Synthesis and scaled-up of non-active and active Belite-Alite-Ye'elimite clinker (BAY)
Abstract
Ordinary Portland cement (OPC) is an environmentally contentious material, as for every ton of OPC produced, ~0.97 tons of CO2 are released. This opens the need of designing new formulations of cements formed by low calcite demanding phases, such as ye'elimite, that release less CO2 during their fabrication. Belite-Alite-Ye’elimite (BAY) cements are promising eco-friendly building materials as OPC substitutes at a large scale[1]. There action of alite and ye´elimite with water should develop cements with high mechanical strengths at early ages,while belite will contribute to later curing times. However, they develop lower mechanical strengths at early-medium ages than OPC[2]. It is known that the presence of different polymorphs of belite and ye'elimite affects the hydration due to the different reactivity of those phases[3]. The aim of this work is to process, characterize and scaled-up a non-active (with coexisting alite,β-belite and ye'elimite) and an active(with coexisting alite,α'H-belite and ye'elimite) BAY clinkers prepared with CaF2 and ZnO, named here after BAY-Z and a-BAY-Z respectively, to develop, in a future step,comparable mechanical strengths to OPC. The parameters evolved in the preparation of the clinker shave been optimized, such as these lection of raw materials (including mineralizers and activators), clinkering conditions and scaled-up methodology. Finally, the clinker was characterized through laboratory X-ray powder diffraction in combination with the Rietveld methodology. Cement nomenclature: C=CaO, S=SiO2, A=Al2O3, s=SO3, C2S= belite, C3S= alite, C4A3s=ye’elimite, C4AF=ferrite, C3A=tricalciumaluminate, Cs=anhydrite.
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Book of Abstracts CPSSC 16 Challenges and Prospects for Solid State Chemistry
Book of Abstracts CHALLENGES AND PROSPECTS FOR SOLID STATE CHEMISTRY University of Sevilla, 9 and 10 September 2016 SUPPORTED BY
CHALLENGES AND PROSPECTS FOR SOLID STATE CHEMISTRY This Discussion Meeting of the EuCheMS Division of Solid State and Materials Chemistry is focused on the latest developments in synthesis, properties, and structural investigations of solids. The meeting has been held just before the 6th EuCheMS Congress, 11-15 September (euchemsseville2016.eu/). Topics included: Frontiers of solid materials synthesis - FSM Structural advances through new methodology – SAM Solid state chemistry and applications - SSC Rationales for functional materials synthesis - RFM The conference includes plenary invited talks and poster presentations. ORGANIZING COMMITTEE Paul Attfield, University of Edinburgh Alfonso Caballero, University of Seville and ICMS-CSIC Martin Jansen, MPI Stuttgart Antoine Maignan, University of Caen Emilio Moran, Complutense University Madrid Jose Antonio Odriozola, University of Seville and ICMS-CSIC
CHALLENGES AND PROSPECTS FOR SOLID STATE CHEMISTRY University of Sevilla, 9 and 10 September 2016 Program Friday, 9 September 2016 09:00 - 09:30 Registration 09:30 - 10:00 Opening Remarks Prof. José Antonio Odriozola, Organizing Committee Prof. Pilar Malet Maenner, Dean of the Chemistry Department Prof. Martin Jansen, Chair of Division Frontiers of solid materials synthesis Chair: Maria Gracia Francesconi 10:00 - 10:50 Ullrich Haussermann, Stockholm University “Hydrogen incorporation in Zintl phases and transition metal oxides– new environments for the lightest element in the solid state” 10:50 - 11:30 COFFEE BREAK Chair: Alfonso Caballero Martínez 11:30 - 12:20 Andrei Shevelkov, Moscow State University “Back to the Iron Age: Structure and properties of iron compounds with strong electron correlations” 12:20 - 13:10 Amparo Fuertes, ICMAB Barcelona “New developments in the chemistry of oxynitride materials” 13:10 - 15:00 LUNCH Structural advances through new methodology Chair: Paul Attfield 15:00 - 15:50 Florence Babonneau, UMPC Paris "Solid-state NMR characterization of organic-inorganic materials: some recent advances" 15:50 - 16:50 COFFEE BREAK AND POSTER SESSION Chair: Wolfgang Bensch 16:50 - 17:40 Thierry Epicier, INSA Lyon “Life materials chemistry at the nano scale in environmental transmission electron microscopy”
17:40 - 18:30 Andrew Goodwin, Oxford University “Local symmetry and hidden order” Saturday, 10 September 2016 Solid state chemistry and applications Chair: Colin Greaves 10:00 - 10:50 Barbara Albert, TU Darmstadt “Complexity in borides: exotic solids or useful materials?” 10:50 - 11:40 Clare Grey, Cambridge University “Challenges for rechargeable batteries - new characterisation approaches and new chemistries” 11:40 - 12:20 COFFEE BREAK Chair: Antoine Maignan 12:20 - 13:10 Teofilo Rojo, CIC energiGUNE “Towards all solid state batteries” 13:10 - 15:00 LUNCH Rationales for functional materials synthesis Chair: Edmund Cussen 15:00 - 15:50 Claudia Felser, MPI-CPS Dresden “Topology – from the materials perspective” 15:50 - 16:40 Maarit Karpinnen, Aalto University “Layer-engineering of novel functional oxide materials” 16:40 - 17:10 COFFEE BREAK Chair: Emilio Moran 17:10 - 18:00 Joao Rocha, Aveiro University ”Microporous lanthanide silicates and coordination polymers for optical sensing and nanothermometry” 18:00 - 18:30 Quo vadimi? Panel and audience: Concluding discussion
INDEX New Double Cation Ordering in High Pressure Double Perovskites FSM1 A.M. Arévalo-López, E. Solana-Madruga, A.J. Dos Santos-García, R. SáezPuche, J.P. Attfield Uncommon morphological shapes of graphene: 3D graphenes FSM2 A. Benítez de la Torre, C. Hernández Rentero Structural and orbital orders in Ga-V oxide spinels FSM3 A.J. Browne, J.P. Attfield Hydrides of CrB-structure type Zintl phases – An in situ investigation FSM4 H. Auer, H. Kohlmann Microcrystalline calcium phosphate synthesis in non-aqueous medium FSM5 M. Kuzina, D. Larionov, V. Putlyaev Towards All Solid State Batteries FSM6 T. Rojo Conversion reactions of binary of ternary chalcogenides FSM7 S. Rommel, S. Haumann, F. Pielnhofer, A. S. Tragl, F. Bachhuber, J. Rothballer, W. Yan, P. Peter, A. Krach, A. Furtner, R. Weihrich The parent Li(OH)FeSe phase of lithium iron hydroxide selenide superconductors FSM8 D.N. Woodruff, F. Schild, C.V. Topping, S.J. Cassidy, J.N. Blandy, S.J. Blundell, A.L. Thompson, S.J. Clarke Microstructural Flexibility and Magnetic Structure of SbxV1-xO2 (0<x<0.5) Solid Solution SAM1 A.R. Landa-Cánovas, P. Vilanova-Martínez, F. Agulló-Rueda, J. HernándezVelasco Functionalized Gold Nanoparticles as Platforms for Ligand-ReceptorInteractions SAM2 F. Machka, E. Pouokam, M. Diener, M.S. Wickleder Synthesis and Characterization of Rare Earth doped ZrO2 Nanoparticles SAM3 A.S. Schulze, M.S. Wickleder Orbital Dinner model for Spin-Glass State in Y2Mo2O7 SAM4 P.M.M. Thygesent, J.A.M. Paddison, R. Zhang, K.A. Beyer, K.W. Chapman, H.Y. Playford, M.G. Tucker, D.A. Keen, M.A. Hayward, A.L. Goodwin
Efficient UV-photocatalytic activity of ZnO and Ag/ZnO synthesized by a facile method SSC28 C. Jaramillo-Páez, J.A. Navío*, M.C. Hidalgo, M. Macías Solid solutions of layered tetrel antimony chalcogenides SSC29 R. Schlegel, S. Schwarzmüller, J. Barnes, H. Hölzig, O. Oeckler Disorder-phonon coupling in crystal-like aperiodic solids SSC30 A. Overy, A. Cairns, M. Cliffe, A. Simonov, P. Chater, M. Tucker, A. Goodwin Perturbation of the Verwey structure of Fe3O4 SSC31 E. Pachoud, G. Perversi, J. Cumby, J.P. Wright, J.P. Attfield Mixed ionic-electronic conductors based on lanthanum molybdates SSC32 J.M. Porras-Vázquez, L. dos Santos-Gómez, C. Frontera, J. Canales-Vázquez, D. Marrero-López, E. Ramírez-Losilla Magnesium secondary battery: New electrolytes and cathode materials SSC33 E. Anger, I. Dez, A.C. Gaumont, V. Pralong Synthesis, Physico-chemical and Electrochemical Characterizations of Na4VO(PO4)2 as Cathode Material for Na-ion Batteries SSC34 W. Deriouche, M. Freire, N. Amdouni, A. Maignan, V. Pralong An active Li-Mn-O compound for high energy density Li-ion batteries SSC35 M. Freire, N.V. Kosova, C. Jordy, D. Chateigner, O.I. Lebedev, A. Maignan, V. Pralong Fe[HO3PCH(OH)CO2]·2,5H2O and doped metal derivates: photocatalytic properties SSC36 I.R. Salcedo, M. Bazaga-García, R.M.P. Colodrero, A.S. Albean, P.OliveraPastor, A. Cabeza Obtainment of polyethyleneimine modified ZnO nanoparticles for bioanalytical applications SSC37 M. Shiriaev, J. Young Jeong, B. Hyun Chung, A. Baranov Insertion of diols into a layered niobate SSC38 C.I. Thomas, M. Stenholm, M.J. Karppinen Effect of preparation pH on Bismuth Titanate materials with high visible light photocatalytic activity SSC39 P. Zambrano, J.A. Navío, M.C.Hidalgo Synthesis and scale-up of non-active and active Belite-AliteYe’elimite Clinker (BAY) SSC40 J.D. Zea-García, M.A.G. Aranda, A.G. De la Torre, I. Santacruz New representatives and physical properties of 3d-5d double perovskites RFM1
Abstracts
CPSSC16: Challenges and Prospects for Solid State Chemistry, September 9-10 2016, Seville, Spain SSC - 40