp.
s ain
GN-1
10
0.05
0.1
1
5
0.05
2.5
0.05
0.05
2.5
H.
cali o niae
ATCC
33799
10
0.05
1
0.5
10
0.1
1
0.05
0.5
2.5
H.
sinaiiensis
ATCC
33800
10
0.05
1
0.5
5
0.05
2.5
0.05
0.05
1
a
Bold ace
ype
indica es
concen a ions
in ol ing
ole ance
o
he
co esponding
me al
ion.
medium
used
in
he
p esen
s udy.
In
addi ion,
he
o ma ion
o
me al
complexes
in
his
cul u e
medium
may
de e mine
he
ue
soluble
me al
concen a ions,
and,
indeed,
he
oxici y
o
some
me als
could
be
a ibu ed
o
a
me al
complex
a he
han
a
me al
ca ion.
The
MICs
o
he
hea y
me als
es ed
agains
he
halobac e ial
collec ion
s ains
used
in
he
p esen
s udy
a e
shown
in
Table
1.
On
he
basis
o
he
simila
MICs
o
all
he
me als
es ed,
hese
s ains
can
be
g ouped
in o
i e
majo
g oups.
(i)
Halobac e ium
medi e anei
and
Halobac e ium
olcanii
appea ed
o
be
he
leas
suscep ible.
(ii)
Halobac-
e ium
hispanicum,
Halobac e ium
allismo is,
and
Halobac e ium
gibbonsii
had
he
same
esponse
o
each
me al
and
we e
equally
a ec ed
by
h ee
me al
ions
(C ,
Ni,
and
Pb).
(iii)
Halobac e ium
halobium,
Halobac e ium
sac-
cha o o um,
Halobac e ium
apanicum,
and
Halobac e-
ium
salina ium
had
a
simila
esponse
o
Ag,
C ,
Co,
Hg,
and
Ni
ions.
Howe e ,
he
MICs
o
Cd,
Cu,
and
Zn
ions
o
H.
salina ium
we e
lowe ,
bu
his
s ain
was
he
only
one
in
his
g oup
o
which
he
MIC
o
As
ion
was
highe .
O he -
wise,
all
hese
s ains
we e
ela i ely
ole an
o
C
and
Pb
ions
(MICs,
2.5
and
5
mM,
espec i ely),
and
h ee
o
hem
we e
also
ole an
o
Cu
ion
(MIC,
2.5
mM).
(i )
Haloa cula
sp.
s ain
WS-1
and
Haloa cula
sp.
s ain
GN-1
had
he
same
esponse
o
each
o
he
me als
es ed
and
we e
ole an
o
C ,
Cu,
and
Pb
ions.
( )
Haloa cula
cali o niae
and
Haloa cula
sinaiiensis
we e
inhibi ed
by
he
lowes
concen-
a ions
o
mos
o
he
me als
es ed.
TABLE
2.
Suscep ibili y
o
68
halobac e ial
s ains
o
10
me al
ions
Cumula i e
%
o
s ains
suscep ible
o
he
ollowing
me al
Me al
ion
ion
concn
(mM):
0.005
0.01
0.05
0.1
0.5
1
2.5
5
10
20
As
0
0
0
0
0
5
12
41
85
100
Ag
0
28
35
71
90
100
100
100
100
100
Cd
0
0
0
28
66
91
100
100
100
100
Co
0
0
0
7
38
75
100
100
100
100
C
0
0
0
0
0
32
41
85
100
100
Cu
0
0
0
0
5
20
98
100
100
100
Hg
0
70
100
100
100
100
100
100
100
100
Ni
0
0
0
7
10
55
86
100
100
100
Pb
0
0
0
0
0
0
6
20
66
100
Zn
0
0
10
43
84
94
100
100
100
100
All
he
cul u e
collec ion
s ains
we e
ela i ely
ole an
o
lead
and
ch omium
(excep
o
H.
cali o niae
o
he
la e
me al).
Only
he
s ains
belonging
o
g oup
iii
(excep
o
H.
salina ium)
and
he
Haloa cula
s ains
(excep
o
H.
sinaiiensis)
we e
ole an
o
coppe .
Only
h ee
s ains
(H.
medi e anei,
H.
olcanii,
and
H.
salina ium)
we e
ole an
o
a sena e.
H.
medi e anei
showed
he
highes
ole ance
o
cadmium
o
all
he
s ains
es ed.
The
cumula i e
pe cen ages
o
s ains
suscep ible
o
a -
ious
concen a ions
o
me al
ions
a e
shown
in
Table
2.
A
wide
ange
o
concen a ions
was
es ed
because
o
he
pauci y
o in o ma ion
on
he
suscep ibili y
o
halobac e ia
o
hea y
me als.
I
was
hoped
ha
an
inhibi o y
concen a-
TABLE
3.
Pa e ns
o
ole ance
o
10
hea y
me al
ions
in
68
halobac e ial
s ains
No.
o
di e en
No.
(%)
ole ances
o
s ains
8
As,
Cd,
Co,
C ,
Cu,
Ni,
Pb,
Zn
1
(1.5)
7
Cd, Co,
C ,
Cu,
Ni,
Pb,
Zn
1
(1.5)
6
C ,
Co,
Cu,
Ni,
Pb,
Zn
1
(1.5)
5
Co,
C ,
Cu,
Ni,
Pb
7
(10.3)
As,
C ,
Cu,
Ni,
Pb
2
(2.9)
As,
Cd,
C ,
Ni,
Pb
1
(1.5)
As,
C ,
Co, Cu,
Pb
1
(1.5)
Cd,
C ,
Cu,
Ni,
Pb
1
(1.5)
Co,
C ,
Cu,
Ni,
Pb
1
(1.5)
4
C ,
Cu,
Ni,
Pb
6
(8.8)
Co,
Cu,
Ni,
Pb
4
(5.9)
As,
C ,
Ni,
Pb
1
(1.5)
Cd,
C ,
Cu,
Pb
1
(1.5)
C ,
Cu,
Pb,
Zn
1
(1.5)
Cd, Co,
Cu,
Pb
1
(1.5)
3
C ,
Cu,
Pb
12
(17.6)
C ,
Ni,
Pb
4
(5.9)
As,
C ,
Pb
3
(4.5)
As,
Cu,
Pb
1
(1.5)
Cu,
Ni,
Pb
1
(1.5)
2
Cu,
Pb
12
(17.6)
C ,
Pb
5
(7.5)
1200
NOTES
NOTES
1201
ion
would
be
ob ained
which
could
be
used
as
a
guide
o
u he
in es iga ions,
despi e
he
ac
ha
he
oxici ies
o
some
me als
could
be
a ibu ed
o
me al
complex
o ma ion.
On
he
o he
hand,
in
expe imen s
in
which
he
sal
concen-
a ion
in
he
es
medium
was
15,
20,
o
30%
(w / ol),
ins ead
o
he
s anda d
25%,
no
signi ican
di e ences
in
he
MICs
we e
obse ed
in
he
ange
o
20
o
30%
sal s.
Howe e ,
a
he
lowes
sal
concen a ion,
an
enhanced
oxici y
o
he
hea y
me als
es ed
was
ound.
This
esul
may
ha e
been
due
o
a
highe
a ailabili y
o
cells
o
ake
up
he
me al
ions
in
he
medium
wi h
he
lowes
sal
concen a-
ion
(closely
ela ed
o
physiological
cellula
changes
which
ake
place
a
his
low
salini y)
o
o
a
lowe
deg ee
o
in e ac ion
be ween
he
ee
me al
ions
and
he
sal s
p esen
in
he
medium.
The
equencies
o
ole ance
o
each
me al
ion
in
all
he
s ains
es ed
we e
as
ollows:
As,
15%;
Ag,
0%;
Cd,
9%;
Co,
25%;
C ,
72%;
Cu,
80%;
Hg,
0%;
Ni,
45%;
Pb,
100%;
and
Zn,
6%.
All
halobac e ia
es ed
we e
ole an
o
lead,
and
a
g ea
pe cen age
o
hem
we e
ole an
o
e en
a
10
mM
concen a ion
o
his
me al.
Fu he mo e,
a
g ea
ac-
ion
o
he
s ains
we e
also
ole an
o
coppe
and
ch o-
mium.
Howe e ,
i
should
be
poin ed
ou
ha
his
high
ole ance
o
lead,
coppe ,
and
ch omium
could
ha e
been
due
o
he
binding
o
hese
me al
ions
o
some
o
he
componen s
o
he
es
medium,
as
has
been
epo ed
by
Ramamoo hy
and
Kushne
(13).
These
in es iga o s
showed
ha
di e en
componen s
o
he
medium
(yeas
ex ac ,
pep one,
yp one,
e c.)
exhibi ed
high
binding
o
lead,
coppe ,
and
cadmium.
Besides,
lead
can
be
accumu-
la ed
in
he
cell
wall
and
memb ane
(18).
Mo eo e ,
i
may
be
ha
he e
was
much
less
lead
a ailable
in
he
cul u e
medium
han
ini ially
added,
since
he e
was
a
g ea
amoun
o
sul a e
p esen
in
he
medium.
As
a
esul ,
he
soluble
lead
would
be
a
a
lowe
concen a ion.
Ne e heless,
since
e y
li le
esea ch
has
been
conduc ed
on
he
gene ic
basis
o
lead
esis ance
in
bac e ia,
he
ole ance
exhibi ed
by
halobac e ia
appea s
o
be
an
in e es ing
ield
o
addi ional
esea ch.
O he wise,
all
he
s ains
demons a ed
a
high
suscep ibil-
i y
o
me cu y
and
sil e
and
e y
li le
ole ance
o
zinc,
cadmium,
and
a sena e.
Me cu y
was
he
agen
ha
showed
he
highes
ac i i y
agains
he
halobac e ia
es ed;
all
we e
inhibi ed
by
a
0.05
mM
concen a ion
o
his
me al
ion,
and
mos
o
hem
we e
inhibi ed
by
0.01
mM.
The
suscep ibili y
o
halobac e ia
o
me cu y
has
been
p e iously
used
as
a
pheno ypic
ea u e
in
some
axonomic
s udies
on
halobac-
e ia
(5,
15).
Howe e ,
he
concen a ion
o
HgCl2
used
in
hose
epo s
was
highe
han
0.1
mM,
a
concen a ion
which
inhibi ed
all
he
s ains
es ed.
I
was
epo ed
(1)
ha ,
in
he
p esence
o
high
concen a ions
o
NaCl,
he
oxici y
o
zinc
was
inc eased,
and
his
was
he
esul
no
o
a
syne gis ic
in e ac ion
be ween
Zn2+
and
ele a ed
osmo ic
p essu es
bu
o
he
o ma ion
o
complex
anionic
ZnCl-
species,
which
exe ed
g ea e
oxici ies
han
did
ca ionic
Zn2+.
This
ac
could
be
esponsible
o
he
high
suscep i-
bili y
o
halobac e ia
o
zinc.
All
he
s ains
es ed
we e
ole an
o
mul iple
me al
ions:
17
we e
ole an
o
wo
me al
ions
(25%),
21
we e
ole an
o
h ee
(30.9%),
14
we e
ole an
o
ou
(20.7%),
13
we e
ole an
o
i e
(19.2%),
and
1
(1.5%),
1
(1.5%),
and
1
(1.5%)
we e
ole an
o
six,
se en,
and
eigh
me al
ions,
espec-
i ely.
S ains
wi h
iple
ole ance
we e
ound
mos
e-
quen ly,
ollowed
by
hose
wi h
double
ole ance.
Howe e ,
s ains
ole an
o
i e
o
ou
di e en
me al
ions
we e
signi ican ly
de ec ed
(abou
40%
o
he
o al
s ains).
The
pa e ns
o
ole ance
o
he
hea y
me als
es ed
in
he
68
halobac e ial
s ains
es ed
a e
shown
in
Table
3.
I
is
well
documen ed
ha
many
me al
esis ances
can
be
go e ned
by
plasmid-encoded
mechanisms
in
bo h
g am-
nega i e
and
g am-posi i e
eubac e ia
(8,
16,
20).
Since
we
ha e
ecen ly
ound
ha
75%
o
all
halobac e ia
used
in his
s udy
ca y
a
leas
one
plasmid
and
ha
in
he
majo i y
o
hese
s ains
h ee
o
ou
megaplasmids
can
be
de ec ed
(6),
addi ional
expe imen s
o
co ela e
he
p esence
o
plasmids
and
he
ole ance
o
some
hea y
me al
ions
in
each
indi id-
ual
s ain
a e
now
in
p og ess
in
ou
labo a o y.
This
in es iga ion
was
suppo ed
by
g an s
om
he
Comisi6n
Aseso a
pa a
el
Desa ollo
de
la
In es igaci6n
Cien i ica
y
Tecnica
and
om
he
Jun a
de
Andalucia.
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NOTES