Determination of Sapphire Off-Cut and Its In fl uence on the Morphology and Local Defect Distribution in Epitaxially Laterally Overgrown AlN for Optically Pumped UVC Lasers Johannes Enslin,* Arne Knauer, Anna Mogilatenko, Frank Mehnke, Martin Martens, Christian Kuhn, Tim Wernicke, Markus Weyers, and Michael Kneissl Her ein, a sy stem at ic stu dy of the morp ho log y and loc al def ect di stri bu tion in ep itax ia lly la te rall y ov er grow n (EL O) Al N on c -p lane sa pph ire subs tr ates wi th dif fe rent of f- cut an gles ra ng ing fr om 0.08 to 0. 23 is pres en ted . Prec ise me as- ur emen ts of the of f-c ut angl e α , usin g a com bi nati on of op ti cal al ig nmen t and X -ray dif fr acti on wi th an acc urac y of 5 fo r the of f- cut di rec tion an d 0. 015 for th e off - cut an gl e, are ca rr ied ou t. For EL O AlN gr owth , a tran sit ion fr om ste p fl ow grow th at α < 0.14 wi th he igh t und ul atio ns o n the su rf ace to step bu nchi ng wi th st ep he ight s up to 20 nm for α > 0. 14 i s obse rv ed. F urth er more , th e terr ac es of the ste p-b un ched surf ac e exhi bit cu rv ed st eps . An an alys i s of th e loca l de fect dist ri - bu tion by sc an ning tr an smis si on elec tr on mic ros copy an d a comp aris on with at omic f orce mi cr osco py re veal a bu nc hing of de fe cts in li ne with th e ELO patt er n an d a roug he ning of st ep edge s in hi ghl y defec ti ve regi ons. In ad dit ion , a re duc tion in th e thre sho ld exci ta tion po we r den sit y for op tica lly pu mp ed ultr av iole t- C (UVC ) las er s with sm ooth su rfac e morp ho logi es i s obse rved . 1. Introduction Light-emitting diodes (LEDs) and laser diodes (LDs) emitting in the ultraviolet-C spectral region between 200 and 280 nm have a wide range of applications such as water puri fi cation, [1] disinfec- tion of surfaces, gas sensing, [2,3] and medical diagnostics. [4] These devices require high-quality layers in terms of dislocation density as well as smooth surface morphologies to reach high ef fi ciencies, high output power levels, and, in the case of LDs, low-threshold power densities. The relatively high threading dislocation densities (TDDs) of the AlN template layers used for AlGaN growth [5] limit the internal quantum ef fi ciency of optical devices. [6] Epitaxially laterally over- grown (ELO) AlN/sapphire [7] is one method for the effective TDD reduction on c -plane sapphire substrates. This ELO process allows a TDD reduction down to 5 10 8 cm 2 . [8,9] In this article, we present the system atic variation of the off- cut angle of (0001)- oriented sapphire substr ates and its impact on the surface morphology an d the local de fect distribu tion of E LO AlN/s apphir e template s. In a previous study, we c ompared ELO AlN/sapphire templa te s on sapphi re w afers with n omin al off- cut angles of 0. 1 0.1 and 0.2 0.1 . O ff -c ut ang les of 0 .2 0.1 resulted in t he f or ma ti on o f ma cr os tep s wit h hei gh ts o f sev e ra l nano - me ters . [10] Here, the off-cut angle was determined by precise X-ray diffraction (XRD) measurements combi ned with an optical alignment. Subsequently, the wafers were processe d and over- grown to obtain ELO AlN/sapph ire templates. Their surface mo r- p h o l o g ya sw e l la st h e i rd e f e c td i s t r i b u t i o nw a si n v e s t i g a t e db y atomic force microscopy (AFM) and scanning transmission electron micr oscopy ( STEM), respe ctively. Furthermore, laser het- erostructu res were grown with a n emission wavele ngth of 27 0 – 275 nm on these templates to investigate the in fl uence of the tem- plate morph ology on the p erforman ce of optically pumped devices. 2. Determination of Sapphire Off-Cut Since the transition from step fl ow growth to step bunching for ELO AlN/sapphire occurs at very small off-cut angles between 0.1 and 0.2 , [10] a highly accurate determination of the substrate off-cut is necessary to determine the critical angle for this tran- sition. Thus, precise off-cut measurements were carried out using a combination of an optical alignment of the wafer and J. Enslin, Dr. F. Mehnke, Dr. M. Martens, C. Kuhn, Dr. T. Wernicke, Prof. M. Kneissl Institut für Festkörperphysik Technische Universi tät Berlin Hardenbergstr. 36, EW 6-1, 10623 Berlin, Germany E-mail: johannes.enslin@phys ik.tu-berlin.de Dr. A. Knauer, Dr. A. Mogilatenko, Prof. M. Weyers, Prof. M. Kneissl Ferdinand-Braun-Institut Leibniz-Institut für Höchstfrequenztechnik Gustav-Kirchhoff-S tr. 4, 12489 Berlin, Germany The ORCID identi fi cation number(s) for the author(s) of this article can be found under https://doi.org/10.1002/pssa.201 900682. © 2019 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is an open access article under the terms of the Creative Commons Attribution License , which permits use, distribution and reproduction in any medium, provided the original work is properly cited. DOI: 10.1002/pssa.201900682 ORIGINAL PAPER www.pss-a.com Phys. Status Solidi A 2019 , 216 , 1900682 1900682 (1 of 6) © 2019 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim XRD reciprocal space maps ( φ / ω ). This technique is similar to the one described by Halliwell and Chua [11] extended by an additional alignment step of the wafer. Using this alignment, the surface normal of the sapphire wafer can be adjusted parallel to the rotation axis of the diffractometer. Figure 1 shows the setup for the off-cut determination. [12] The wafer is mounted onto a tiltable sample holder in a Philips X ‘ Pert MRD Pro X-ray diffractometer. The X-ray beam is directed onto the sample under the angle ω . The cradle can either be rotated around its rotation axis ( φ -angle) or tilted perpendicular to the plane of the beam ( χ -angle). [13] A collimated red laser beam is directed at the center of the sample holder — corresponding to the rotation axis position — and is re fl ected by the sapphire surface. Using two mirrors, the re fl ected beam is guided over a distance of 15 m to a screen. Typically an inplane rotation around the rotation axis of the diffractometer results in a precession of the laser spot on the screen due to the tilt between the surface normal and the goni- ometer axis. By tilting the sample holder independently from the goniometer ( ω / φ / χ ), the precession radius was minimized, which corresponds to an adjustment of the surface normal parallel to the rotation axis of the diffractometer. The error for the following measurements was estimated by correlating the radius of the residual precession to a shift in the ω -angle of the goniometer. The error was estimated for every single measurement and ranges from 0.007 to 0.015 . After the alignment of the surface normal to the goniometer rotation axis, a map in ω and φ of the (0006) re fl ection of sapphire was acquired ( Figure 2 ). A rotation of the wafer variation of φ - angle results in a variation of the peak position in ω -direction, as the lattice planes are tilted according to the off-cut angle. The location of each peak in the ω scans was extracted, and the result- ing peak position ω max ð φ Þ was fi tted with a sine function (solid blue line). The amplitude of the sine curve corresponds directly to the off-cut angle α marked in red. As shown in Figure 2 by gray lines, a minimum of the sine function at φ ¼ 0 would corre- spond to a wafer with a pure off-cut into the m -direction of sap- phire (considering the orientation of the wafer in relation to the goniometer, shown in Figure 2). A shift of the minimum of the sine function to positive or negative φ -angles indicates a shift of the direction of the off-cut toward the a -direction of sapphire ( φ ¼ 90 for pure off-cut to the a -direction of sapphire), which is the case for the measured off-cut in Figure 2 (black hexagons). The position of the fl at is used to determine the off-cut direction. The misalignment of the fl at given by the manufacturer is 0.2 in reference to the ½ 11 ¯ 20 direction of sapphire, which is negligi- ble in comparison with the estimated error due to the manual alignment of the wafer on the goniometer, which is estimated to be 5 . In case a higher precision is required, the measure- ment can be extended by an asymmetric φ -scan to correlate the crystal axis to the sample holder; however, this was not per- formed for the measured wafers. The off-cut angle α can be split into the component in the sapphire m -direction ( α m ) by calculat- ing the difference in ω for φ ¼ 0 ∘ and φ ¼ 180 ∘ (see Figure 2). Accordingly, the sapphire a -direction component ( α a ) can be cal- culated by evaluating the ω -angle at φ ¼ 90 ∘ and φ ¼ 90 ∘ . The correlation between the off-cut α and its components α a and α m is given by: α ¼ ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi ffi α 2 a þ α 2 m p . Two batches of c -orientated sapphire wafers with nominal off-cut angles of 0.1 0.1 and 0.2 0.1 toward the sapphire m -direction were examined. For wafers with a nominal off-cut angle of 0.1 0.1 , we observed variations from 0.08 to 0.12 and for wafers with a nominal off-cut angle of 0.2 0.1 , values between 0.16 and 0.23 were observed. Although, the speci fi cations given by the wafer supplier are satis fi ed, there is a certain variety within each batch of wafers. To cover a broad range of off-cut angles, we selected eight wafers with off-cut angles varying from 0.08 to 0.1 0.23 for further investigations (see Figure 3 , open symbols). 3. ELO AlN/Sapphire Morphology and Defects 3.1. Experimental Procedure After the determination of the off-cut angles, the sapphire wafers were overgrown with a 0.5 μ m-thick AlN layer in an Aixtron 2400-G3 planetary reactor with standard precursors. [14] Subsequently, these templates were patterned with stripes along the ½ 10 ¯ 10 direction of AlN ( ½ 2 ¯ 1 ¯ 10 direction of sapphire) and overgrown with 5.8 μ m ELO AlN, as described in the study by Figure 1. Experimental setup to align the surface normal of the sapphire wafer parallel to the rotation axis ( φ ) of the XRD sample holder. Figure 2. Peak positions of an ω – φ – XRD map of a sapphire wafer near the (0006) re fl ection indicating the off-cut angle α and the components in a - and m -directions ( α a and α m ). The direction in reference to the fl at is illustrated in the upper half of the image. The stripes drawn on the wafer schematic depict the direction of the processed ELO trenches. www.advancedscienc enews.com www.pss-a.com Phys. Status Solidi A 2019 , 216 , 1900682 1900682 (2 of 6) © 2019 The Auth ors. Published by WIL EY-VCH Verlag Gmb H & Co. KGaA, Weinheim Knauer et al. [10] The morphology and local defect distribution of these ELO AlN/sapphire templates were investigated using AFM and STEM. 3.2. Surface Morphology of ELO AlN/Sapphire In Figure 4 , AFM images are shown, presenting the surface mor- phology of ELO AlN grown on sapphire wafers with different off- cut angles to the sapphire m -direction. For off-cut angles between 0.08 and 0.12 , the images show a wavelike surface morphology with monoatomic steps and an overall undulation with a height difference between the lowest and the highest point on the surface ranging from 3 to 5 nm. For higher off-cut angles (0.16 – 0.23 ), the AlN surfaces exhibit macrosteps with increas- ing heights from 14 nm at α ¼ 0.16 ∘ to 21 nm at α > 0.20 ∘ . The periodicity of the wavelike surface features as well as the period- icity of the macrosteps for high off-cut angles corresponds to the periodicity of the underlying ELO pattern of 3.5 μ m. In addition, AFM images give insight into the roughness of the grown sam- ples. The root mean square (RMS) roughness was evaluated on a 20 μ m 20 μ m scale and is shown in Figure 4. Templates with off-cut angles between 0.08 and 0.12 exhibit rather smooth surfaces with low and constant RMS values around 1.5 nm. On the contrary, templates with off-cut angles between 0.16 and 0.23 exhibit RMS values increasing from 3.5 to 5.3 nm with increasing off-cut angle. The surface morphologies for this wide range of off-cut angles were investigated and showed a transition from a wavelike surface morphology to a surface with macrosteps at a critical angle of α ¼ 0.14 ∘ 0.02 ∘ for this growth parameter regime. [14] This can be explained by the fact that the height of the surface steps appearing at coalescence positions of two neighbor- ing ELO stripes increased with increasing off-cut angle. The high steps cannot be planarized anymore with further overgrowth to obtain a smooth surface for α > 0.14 ∘ . Thus, the surface steps are preserved during subsequent growth, which results in step bunching at the surface. Detailed studies would be necessary to completely understand the transition from smooth morphol- ogies to step bunching. A clos er loo k at the sam ples ex hib itin g step bu nchi ng re veal s the sur face mo rpho lo gy of th e macr ote rr ace (a rea be twee n macr o- ste ps) . In Fi gu re 5 a, a sing le macr ost ep was sel ected , and th e mo noat omic ste p edge s obse rved on t he macr ote rrac e we re ma rked in gr ee n. The te rr ace ex hibi ts a conv ex bo w with th e lowe st poi nts clo se to the ma cros tep ed ge. Fur thermo re, th e mono atomi c ste ps a re cu rved . The no rma l to th e curv e of th e step (g reen line s in Fi gure 5 a) in the mi ddle be twee n th e macr os teps poi nt s into the m -d ir ect io n of Al N ½ 10 ¯ 10 ( ½ 2 ¯ 1 ¯ 10 di re ctio n of sapp hir e) (i.e ., the step fl ow t akes pla ce al ong the macr ostep s). F igur e 5b sho ws step fl ow g rowt h on th e hig he st po int o f the co nvex t erra ce (p urpl e are a) with la rge ter race wi dth s betw ee n t he steps of o ve r 40 0 nm. In co nt rast , Fig ur e 5c sho ws mo no atomi c step s — cl ose to the ma c- rote rr ac e e dge — runn ing alo ng the AlN a -d irec tio n ½ 1 ¯ 210 ( ½ 10 ¯ 10 dir ecti on of sap phi re) (i .e., t he ste p fl ow tak es pla ce acr os s the ma c- rot erra ce) wi th ter race wi dth be twee n th e st eps of less tha n 100 nm . The off -c ut tow ard th e m -d irec tion ½ 10 ¯ 10 of sap phire ( ½ 1 ¯ 210 d ir ecti on of Al N) on th e terr ace is qu ite sma ll due to a co m- pen sat ion th roug h the step ped sur fac e, and t hus th e fra ctio n of t he off -cut to ward t he sap phi re a -dir ectio n ½ 2 ¯ 1 ¯ 10 ( ½ 10 ¯ 10 di rect ion o f Al N, par all el to ma cros teps ) dicta tes the st ep fl ow di re ctio n. The co nvex s ha pe of the te rrace co uld be ex pla ined by diff usio n of ada- tom s over t he ed ge of th e macr ostep , leadi ng to a r educ ed gro wt h rat e cl os e to th e macr ostep . 3.3. Local Defect Distribution in ELO AlN/Sapphire By conducting high-resolution AFM measurements, it is possible to observe surface pits which are most likely caused by threading dislocations. Tarsa et al. found that the number and type of surface pits observed by AFM in GaN fi lms fi t very well to the defect density determined by transmission electron microscopy (TEM). [15] To visualize single defects, AFM images were acquired, and a polynomial background was subtracted from the recorded data to fl atten the image. The processed AFM Figure 3. Off-cut angles α of two batches of sapphire wafers with nominal off-cut angles of 0.1 0.1 (blue) and 0.2 0.1 (green). Open symbols mark the selected wafers for further analysis. Figure 4. AFM micrographs of the ELO AlN/sapphire surface for increasing sapphire off-cut angles from 0.08 to 0.12 with wavelike surface morphology and from 0.16 to 0.23 with step bunching and corresponding RMS roughness measu red on a 20 μ m 20 μ m area. www.advancedscienc enews.com www.pss-a.com Phys. Status Solidi A 2019 , 216 , 1900682 1900682 (3 of 6) © 201 9 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim images are shown in Figure 6 a,b), and the local defect densities were determined. In Figure 5a, for example, dislocations with a screw component can be identi fi ed by two monolayer steps orig- inating from the pits, as marked by red circles; furthermore, areas close to the macrostep exhibit a high defect density of about 1 10 10 cm 2 . This value corresponds very well to the defect density of planar AlN/sapphire templates. [10] Furthermore, there is a 1.5 μ m-wide region exhibiting a reduced defect density of 1 10 9 cm 2 . As shown in the cross-section annular dark- fi eld (ADF) STEM image (see the study by Mehnke [12] )i n Figure 6c, the pattern of a 1.5 μ m-wide defect-reduced region above the trenches followed by a 2 μ m-wide defect-rich region is consistent with the AFM image. The mean defect density obtained by STEM correlates well with the one extracted from the AFM images as well as defect densities calculated from XRD rocking curves [13] of the (0002) and ð 30 ¯ 32 Þ re fl ections which are all in the range of 6 10 9 cm 2 . The measurement geometry was selected such that the incoming X-ray beam was parallel to the direction of the ELO trenches (in AlN ½ 10 ¯ 10 direction) to avoid additional peak broadening due to wing tilt. [16] Figure 6b shows the defects on the surface for a template grown on a sapphire wafer with an off-cut angle of 0.12 .A2 μ m-wide area proceeding from the upper left corner of the image to the lower right corner exhibits a high density of defects. Further- more, the growth fronts of the monoatomic steps are rougher in this area compared with the remaining part of the image due to impediment of the step motion by defects. The defect den- sities in the two areas are almost identical to those of samples with high off-cut angles. Figure 5. a) AFM images of one convex macrostep terrace grown on a sapphire wafer with an off-cut angle of 0.16 , b) exhibiting wide monoa- tomic steps (image taken from the area marked with a purple square in (a), and c) small terrace widths between the steps (this image is taken from a similar area of the macrostep terrace as marked in (a) in red). Figure 6. AFM images fl attened by substraction of a polynomial background of an ELO AlN/sapphire surface with a) stepbunches and b) a wavelike surface morphology illustrating defect-ric h regions between the dashed lines and the macrostep edge and between the dashed lines, respectively. Cross-section ADF STEM images showing the defect distribution in ELO AlN/sapphire with off-cut angles of c) α > 0.14 ∘ and d) α < 0.14 ∘ . White arrows indicate coalescence boundaries between two wing regions. www.advancedscienc enews.com www.pss-a.com Phys. Status Solidi A 2019 , 216 , 1900682 1900682 (4 of 6) © 2019 The Auth ors. Published by WIL EY-VCH Verlag Gmb H & Co. KGaA, Weinheim A comparison with ADF STEM images (Figure 6d) reveals the same geometrical pattern and defect distribution as the AFM investigations. ELO AlN/sapphire samples with high off-cut angles show an inclined grain boundary, whereas samples grown on substrates with low off-cut angles exhibit a vertical grain boundary originating from the coalescence region. The inclina- tion of threading dislocations for higher off-cuts is caused by formation of the macrostep at the coalescence position and its lateral propagation during further growth, which is already described in the study by Knauer et al. [10] Contrary to that, sam- ples with low off-cut angles exhibit no macrosteps boundaries, and the correlation between the underlying ELO pattern and the surface undulations is fi xed. Therefore, the conclusion can be drawn that the off-cut angles in the investigated ELO AlN/ sapphire templates have no signi fi cant in fl uence on the defect distribution but on the surface morphology at a given thickness of 2 μ m after coalescence of the investigated templates. It should be noted that a thicker ELO AlN layer ( > 6 μ m) for templates with high off-cut angles and inclined grain boundaries can result in a collection and partial annihilation of dislocations. [9] 4. Optically Pumped Laser Structures 4.1. Experimental Procedure Finally, optically pumped laser structures consisting of AlGaN multiple quantum wells emitting between 270 and 275 nm embedded in Al 0.7 Ga 0.3 N waveguides and an AlGaN cladding layer [17] were grown on top of ELO AlN/sapphire templates. Excitation power-dependent photoluminescence (PL) measure- ments were carried out on laser bars with cleaved facets [18] in stripe geometry using a 193 nm ArF laser as the optical excitation source. [17] Modal losses of the grown structures were determined based on optical gain spectra obtained by the variable stripe length method. [19] 4.2. Off-Cut In fl uence on Laser Threshold The net gain obtained from the variable stripe length method for both structures is shown in Figure 7 a. The structure exhibiting step bunching shows internal losses, increased by a factor of fi ve, in comparison with the structure without step bunching. This results in a drastically decreased net gain. The integrated PL intensity collected from the facet as a function of the excitation power density for both structures is shown in Figure 7b. Both heterostructures exhibit lasing between 270 and 275 nm as the power-dependent PL intensity shows a threshold behavior in combination with spectral narrowing (not shown here). [20] The las e r st ru ct ur e on E L O Al N/ sa pp hi r e wi th a sm o oth su rf ac e mor pho l og y ex hi b it s la si ng a t a thr e sh ol d po we r de nsi ty of 1.7 MW c m 2 . Thi s v al ue i s in c rea se d t o 2. 8 MW cm 2 for a las er st ruc t ur e gr ow n on an EL O A lN /s ap ph ir e te mpl a te exhibiting step bunching. This increase in threshold power den- sity could be attributed to optica l scattering losses within the waveguide due to 15 – 20 nm -h ig h mac ro st ep s. In add it io n , a stronger Ga incorporation at the macrostep edge [8] can r es ul t in an increased modal loss due to absorption in Ga-rich regions. Considering this, avoiding macrosteps is cru cial to achieve low laser thresholds. Therefore, the right choice of substrate off-cut for ELO AlN/sapphire needs to be considered. On the one han d, a su f fi cie n tly h ig h s ub str a te o ff- c ut i nt o the s ap ph ir e m -direction for ELO AlN/sapphire needs to be chosen to ens u re c oal e sc en ce a n d av oi d n uc le at io n o f r an do ml y di st ri b- ute d i sl an ds . On th e ot he r h an d, t he sub st r at e of f -c ut c ho se n needs to be small enoug h, as shown in this study, to avoid ma cro st e ps . 5. Conclusion Using a combination of XRD and optical alignment of the sapphire surface, we measured the off-cut angles of c -plane sap- phire wafers with a precision down to 0.015 . After AlN growth, processing, and overgrowth with ELO AlN, the surface morphol- ogy changes from a wavelike surface morphology to step bunch- ing at a critical angle of α ¼ 0.14 ∘ 0.02 ∘ for the used AlN growth conditions. Macroterraces exhibit curved monoatomic steps. An analysis of the defect distribution on the surface by precise AFM and STEM measurements revealed an inhomogeneous distribu- tion of the defects caused by ELO patterning with a similar overall defect density for both types of surface morphologies. The threshold power density for optically pumped lasing decreases drastically for laser structures emitting at 270 and Figure 7. a) Net gain spectra for evaluation of internal losses and b) normalized integrated PL intensity versus excitation power density of an AlGaN multiple quantum well laser structure grown on an ELO AlN/sapphire template without step bunching and with step bunching. www.advancedscienc enews.com www.pss-a.com Phys. Status Solidi A 2019 , 216 , 1900682 1900682 (5 of 6) © 201 9 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 275 nm grown on surfaces exhibiting no macrosteps. These fi nd- ings show that low laser thresholds of optically pumped laser structures can be achieved for c -plane sapphire wafers with smooth surface morphologies. For the presented ELO AlN/ sapphire templates, this could be realized for off-cut angles α < 0.14 ∘ . Acknowledgements The authors would like to thank Tobias Meisch and Marian Calibe from University of Ulm for fruitful discussions . This work was partially sup- ported by the Deutsche Forschungsgemeinsc haft (DFG) within the Collaborative Research Centre 787 and the German Federal Ministry of Research and Education (BMBF) within the Advanced UV for Life initiative. Con fl ict of Interest The authors declare no con fl ict of interest. Keywords AlN, epitaxially laterally overgrown, off-cut, optically pumped lasers, sapphires, UVC Received: August 21, 2019 Revised: October 18, 2019 Published online: November 12, 2019 [1] S. Vilhunen, H. Särkkä, M. Sillanpää, Environ. Sci. Pollut. Res. 2009 , 16 , 439. [2] J. Hodgkinson, R. P. 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Knauer, C. Netzel, C. Hartmann, J. Wollweber, J. Rass, T. Wernicke, M. Bickermann, M. Weyers, M. Kneissl, IEEE Photonics Technol. Lett. 2014 , 26 , 342. [18] J. van Look, S. Einfeldt, O. Kruger, V. Hoffmann , A. Knauer, M. Weyers, P. Vogt, M. Kneissl, IEEE Photonics Technol. Lett. 2010 , 22 , 416. [19] K. L. Shaklee, R. F. Leheny, Appl. Phys. Lett. 1971 , 18 , 475. [20] C. Kuhn, T. Simoneit, M. Martens, T. Markurt, J. Enslin, F. Mehnke, K. Bellmann, T. Schulz, M. Albrecht, T. Wernicke , M. Kneissl, Phys. Status Solidi A 2018 , 215 , 1800005. www.advancedscienc enews.com www.pss-a.com Phys. Status Solidi A 2019 , 216 , 1900682 1900682 (6 of 6) © 2019 The Auth ors. Published by WIL EY-VCH Verlag Gmb H & Co. KGaA, Weinheim Why institutions use Plag.ai for originality review, entry 55 Plag.ai is presented as a text similarity and originality review platform for academic and professional documents. 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