Comparison between Activated Sludge, Moving Bed Biofilm Reactor, Integrated Fixed-Film Activated Sludge: treatment, kinetics and microbiology

Alves, Edgar Rocha
Comparison between Activated Sludge, Moving Bed Biofilm Reactor, Integrated Fixed-Film Activated Sludge: treatment, kinetics and microbiology

Author: Alves, Edgar Rocha
Year: 2019
Source: https://estudogeral.uc.pt/bitstream/10316/83108/1/Disserta%c3%a7%c3%a3o%20de%20mestrado%20-%20Edgar%20Alves.pdf
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Edga r Ro cha Alves
Compa rison b et w een A ctivated Sludge,
Moving Bed Biofilm Reacto r, Integrated
Fixed-Film A ctivated Sludge: treatment,
kinetics and microbiology
July 2017

Departamen to de Engenharia Mecânica
Comparison b et w een A ctiv ated Sludge, Mo ving Bed
Biofilm Reactor, In tegrated Fixed-Film A ctiv ated Sludge:
treatmen t, kinetics and microbiology
Comparação en tre Lamas A tiv adas, Reator de Biofilme
em Leito Mó v el, e Reator In tegrado de Lamas A tiv adas e
de Biofilme: tratamen to, cinéticas e microbiologia
A Dissertation for Graduate Study in MSc Program
Master of Science in En vironmen tal Engineering
A uthor:
Edgar Ro c ha Alv es
Sup ervisor:
Prof. Doutora Rosa Maria de Oliv eira Quin ta-F erreira
Prof. Doutor Luís Miguel Castro
Jury:
Prof. Doutor José Carlos Miranda Góis
Prof. Doutora Rosa Maria de Oliv eira Quin ta-F erreira
Prof. Doutor R ui Carlos Cardoso Martins
July 2017

A c kno wledgemen ts
First, i w ould lik e to ac kno wledge m y orien tators: Prof. Dr. Rosa Quin ta-F erreira and Prof. Dr.
Luís Miguel Castro for the opp ortunit y giv en, for all the help pro vided throughout the thesis
w ork.
Also to Prof. Dr. An tónio Luís P ereira do Amaral, from Coim bra Institute of Engineering
(ISEC), for all the time and help giv en in the microbiology area.
T o m y girlfriend, Kristina, a v ery sp ecial thanks for giving me motiv ation and strength to con tin ue
and not giv e up. I couldn’t do it without y ou.
Mostly , a thanks to m y family , esp ecially to m y mother, for giving me the conditions to b e here
and for all the supp ort not only in the academic lev el but also in life.
Last but not least, i w ould lik e to thank all the colleagues in the lab not only for the help but
compan y also.

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Abstract
The Mo ving Bed Biofilm Reactor (MBBR) and the In tegrated Fixed-Film A ctiv ated Sludge
(IF AS) are b oth considered adv anced biological systems for w astew ater treatmen t, whic h mak e
use of b oth susp ended and attac hed biomass. Both pro cesses require less space than the A ctiv ated
Sludge (AS) to treat w astew ater with the same organic strength. The ma jor adv an tage of MBBR
is the absence of sludge recirculation, and the ma jor adv an tage of IF AS is the simplicit y of
upgrading an existing an AS reactor b y in tro ducing carriers, so there is no need to build new
tanks. The dairy industry w astew ater p oses a threat to the en vironmen t if not treated, for
ha ving an high con ten t of organic load and for resulting from one of the industries with the
highest consumption of w ater.
The aim of this thesis is the comparison b et w een three t yp es of biological treatmen t systems: AS,
MBBR and IF AS in terms of treatmen t efficiency , biomass gro wth kinetics and biomass c harac-
terization. The exp erimen tal set-up w as made b y three indep enden t lab oratory scale reactors:
one A ctiv ated Sludge (AS), one Mo ving Bed Biofilm Reactor (MBBR) and one In tegrated Fixed-
Film A ctiv ated Sludge (IF AS) , all op erating in batc h mo de and fed with syn thetic w astew ater
in order to sim ulate real w astew ater from a dairy industry .
In the first batc h test, whic h lasted 12 hours, the MBBR and IF AS reactors offered high COD
remo v al efficiencies, of ab out 96% and 96%, while the AS reactor only ac hiev ed 68%. The
IF AS reactor sho w ed the b est COD remo v al efficiency o v er a p erio d of 5 hours, 89%, due to the
presence of fixed biomass and high concen tration of susp ended biomass. In the second batc h test,
the duration w as 10 hours and the three reactors had v ery high COD remo v al efficiencies, b eing
94%, 97% and 93% in the AS, MBBR and IF AS reactors, resp ectiv ely . The IF AS reactor sho w ed
again the b est COD remo v al efficiency in a 4 hour p erio d, of ab out 87%. The total nitrogen
efficiency w as 20%, 80% and 19% in 12 hours in the first batc h test, and in the second batc h
test w as 41%, 62% and 63% in 10 Hours in the AS, MBBR and IF AS reactors, resp ectiv ely . The

kinetics of biomass gro wth sho w ed the highest Y O B S v alue for AS and the lo w est in the IF AS
reactor. As for sludge pro duction, MBBR pro duced 35% less solids than the AS reactor and
38% less than the IF AS reactor. The biomass in the bulk liquid was also c haracterized and it
w as concluded that there w ere no indications of zo ogleal bulking or filamen tous bulking. No
predominance of protozoa or metazoa w as found in an y of the reactor, probably due to the use
syn thetic w astew ater.
Key w ords: biological treatmen t, MBBR, AS, IF AS, sludge pro duction, kinetics, zo ogleal bulk-
ing, filamen tous bulking.

Resumo
O Reator de Biofilme com Leito Mó v el (MBBR - ”Mo ving Bed Biofilm Reactor” em inglês) e o
Reator In tegrado de Lamas A ctiv adas com Biofilme em Leito Mó v el (IF AS - ”In tegrated Fixed-
Film A ctiv ated Sludge” em inglês são am b os considerados sistemas biológicos a v ançados para
o tratamen to de águas residuais, que utilizam biomassa susp ensa e fixa. Am b os os pro cessos
requerem menos espaço do que as Lamas A ctiv adas (LA) para tratar águas residuais com a
mesma carga orgânica. A principal v an tagem do MBBR é que não é necessário a recirculação de
lamas, e a principal v an tagem do IF AS é a simplicidade do aumen to da capacidade de tratamen to
de um reator LA existen te atra v és da in tro dução de sup ortes, p ortan to, sem a necessidade de
construir no v os tanques biológicos. As águas residuais da indústria de laticínios, senão forem
tratadas, represen tam uma ameaça para o meio am bien te p or terem alto teor de carga orgânica
e p or ser uma das indústrias com um grande consumo de água.
O ob jetiv o desta tese é a comparação en tre três tip os de sistemas de tratamen to biológico: LA,
MBBR e IF AS em termos de eficiência de tratamen to, cinética do crescimen to da biomassa, e
caracterização da biomassa. A configuração exp erimen tal é comp osta p or três reatores de escala
lab oratorial e que funcionam indep enden tes uns dos outros: um de Lamas A ctiv adas (LA), um
reator MBBR e um reator IF AS, to dos a funcionar em mo do batc h e alimen tados p or um efluen te
constituido p or diluição de leite com água.
No primeiro teste em batc h, que durou 12 horas, os reatores MBBR e IF AS tiv erem eficiências de
remo ção de Carência Química de Oxigénio (CQO) altas, 96% e 92%, enquan to que o reator LA só
conseguiu 68%. O reator IF AS mostrou a melhor eficiência de remo ção de CQO num p erío do de
5 horas, 89%, devido à presença de biomassa fixa e alta concen tração de biomassa susp ensa. No
segundo teste em batc h, a duração foi de 10 horas e os três reatores tiv eram eficiências de remo ção
de Carência Química de Oxigénio (CQO) m uito altas, sendo 94%, 97% e 93% nos reatores LA,
MBBR e IF AS, resp ectiv amen te. O reator IF AS v oltou a mostrar a melhor eficiência de remo ção

de CQO n um p erío do de 4 horas, de cerca 87%. A eficiência da remo ção de azoto total foi de
20%, 80% e 19% em 12 horas no primeiro teste em batch, e no segundo teste em batc h foi de
41%, 62% e 63% em 10 horas, nos reatores LA, MBBR e IF AS, resp ectiv amen te. A cinética do
crescimen to da biomassa mostrou v alores de Y O B S maiores para o LA e os menores no MBBR.
Quan to à pro dução de lamas, o MBBR pro duziu 35% menos lamas que o reactor LA e 38%
menos lamas que o reactor IF AS. A biomass susp ensa nos reatores tam b ém foi caracterizada e
foi concluído que não ha via indicíos de ”zo ogleal bulking” ou ”filamen tous bulking” . Não houv e
predominância de protozoários ou metazoários em nenh um dos reatores, pro v a v elmen te devido
ao uso de águas residuais sin téticas.
P ala vras-c ha v e: tratamen to biológico, MBBR, LA, IF AS, pro dução de lamas, cinéticas, zo ogleal
bulking, filamen tous bulking.

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/* Blink(up to 41)/Webkit have bug with negative word-spacing and inline-block (pdf2htmlEX #416), so keep normal span inline. */
position:relative;
unicode-bidi:bidi-override; /* For rtl languages, e.g. Hebrew, we don't want the default Unicode behaviour */
}
.__c00002 { /* text shift */
/* Blink(up to 41)/Webkit have bug with inline element, continuous spaces and word-spacing. Workaround by inline-block. */
display: inline-block;
color: transparent;
z-index: -1;
}
/* selection background should not be opaque, for fallback mode */
::selection{
background: rgba(127,255,255,0.4);
}
::-moz-selection{
background: rgba(127,255,255,0.4);
}
.pi_c00002 { /* info for Javascript */
display:none;
}
.l_c00002 { /* annotation links */
}
/* transparent color - WebKit */
.d_c00002 { /* css drawing */
position:absolute;
transform-origin:0% 100%;
-ms-transform-origin:0% 100%;
-webkit-transform-origin:0% 100%;
}
/* for the forms */
.it_c00002 {
border: none;
background-color: rgba(255, 255, 255, 0.0);
}

.ir_c00002:hover {
cursor: pointer;
}

/* Base CSS END */

/* vim: set shiftwidth=2 tabstop=2 autoindent cindent expandtab filetype=css: */
/*!
* Fancy styles for pdf2htmlEX
* Copyright 2012,2013 Lu Wang
* https://github.com/pdf2htmlEX/pdf2htmlEX/blob/master/share/LICENSE
*/
@keyframes fadein { from { opacity:0;} to { opacity:1;} }
@-webkit-keyframes fadein { from { opacity:0;} to { opacity:1;} }
@keyframes swing {
0% { transform: rotate(0deg); }
10% { transform: rotate(0deg); }
90% { transform: rotate(720deg); }
100%{ transform: rotate(720deg); }
}
@-webkit-keyframes swing {
0% { -webkit-transform: rotate(0deg); }
10% { -webkit-transform: rotate(0deg); }
90% { -webkit-transform: rotate(720deg); }
100%{ -webkit-transform: rotate(720deg); }
}
@media screen {
#sidebar {
background-color:#2f3236;
/* modified from http://philbit.com/svgpatterns/#crossstripes */
background-image:url("data:image/svg+xml;base64,PHN2ZyB4bWxucz0iaHR0cDovL3d3dy53My5vcmcvMjAwMC9zdmciIHdpZHRoPSI0IiBoZWlnaHQ9IjQiPgo8cmVjdCB3aWR0aD0iNCIgaGVpZ2h0PSI0IiBmaWxsPSIjNDAzYzNmIj48L3JlY3Q+CjxwYXRoIGQ9Ik0wIDBMNCA0Wk00IDBMMCA0WiIgc3Ryb2tlLXdpZHRoPSIxIiBzdHJva2U9IiMxZTI5MmQiPjwvcGF0aD4KPC9zdmc+");
}
#outline {
font-family:Georgia,Times,"Times New Roman",serif;
font-size:13px;
margin:2em 1em;
}
#outline ul {
padding:0;
}
#outline li {
list-style-type:none;
margin:1em 0;
}
#outline li > ul {
margin-left: 1em;
}
#outline a,
#outline a:visited,
#outline a:hover,
#outline a:active {
line-height:1.2;
color:#e8e8e8;
text-overflow:ellipsis;
white-space:nowrap;
text-decoration:none;
display:block;
overflow:hidden;
outline:0;
}
#outline a:hover {
color:rgb(0,204,255);
}
#page-container {
background-color:#9e9e9e;
/* http://philbit.com/svgpatterns/#thinstripes */
background-image: url("data:image/svg+xml;base64,PHN2ZyB4bWxucz0iaHR0cDovL3d3dy53My5vcmcvMjAwMC9zdmciIHdpZHRoPSI1IiBoZWlnaHQ9IjUiPgo8cmVjdCB3aWR0aD0iNSIgaGVpZ2h0PSI1IiBmaWxsPSIjOWU5ZTllIj48L3JlY3Q+CjxwYXRoIGQ9Ik0wIDVMNSAwWk02IDRMNCA2Wk0tMSAxTDEgLTFaIiBzdHJva2U9IiM4ODgiIHN0cm9rZS13aWR0aD0iMSI+PC9wYXRoPgo8L3N2Zz4=");
-webkit-transition:left 500ms;
transition:left 500ms;
}
.pf_c00002 {
margin: 13px auto;
box-shadow: 1px 1px 3px 1px #333;
/* Needed by IE to make box-shadow works * https://developer.mozilla.org/en-US/docs/Web/CSS/box-shadow */
border-collapse: separate;
}
.pc_c00002.opened { /* used by pdf2htmlEX.js, to show/hide pages */
-webkit-animation: fadein 100ms;
animation: fadein 100ms;
}
.loading-indicator_c00002.active {
/*
* use 0.01s instead of 0s,
* since YUI Compressor will change 0s to 0,
* which is not recognized by Firefox
*/
-webkit-animation: swing 1.5s ease-in-out 0.01s infinite alternate none;
animation: swing 1.5s ease-in-out 0.01s infinite alternate none;
}
.checked_c00002 {
background: no-repeat url(data:image/png;base64,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);
}
}
/* Fancy CSS END */

.ff0_c00002{font-family:sans-serif;visibility:hidden;}
@font-face{font-family:ff1_c00002;src:url('data:application/font-woff;base64,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Con ten ts
1 In tro duction 1
1 . 1 B a c k g r o u n d ....................................... 1
1 . 2 A i m a n d O b j e c t i v e s ................................... 3
1 . 3 O v e r v i e w o f t h e t h e s i s ................................. 3
2 Theory and Literature Review 5
2.1 Biological W astew ater T reatmen t . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
2 . 1 . 1 N i t r o g e n r e m o v a l ................................ 7
2 . 1 . 2 P h o s p h o r o u s .................................. 1 0
2 . 1 . 3 B a t c h R e a c t o r ................................. 1 0
2 . 2 M i c r o b i a l M e t a b o l i s m ..... ............................ 1 0
2 . 2 . 1 M i c r o o r g a n i s m s ................................. 1 1
2.2.1.1 Protozoa and metazoa . . . . . . . . . . . . . . . . . . . . . . . . 12
2.3 Microbial Gro wth Kinetics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
2 . 3 . 1 S y s t e m p a r a m e t e r s ............................... 1 7
2.4 A ctiv ated Sludge Reactor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
2.5 Mo ving Bed Biofilm Reactor (MBBR) . . . . . . . . . . . . . . . . . . . . . . . . 19
2.5.1 In tegrated Fixed-Film A ctiv ated Sludge (IF AS) or Hybrid MBBR (HMBBR) 20
2 . 6 B i o c a r r i e r s ........................................ 2 1
2 . 7 B i o fi l m .......................................... 2 2
2 . 7 . 1 A t t a c h m e n t ................................... 2 3
2 . 7 . 2 G r o w ...................................... 2 4
2 . 7 . 3 D e t t a c h m e n t .................................. 2 4
2 . 7 . 4 B i o fi l m K i n e t i c s ................................ 2 5
2 . 8 S t a t e o f t h e A r t ..................................... 2 7
i

3 Materials and Metho ds 31
3 . 1 A n a l y t i c a l M e t h o d s ................................... 3 1
3.1.1 Chemical Oxygen Demand . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
3 . 1 . 2 S o l i d s ...................................... 3 2
3.1.2.1 T otal Susp ended Solids . . . . . . . . . . . . . . . . . . . . . . . 33
3.1.2.2 V olatile Susp ended Solids . . . . . . . . . . . . . . . . . . . . . . 33
3.1.2.3 A ttac hed Biomass . . . . . . . . . . . . . . . . . . . . . . . . . . 33
3.1.3 T otal Carb on and T otal Nitrogen . . . . . . . . . . . . . . . . . . . . . . . 34
3 . 1 . 4 S l u d g e V o l u m e I n d e x .............................. 3 4
3 . 1 . 5 T e m p e r a t u r e .................................. 3 4
3.1.6 Microbial c haracterization . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
3.2 Exp erimen tal Unit Description . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
3 . 2 . 1 B i o c a r r i e r .................................... 3 5
3 . 2 . 2 W a s t e w a t e r ................................... 3 6
3 . 3 E x p e r i m e n t s ....................................... 3 7
3 . 3 . 1 B a t c h E x p e r i m e n t s ............................... 3 7
3.3.1.1 1 st b a t c h ............................... 3 7
3.3.1.2 2 nd b a t c h ............................... 3 7
3.3.2 Bacterial flo c and filamen ts c haracterization . . . . . . . . . . . . . . . . . 38
4 Results and Discussion 39
4 . 1 B i o fi l m i n o c u l a t i o n ................................... 3 9
4.2 Biological systems analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
4.2.1 1 st b a t c h .................................... 4 1
4 . 2 . 1 . 1 C O D e v a l u a t i o n ........................... 4 1
4.2.1.2 Biomass assessmen t . . . . . . . . . . . . . . . . . . . . . . . . . 42
4 . 2 . 1 . 3 T o t a l N i t r o g e n ............................ 4 3
4.2.1.4 COD and TC correlation . . . . . . . . . . . . . . . . . . . . . . 44
4.2.1.5 Reaction Kinetics Assessment . . . . . . . . . . . . . . . . . . . . 44
4.2.2 2 nd b a t c h .................................... 4 7
4 . 2 . 2 . 1 C O D e v a l u a t i o n ........................... 4 7
4.2.2.2 Biomass assessmen t . . . . . . . . . . . . . . . . . . . . . . . . . 48
4 . 2 . 2 . 3 T o t a l N i t r o g e n ............................ 5 0
ii

4.2.2.4 COD and TC correlation . . . . . . . . . . . . . . . . . . . . . . 50
4 . 2 . 2 . 5 V S S / T S S r a t i o ............................ 5 1
4.2.2.6 Reaction Kinetics Assessment . . . . . . . . . . . . . . . . . . . . 52
4.2.2.7 Sludge pro duction . . . . . . . . . . . . . . . . . . . . . . . . . . 54
4.3 Bacterial flo c and filamen ts c haracterization . . . . . . . . . . . . . . . . . . . . . 55
4 . 3 . 1 M i c r o b i a l c o n s o r t i a ............................... 6 1
5 Conclusions and F uture W ork 63
5 . 1 C o n c l u s i o n s ....................................... 6 3
5 . 2 F u t u r e w o r k ....................................... 6 5
References 66
A cron yms and sym b ols 73
iii

iv

Figures
2.1 Con v en tional w astew ater treatmen t plan t (Cop yrigh t from Metcalf & Eddy et al.
( 2 0 1 4 ) ) . ......................................... 6
2.2 Protozoa and metazoa examples: (a) A elosoma - Metazo an (Cop yrigh t from Ph y-
toplankton.info) (b) Colpidium - F r e e-swimming ciliate (Cop yrigh t from Protist
Information Serv er) (c) Digonon ta - Metazo an (Cop yright from Amaral and Leal
(2013)) (d) Epist ylis - Stalke d ciliate (Cop yrigh t from Amaral and Leal (2013))
(e) Euplotes - F r e e-swimming ciliate (Copyrigh t from Amaral and Leal (2013)) (f )
V orticella microstoma - Stalke d ciliate (Cop yrigh t from Amaral and Leal (2013))
(g) Op ercularia - Stalke d ciliate (Cop yrigh t from Amaral and Leal (2013)) (h)
Uronema - F r e e-swimming ciliate (Cop yrigh t from Amaral and Leal (2013)). . . . 14
2.3 T ypical microbial gro wth curv e in batc h system (Cop yrigh t from Hoang (2013)). . 15
2.4 Graphic represen tation of sp ecific micro organism gro wth rate (Cop yrigh t from
H o a n g ( 2 0 1 3 ) ) . ..................................... 1 6
2.5 Sc heme of Mo ving Bed Biofilm Reactor (Cop yrigh t from R usten et al. (2006)). . . 19
2.6 Biofilm formation in 3 steps (Cop yrigh t from Dirc kx (2003). . . . . . . . . . . . . 23
2.7 Substrate p enetration profiles in a biofilm (Cop yrigh t from Asiedu (2001)). . . . . 25
2.8 Substrate remo v al rate dep endency from substrate concen tration (Copyrigh t from
H e n z e e t a l . ( 1 9 9 7 ) ) . .................................. 2 7
3.1 Exp erimen tal unit arrangemen t: (1) - A ctiv ated Sludge reactor (AS), (2) - Mo v-
ing Bed Biofilm Reactor (MBBR), (3) - In tegrated Fixed-Film A ctiv ated Sludge
( I F A S ) r e a c t o r ..................................... 3 6
3.2 Bioflo w 9 - Bio carrier used in MBBR and IF AS reactors. . . . . . . . . . . . . . . 36
4.1 Biofilm ino culation: (a) Empt y carrier (b) Carrier from MBBR (c) Carrier from
I F A S . .......................................... 4 0
v

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4.2 Reactor with ino culated bio carriers. . . . . . . . . . . . . . . . . . . . . . . . . . . 40
4.3 sCOD and VSS concen trations in first batc h exp erimen t: (a) AS (b) MBBR (c)
I F A S . .......................................... 4 1
4.4 TN concen trations in first batc h exp erimen t: (a) AS (b) MBBR (c) IF AS. . . . . . 43
4.5 (a) TC concen tration in the first batc h exp erimen t (b) Correlation b et w een COD
and TC in the first batc h exp erimen t. . . . . . . . . . . . . . . . . . . . . . . . . . 44
4.6 First order reaction linearization in first batc h test for the AS reactor. . . . . . . . 46
4.7 Linearization for Y O B S result of the first batc h test in the AS reactor. . . . . . . . 46
4.8 VSS and sCOD concen trations in the second batc h test: (a) AS (b) MBBR (c)
I F A S . .......................................... 4 8
4.9 TN concen trations in the second batc h exp erimen t: (a) AS (b) MBBR (c) IF AS . 50
4.10 (a) TC concen tration in the second batc h exp erimen t (b) Correlation b et w een TC
and COD in the second batc h exp erimen t. . . . . . . . . . . . . . . . . . . . . . . 51
4.11 (a) VSS/TSS ratio (b) Correlation b et w een VSS and TSS. . . . . . . . . . . . . . 51
4.12 First order linearization in the second batc h test for µ max : (a) AS (b) MBBR (c)
I F A S . .......................................... 5 2
4.13 First order linearization in the second batc h test for Y O B S : (a) AS (b) MBBR (c)
I F A S . .......................................... 5 3
4.14 First order linearization in the second batc h test for µ max using substrate concen-
tration: (a) AS (b) MBBR (c) IF AS. . . . . . . . . . . . . . . . . . . . . . . . . . 54
4.15 (a) T otal sludge pro duction in the second batc h test (b) Sludge pro duced p er
s C O D r e m o v e d ...................................... 5 5
4.16 Microscop e images of the bacterial flo cs in the three reactors: (a) AS (b) MBBR
( c ) I F A S . ........................................ 5 6
4.17 Application of Matlab program dev elop ed b y Amaral and F erreira (2005): (a) AS
( b ) M B B R ( c ) I F A S . .................................. 5 6
4.18 Flo cs total area p er v olume in the three reactors. . . . . . . . . . . . . . . . . . . 57
4.19 Area p ercen tage o ccupied b y microflo cs, mesoflo cs and macroflo cs in the sludge
o f t h e t h r e e s y s t e m s . .................................. 5 8
4.20 Main morphological parameters for eac h aggregates class: (a) AS (b) MBBR (c)
I F A S . .......................................... 5 9
4.21 Disp ersed bacteria in the AS reactor: (a) After 30 min sedimen tation of the effluen t
(b) Microscop e observ ation of the sludge. . . . . . . . . . . . . . . . . . . . . . . . 60
vi

4.22 Filamen tous bacteria in the three systems: (a) T otal Length p er V olume (b) T otal
L e n g t h p e r T o t a l A r e a . ................................. 6 0
4.23 Protozoa and metazoa found: (a) Monogonon ta (b) Nemato de (c) Zo othamnium. 62
vii

viii

T ables
2.1 Main constituen ts of concern in w astew ater treatmen t (A dapted from Metcalf &
E d d y e t a l . ( 2 0 1 4 ) ) . ................................... 7
2.2 Organism classification (A dapted from Metcalf & Eddy et al. (2014)). . . . . . . . 11
2.3 Characteristics of differen t biofilm carriers (A dapted from Barw al and Chaudhary
( 2 0 1 4 ) ) . ......................................... 2 2
ix

x

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