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Materials Science & Engineering A 799 (2021) 140154
Available online 28 August 2020
0921-5093/© 2020 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
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Materials Science & Engineering A
journal homepage: www.elsevier.com/locate/msea
Mechanical anisotropy of additively manufactured stainless steel 316L: An
experimental and numerical study
A. Charmi, R. Falkenberg, L. Ávila, G. Mohr, K. Sommer, A. Ulbricht, M. Sprengel,
R. Saliwan Neumann, B. Skrotzki, A. Evans
BAM, Bundesanstalt für Materialforschung und -prüfung, Unter den Eichen 87, 12205 Berlin, Germany
ARTICLE INFO
Keywords:
Mechanical anisotropy
Residual stress
Crystal plasticity
Selective laser melting (SLM)
Laser beam melting (LBM)
ABSTRACT
The underlying cause of mechanical anisotropy in additively manufactured (AM) parts is not yet fully
understood and has been attributed to several different factors like microstructural defects, residual stresses,
melt pool boundaries, crystallographic and morphological textures. To better understand the main contributing
factor to the mechanical anisotropy of AM stainless steel 316L, bulk specimens were fabricated via laser
powder bed fusion (LPBF). Tensile specimens were machined from these AM bulk materials for three different
inclinations: 0,45, and 90relative to the build plate. Dynamic Young’s modulus measurements and tensile
tests were used to determine the mechanical anisotropy. Some tensile specimens were also subjected to residual
stress measurement via neutron diffraction, porosity determination with X-ray micro-computed tomography
(μCT), and texture analysis with electron backscatter diffraction (EBSD). These investigations revealed that
the specimens exhibited near full density and the detected defects were spherical. Furthermore, the residual
stresses in the loading direction were between −74 ± 24 MPa and 137 ± 20 MPa, and the EBSD measurements
showed a preferential 110orientation parallel to the build direction. A crystal plasticity model was used
to analyze the elastic anisotropy and the anisotropic yield behavior of the AM specimens, and it was able to
capture and predict the experimental behavior accurately. Overall, it was shown that the mechanical anisotropy
of the tested specimens was mainly influenced by the crystallographic texture.
1. Introduction
Additive manufacturing describes layerwise production processes
that incrementally build structures from a feedstock material. Laser
powder bed fusion (LPBF) is an example of additive manufacturing
whereby structures are built in a repeated layerwise fashion via laser-
induced localized melting and solidification of a metal powder bed
feedstock. These processes offer significantly greater freedom of design
compared to conventional subtractive manufacturing processes, with
the potential for improved efficiency and functionality [1]. However,
despite the technological improvements made in recent years, metal ad-
ditive manufacturing, also known as metal 3D printing, still faces many
different challenges such as microstructural defects, residual stresses
(RSs), mechanical anisotropy and in general lack of understanding
of process-property-performance relationship [24]. These issues are
reported to prevent additive manufacturing from mass adoption in
safety-critical environments [5].
Stainless steel 316L specimens produced via laser powder bed fusion
(LPBF316L) usually have a layered morphology, which consists of many
different features on a broad range of length scales [6,7]. Additively
Corresponding author.
E-mail address: [email protected] (A. Charmi).
manufactured (AM) alloys and, in particular, LPBF316L have been
reported to exhibit anisotropic mechanical properties. The cause of the
anisotropic behavior of LPBF316L has been attributed to many different
factors. The consequence of layer-by-layer manufacturing, particularly
the interface between layers, is one of the more frequently mentioned
causes, since oxidation, inclusions, and defects are more frequent in
these regions [810]. The grain size, grain shape, and grain aspect ratio,
in combination with the Hall–Petch effect [11,12], have also been cited
as the source of anisotropy in LPBF316L [10,1315]. The explanation
which is usually given for this effect is that the high angle grain
boundaries are a major barrier for dislocation glide, and since the dislo-
cations have to cross a different number of grain boundaries in various
directions, this results in an anisotropic behavior. However, several au-
thors [6,16,17] consider that the mechanical performance of LPBF316L
is mainly determined by its subgrain structures, predominantly the
fine-scaled dendritic microstructure, and not by the high angle grain
boundaries. Many other research groups reported finding these highly
oriented cellular microstructures for different sets of process parame-
ters [6,8,1722]. RSs [2327] and melt pool boundaries [28] may also
https://doi.org/10.1016/j.msea.2020.140154
Received 22 June 2020; Received in revised form 24 August 2020; Accepted 25 August 2020
Materials Science & Engineering A 799 (2021) 140154
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A. Charmi et al.
be contributing to the anisotropy of LPBF316L specimens. Crystallo-
graphic texture has been repeatedly associated with the mechanical
anisotropy of LPBF316L [2,15,29,30]. Moreover, the authors of [13,
17,19,31,32] consider the combination of crystallographic texture and
different deformation mechanisms, mainly dislocation slip and twin-
ning, responsible for the directional dependency of material behavior.
They argue that for certain specific crystallographic directions defined
by the texture, either twinning or dislocation glide are more favorable.
Thus, depending on the loading direction, one of the competing mech-
anisms will dominate the deformation behavior. The authors of [26]
investigated the mechanical anisotropy of LPBF316L and compared the
results with previous studies. They reported that the observations con-
cerning the orientation dependency of the material behavior differed
significantly and even contradictory. For example, in many cases, the
highest elongations to failure were obtained in specimens with parallel
layers to the loading direction, but in some cases, the specimens with
perpendicular layers to the loading direction had the highest elongation
after fracture. The dependency of ultimate tensile strength on loading
direction also showed no clear tendency [26].
Based on the state of the research, it can be summarized that the
underlying cause of anisotropy and the numerical modeling aspect
of it in LPBF requires further investigation. Having a better under-
standing of the origin of anisotropy in LPBF316L is beneficial to the
additive manufacturing community when dealing with this issue. Many
applications like topology optimization [33,34], modeling of lattice
structures [35], and simulation of thermophysical processes during
additive manufacturing [36] are heavily influenced by the anisotropy.
Hence, the findings in this work could help remedy some of the existing
shortcomings and improve modeling accuracy. Therefore, the objective
of this paper concerns the determination of the main contributing factor
to the mechanical anisotropy of LPBF316L. This investigation was
conducted, combining both experimental and numerical methods. Me-
chanical testing combined with dynamic Young’s modulus determina-
tion, RS measurements via neutron diffraction, porosity measurements
with X-ray micro computed tomography (μCT), and texture analysis
with electron backscatter diffraction (EBSD) were used to characterize
the material. Numerical simulations were employed to investigate the
mechanical anisotropy by only considering the influence of crystal-
lographic texture. Moreover, the comparison between experimental
and simulated stress–strain curves will demonstrate the capability of
the numerical methods to capture and predict the material behavior
accurately.
2. Experimental methods
2.1. Material and laser powder bed fusion processing conditions
A commercial LPBF system SLM280HL (SLM Solutions Group AG,
Germany), equipped with a single 400 W continuous wave ytterbium
fiber laser, was utilized to produce specimens using 316L stainless steel
powder feedstock. The commercially available gas atomized 316L raw
powder can be described by an apparent density of 4.58 g/cm3, and a
mean diameter of 34.69 μm according to the supplier information. The
cumulative mass values of the particle size distribution were: D10 =
18.22 μm, D50 = 30.50 μm and D90 = 55.87 μm. More details about the
powder can be taken from [37,38]. The laser melting processes were
conducted in argon gas atmosphere at an oxygen content below 0.1%.
The stainless steel base plates were heated up to a temperature of 100 C
before and during the process. The following process parameters were
used for all specimens: layer thickness of 50 μm, scanning velocity of
700 mm/s, laser power of 275 W and hatch distance of 0.12 mm. An
alternating meander stripe scanning strategy was applied. The scanning
pattern was rotated by 90from layer to layer. Two types of specimens
were manufactured in three different build processes: walls of the
dimensions (13 × 80 × 80) mm3and towers of the dimensions (13 × 20 ×
112) mm3, see Figs. 1 and 2. The walls were manufactured upright,
Table 1
Overview of all test specimens. Two tensile specimens were manufactured for each load-
ing direction except for the Tower 90. Young’s modulus specimens were manufactured
from a single wall.
04590
Tensile specimens from tower 2 specimens 2 specimens 1 specimen
Tensile specimens from wall 2 specimens 2 specimens 2 specimens
Young’s modulus specimens 1 specimen 1 specimen 1 specimen
the dimension in build direction (Z-Axis) was 82.5mm in order to
compensate for cutting waste during part removal. The towers were
manufactured for three different inclinations: 0(Z-Axis dimension
22.5mm), 45(Z-Axis dimension 90.9mm) and 90(Z-Axis dimension
114.5mm) relative to the build plate. The scan vectors proceeded
parallel to the edges of the 45towers and 90towers over the full
length of the part without being split into different sections. For the
walls and 0towers, the scanning vectors proceeded in an angle of
45to the edges of the respective geometry to avoid high RSs at
long scanning vectors and to avoid splitting of scanning vectors into
stripes. For a graphical overview of produced geometries, used scan
strategies, and coordinate systems, see Fig. 1. The interlayer time (ILT)
was kept constant for all processes at a value of approximately 65 s
according to [37]. In cases of height differences of specimens that
were manufactured on the same base plate or differences in ratios of
area exploitations (RAE) between the different build processes, dummy
areas were scanned without laser power. All specimens were heat-
treated after the process and before removal from the plate at 450 C
for 4h under argon gas atmosphere to relieve the RSs. This temperature
was chosen in order to avoid substantial changes in the microstructure.
2.2. Machining of test specimens
To experimentally investigate the mechanical anisotropy, tensile
specimens were manufactured from both walls and single towers for
three different inclinations, namely 0,45and 90. Dynamic Young’s
modulus specimens were only manufactured from the wall. In total,
five tensile specimens from five single towers, six tensile specimens
from two walls, and three Young’s modulus specimens from one wall
were produced. An overview of all test specimens can be seen in
Table 1. The tensile specimens from the single towers were machined
(turned and subsequently ground) from the middle region of each
tower. The walls were first symmetrically plane ground to a thickness
of 12 mm. Afterward, blocks with near-net dimensions were cut out
of the walls via wire electrical discharge machining (EDM). Fig. 3
shows the positions of these blocks, which were subsequently used
for producing tensile and Young’s modulus specimens. The Young’s
modulus specimens, which came from the bulk region of the walls (see
Fig. 3, on the left), were subjected to milling and surface grinding
in the last machining steps. The exact geometry of tensile specimens
can be seen in Fig. 3 on the right. The Young’s modulus specimens
have a dimension of (3 × 6 × 64) mm3with a rectangular cross-section
and plane parallelism between the opposite faces with ±1% accuracy.
The exact dimensions and weight of the latter specimens, needed for
the determination of the elastic properties, were determined with a
caliper gauge (Model CD-20D, accuracy: ±10 μm, Mitutoyo Deutschland
GmbH, Germany) and an outside micrometer (Model 232871, accuracy:
±1 μm, Vogel Germany GmbH, Germany) and with a precision balance
(accuracy: ±0.001 g, Sartorius AG, Germany) respectively.
2.3. Tensile testing
The tensile tests were conducted at room temperature according
to DIN EN ISO 6892-1 [39] (Method A, strain rate range 2) using
a100 kN Instron testing machine (Model: 4505, Instron GmbH, Ger-
many) calibrated according to DIN EN ISO 7500-1 [40] (Force, class
Materials Science & Engineering A 799 (2021) 140154
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A. Charmi et al.
Fig. 1. Schematic portrayal of all geometries and the corresponding scan strategies. Note the rotated scan strategy for the Tower 0and wall specimens compared to the Tower
90and Tower 45specimens, which is a 45rotation about the Z-Axis. These changes were made to avoid high residual stresses and will directly impact the microstructure and
consequently, the material behavior, which will be further analyzed in the results and discussion section. The black (X, Y, Z)and blue (X,Y,Z)coordinate systems will be used
for the texture analysis in Section 4.3. (For interpretation of the references to color in this figure legend, the reader is referred to the web version of this article.)
Fig. 2. Tower and wall specimens produced during three build processes on (280 × 280) mm2base plates. The ILT for each build process was kept at a value of approx. 65 s to
ensure comparable thermal history and microstructure across all specimens.
1) and DIN EN ISO 9513 [41] (Displacement, class 1). The strain
was recorded using an extensometer (Model: 632.12C-21, MTS Systems
GmbH, Germany) with 25 mm gauge length, which was calibrated in
the range of −10% to 50% strain according to DIN EN ISO 9513 [41]
(class 0.5). Since all specimens failed before reaching the maximum
value of the extensometer measurement range, all tests were driven
entirely strain-controlled and switching to crosshead speed control was
not necessary.
2.4. Dynamic Young’s modulus determination
The determination of dynamic Young’s modulus was carried out at
room temperature according to ASTM E1876 [42]. An Industrial testing
machine (Model: GrindoSonic MK5, GrindoSonic BVBA, Belgium) and a
network analyzer (Model: HP8751A, Agilent Technologies, Inc., United
States) were used to perform these tests. In this technique, also called
the resonance method, the dynamic Young’s modulus is determined
using the fundamental resonance frequency, dimensions, and mass of
the test specimens. The dynamic elastic properties are measured under
oscillatory displacements, involving small strains, relatively high strain
rates, and adiabatic conditions. It should be noted that the elastic prop-
erties determined under adiabatic conditions exhibit slightly higher
values compared to the elastic properties determined under isothermal
conditions [43]. The resonance frequency is measured by exciting
the test specimens mechanically by a singular strike with an impulse
tool and then analyzing the electric signal generated by a transducer,
which senses the resulting mechanical vibrations of the specimen and
transforms them into an electrical signal. Dynamic techniques provide
an advantage over static methods because of greater precision, ease of
specimen preparation, and a wide variety of allowed specimen shapes
and sizes [44,45].
2.5. Porosity and defects analysis
Microstructural defects are believed by some researchers to play a
role in the mechanical anisotropy of AM specimens [810]. Therefore,
Materials Science & Engineering A 799 (2021) 140154
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A. Charmi et al.
Fig. 3. Technical drawings of the test specimens. Position of extracted tensile and Young’s modulus specimens in the wall (shown on the left), which were cut out via EDM, and
the geometry of tensile specimens (shown on the right).
to assess this possibility within the scope of the process parameters
detailed in Section 2.1 and identify the overall quality of the manufac-
turing process, six of the cylindrical tensile specimens were analyzed for
porosity by μCT. Three of them were extracted from towers build with
an inclination towards the build plate of 0,45, and 90, respectively,
and three specimens were extracted from a wall with inclinations
of 0,45and 90. The data was acquired on the commercial μCT
scanner (Model: GE v|tome|x 180/300, Baker Hughes, United States)
using a voltage of 200 kV, a current of 50 μA and a silver prefilter of
0.25 mm thickness. The reconstructed datasets were analyzed using the
commercial software VG Studio MAX Version 3.2 (Volume Graphics
GmbH, Germany). Pores were segmented within a gauge length of
16 mm around the center of the specimens. Due to the achieved voxel
size of 10 μm, only defects larger than 20 μm could be segmented.
2.6. Residual stress measurements
The neutron diffraction experiments were performed using the
angular-dispersive diffractometer E3 at the Helmholtz Zentrum Berlin,
Germany, to determine the state of RSs in six tensile specimens and
further investigating their influence on material behavior. The detailed
set-up of the instrument can be found in [46]. A wavelength of
1.476 Å and corresponding 2𝜃angle of 86were used to record the
Fe-311 reflection. The choice to use the {311} was made based on
the reported similar behavior with the bulk properties in the elastic
regime as well as its low tendency to form intergranular strains [47
49]. In order to calculate the triaxial RSs, strains were determined
along three orthogonal orientations defined by the blank specimen
geometry and aligned to the specimen axis. Small cubes of dimension
(3 × 3 × 3) mm3were cut by wire EDM close to the gauge length of
the specimens extracted from the wall, from the respective specimen
blanks or from specimens located in the vicinity of the investigated
specimen to be used as the stress-free reference. The use of wire EDM
prevents the insertion of additional RSs, as the thin recast layer at the
surface is not sampled, and it is therefore assumed that the macroscopic
RSs are fully released in the cubes [48,50]. The stress-free reference
diffraction angles were measured in three orthogonal directions and
averaged for subsequent stress calculations to minimize the influence
of microscopic RSs. The RS distribution for the Tower 90tensile
specimen was acquired during two measurements, and an angular offset
of approximately 0.02related to the different experimental conditions
was applied for data merging. The Young’s modulus of 184 GPa and
Poisson’s ratio of 0.294 were calculated in [51] for the {311} reflection
assuming random texture using the model of Kröner [52] and measured
single-crystal elastic constants. RSs were then calculated using Hook’s
law:
𝜎𝑖𝑗 =𝐸ℎ𝑘𝑙
1 + 𝜈ℎ𝑘𝑙 (𝜀ℎ𝑘𝑙
𝑖𝑗 +𝜈ℎ𝑘𝑙
1−2𝜈ℎ𝑘𝑙 (𝜀ℎ𝑘𝑙
11 +𝜀ℎ𝑘𝑙
22 +𝜀ℎ𝑘𝑙
33 )),(1)
with 𝜎𝑖𝑗 referring to the stress, 𝐸ℎ𝑘𝑙 and 𝜈ℎ𝑘𝑙 the lattice plane spe-
cific Young’s modulus and Poisson’s ratio, and 𝜀ℎ𝑘𝑙
𝑖𝑗 the measured
strain. The isotropic condition was used per recently reported work on
LPBF316L [51]. However, it is noted that anisotropy of the diffraction
elastic constants (DECs) governed by non-random texture would exert
an effect on the calculated stresses, although the variation is not
considered in the values presented herein. The RSs were determined
using a diffraction gauge volume of (2×2×2) mm3in five measurement
positions on three planes distributed along the gauge volume of six
tensile specimens. The distance between each plane was 18 mm along
the gauge length. The locations of the measurement planes and points
in the tensile specimens are shown in Fig. 4. The neutron diffraction
data analysis was performed using the StressTexCalculator [53].
2.7. Electron backscatter diffraction measurements
For EBSD measurements all specimens were ground and polished:
Emery papers with 180,320,600 and 1200 grits were used, followed
by clothes with 3 μm and 1 μm particle suspensions. Subsequently, the
Materials Science & Engineering A 799 (2021) 140154
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A. Charmi et al.
Fig. 4. Measurement planes and positions used during neutron diffraction experiments. The RSs were determined on three separate planes along the height of each specimen,
which are labeled as Bottom, Middle, and Top. On each plane, five positions were used for the measurements, which are shown on the right side. Note that the sample coordinate
system (X,Y,Z)is different from the coordinate system in Fig. 1 and it will be used to analyze the residual stresses in Section 4.2. In the sample coordinate system, X and Y are
always parallel to the edges of the produced geometry irrespective of the employed scan strategy. Furthermore, Z is always aligned with the loading axis.
specimens were electro-polished on Struers Lectropol-5 (Struers GmbH,
Germany) device using standard electrolyte A2. The measurements
were done on a scanning electron microscope (SEM) Leo Gemini 1530
VP (Carl Zeiss Microscopy GmbH, Germany) equipped with a high res-
olution EBSD detector eFlashHR+ (Bruker Corporation, United States).
The software package ESPRIT 1.94 (Bruker Corporation, United States)
was used for acquisition, indexing and post-processing. The EBSD mea-
surements were done on specimens extracted from the middle section of
a Tower 90specimen, the top section of a Tower 45specimen, and on
specimens extracted from one of the walls. In total five different regions
were used for the EBSD measurements to extract the representative
crystallographic and morphological texture, see Fig. 5. The 70-tilted
samples were investigated using electrons of 20 kV energy. The further
settings for the measurements were 11.9 μm pixel size, 17 ms exposure
time, 10 nA beam current, and a pattern size of 160 ×120 pixels.
3. Numerical methods
3.1. Creation of representative volume elements
The simulations in this paper are conducted in a representative
volume element (RVE) framework. These RVEs equal the statistical
properties of the grain morphology and crystallographic texture, which
were extracted from the EBSD scans of the specimens. To simplify this
procedure and also isolate the influence of crystallographic texture on
the simulation results, the grain size distribution was replaced with a
cubic grain having a dimension of (70 × 70 × 70) μm3, see Fig. 6. This
grain aspect ratio and average grain size are chosen based on the EBSD
measurements and the resulting grain size distributions, see Figs. 9
and 11 in Section 4.3. The simulation results for these 3 RVEs were
compared to ensure convergence. The synthetic RVEs seen in Fig. 6
were generated with software Neper [54]. The crystallographic texture
was extracted from EBSD measurements using the MTEX software [55],
which outputs orientation distribution function (ODF) intensity data.
The ODFs, which were calculated using a 4.5halfwidth, were then
used in the hybridIA scheme [56] to find discrete sets of orientations
matching the number of grains in each RVE. The hybridIA scheme is
capable of reconstructing textures using only a few numbers of equally
weighted orientations, which is beneficial to the accuracy of crystal
plasticity (CP) simulations. In the last step, these extracted orientations
were randomly assigned to the Fourier points inside the RVEs.
3.2. Mechanical equilibrium
To obtain the equilibrium deformation field, the following equation
needs to be solved under a given set of periodic boundary conditions
applied to the RVEs:
Div𝐏= 0,(2)
where 𝐏is the first Piola–Kirchhoff stress tensor. The deformation
mapping 𝝌can be decomposed in a homogeneous deformation gradient
𝐅, and a superimposed deformation fluctuation field
𝐰[57,58]
𝝌=
𝐅𝐱 +
𝐰,(3)
which satisfies the periodicity condition. Therefore, the deformation
gradient can be split into a homogeneous deformation gradient
𝐅and
a locally fluctuating part
𝐅
𝐅=
𝐅+
𝐅.(4)
The solution of the mechanical boundary value problem, expressed
in terms of the deformation gradient field, is obtained solving the
following system of equations [57,58]:
Fbasic [𝐅(𝐱)]= F−1 [{
L
(𝐤)𝐏(𝐤) = 𝟎if 𝐤0
𝛥𝐅BC if 𝐤= 0 ](5)
where 𝐱and 𝐤are position in real space and frequency vector in Fourier
space, respectively. For the sake of brevity, the reader is referred
for specifics about the Gamma operator
L
and the collocation-based
discretization approach necessary for obtaining Eq. (5) to [57], where
the spectral solver of the software DAMASK is described. The boundary
conditions for the RVE are prescribed in terms of the deformation
gradient 𝐅BC through the following equation:
𝛥𝐅BC =
𝐅𝐅BC .(6)
DAMASK allows also the definition of mixed boundary conditions to
avoid non-volume preserving loads for very large deformations. For
example a mixed boundary condition for the simulation of tension in
11 direction can be defined through
𝐅BC =
𝑎0 0
0 0
0 0
and 𝐏BC =
∗∗∗
0
0
,(7)
where 𝑎is then replaced with a number, which defines the loading rate.
The boundary conditions in Eq. (7) can also be used in combination
with a rotation matrix to define other loading directions. In this work,
𝑎is defined to be 𝑎= 3 10−4, and the different load situations for
0∕45∕90are realized by the application of rotation matrices.
3.3. Crystal plasticity
For the modeling of material anisotropy, the following CP model
was applied. The deformation gradient is multiplicatively decomposed
in an elastic and plastic part [59]
𝐅=𝐅e𝐅p.(8)
Materials Science & Engineering A 799 (2021) 140154
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A. Charmi et al.
Fig. 5. Location of five regions used during EBSD analysis (blue surfaces). Two (3 × 4) mm2EBSD measurements were done on specimens extracted from the middle section of a
Tower 90specimen (shown on the left), one (3 × 4) mm2EBSD measurement were done on a specimen extracted from the top section of a Tower 45specimen (shown on the
middle) and eight (3 × 4) mm2measurements were done on specimens extracted from one of the walls (shown on the right). (For interpretation of the references to color in this
figure legend, the reader is referred to the web version of this article.)
Fig. 6. RVEs used for CP simulations. (a) 4096 grains, 1 Fourier point per grain, and dimensions of (1120 × 1120 × 1120) μm3, (b) 4096 grains, 64 Fourier points per grain, and
dimensions of (1120 × 1120 × 1120) μm3, and (c) 8000 grains, 1 Fourier point per grain, and dimensions of (1400 × 1400 × 1400) μm3. Note that the colors of the grains do not
represent the grain orientation.
The quantities in the intermediate configuration are marked with an
overbar () and are obtained when the elastic part of deformation is re-
laxed. Therefore, this state of the body represents a reference configura-
tion for the elastic part of the deformation. The second Piola–Kirchhoff
stress
𝐒can be written as
𝐒=
C
𝐄e,(9)
with
𝐄e=1
2((𝐅e)T𝐅e𝐈)=1
2(
𝐂e𝐈),(10)
where
Cis the fourth order tensor of elastic constants,
𝐂eis the elastic
right Cauchy–Green tensor and 𝐈is the identity tensor. The second
Piola–Kirchhoff stresses are related to the first Piola–Kirchhoff stresses
by 𝐒=𝐏𝐅𝑇. In case of cubic crystals, the elastic tensor Ccan be
specified with three elastic constants 𝐶11,𝐶12 and 𝐶44. The total power
per unit volume can be decomposed into elastic and plastic parts [60]
𝑤=
𝑤e+
𝑤p=
𝐒
𝐄e+ (
𝐂e
𝐒)
𝐋p,(11)
where
𝐋pis the plastic velocity gradient in the intermediate configura-
tion, which can be written as a function of dislocation glide on different
slip systems
𝐋p=
𝐅p(𝐅p)−1 =
𝑁
𝛼=1
𝛾𝛼𝐦𝛼
0𝐧𝛼
0,(12)
where 𝐦𝛼
0and 𝐧𝛼
0are unit vectors representing the slip direction and the
normal of the slip plane for the slip system 𝛼, respectively. The plastic
power per unit volume can be calculated using the resolved shear stress
𝜏𝛼and the slip rate 𝛾𝛼
𝑤p=
𝑁
𝛼=1
𝜏𝛼𝛾𝛼,(13)
where 𝑁is the number of slip systems. With the Eqs. (11)(13) the
resolved shear stress 𝜏𝛼acting on slip system 𝛼reads
𝜏𝛼=
𝐂e
𝐒(𝐦𝛼
0𝐧𝛼
0).(14)
The employed phenomenological model in this paper utilizes a rate-
dependent power-law function to define the slip rate 𝛾𝛼[61]
𝛾𝛼=𝛾0|||||
𝜏𝛼
𝜏𝛼
c|||||
𝑛
sgn(𝜏𝛼),(15)
where 𝛾0is the reference shearing rate, 𝑛describes the microscopic
strain rate sensitivity and 𝜏𝛼
cis the slip resistance, which evolves
asymptotically from 𝜏0towards 𝜏[58]. Moreover, to incorporate
work-hardening in the material model, the slip resistance
𝜏𝛼
cis made
to be a function of shear rate
𝜏𝛼
c=
𝑁
𝛽
𝛼𝛽 𝛾𝛽,(16)
Materials Science & Engineering A 799 (2021) 140154
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A. Charmi et al.
Table 2
Single-crystal elastic constants of stainless steel 316L [62].
𝐶11 (GPa)𝐶12 (GPa)𝐶44 (GPa)
206 133 119
Table 3
Results from tensile tests according to DIN EN ISO 6892-1 [39].
04590
Spec. 1 Spec. 2 Spec. 1 Spec. 2 Spec. 1 Spec. 2
Rp0.2 MPa
Tower 583 583 540 537 500 −−
Wall 581 581 564 563 514 506
Rm
Tower 692 692 652 653 619 −−
Wall 689 691 670 671 620 611
A
%
Tower 54 55.5 56.5 56.5 60 −−
Wall 56.5 56.5 56.5 53 59.5 53.5
ZTower 72.2 71.3 73.3 71.5 72.2 −−
Wall 73 72.5 71 70.6 72.5 72.3
E GPa Tower 212 218 196 199 198 −−
Wall 213 218 194 210 194 181
where 𝛼𝛽 is the instantaneous strain hardening, which can be calcu-
lated by a saturation-type law [58]
𝛼𝛽 =0[𝑞+ (1 𝑞)𝛿𝛼𝛽 ]|||1 𝜏𝛽
c𝜏|||
𝑎sgn(1 𝜏𝛽
c𝜏).(17)
The parameters 𝑞,0,𝜏and 𝑎are the latent-hardening, the reference
self-hardening coefficient, saturation value of the slip resistance and the
hardening exponent, respectively. The single-crystal elastic constants
of stainless steel 316L, which are necessary for the calculation of the
elastic tensor C, were taken from [62] and are listed in Table 2.
3.4. Parameter identification
The parameter identification was conducted using a least-squares
based regression analysis. The residual to be minimized by the
Levenberg–Marquardt scheme [63,64] is defined as
minimize (𝐩) = 1
2
𝑁
𝑖=1
𝑤𝑖(𝑓𝑖(𝐩) 𝑦𝑖)2,
by changing 𝐩𝑆 ,
such that 𝑔𝑗(𝐩)0, 𝑗 = 1,, 𝑛g,
(18)
where is the residual function, 𝑔𝑗is a vector of constraints, 𝐩is a
vector containing the material parameters to be optimized and 𝑤𝑖is
the weight associated to experiment 𝑖. The residual function is the
least-square distance between experiments and simulations. The vector
𝐩contained the parameters 𝑛,0,𝑎,𝜏0and 𝜏. The parameters 𝑞and 𝛾0
were set to a fixed value of 1. During the calibration process only one
tensile test (Tower 45) and one EBSD measurement (Tower 45) were
used, and the strain range was limited with the lower bound of 0and
upper bound of 0.015. The calibrated parameters were validated using
the remaining experimental data, see Section 4.5 for more details.
4. Results and discussion
4.1. Results from tensile tests and resonance method
The characteristic values for each specimen determined in the ten-
sile tests are listed in Table 3 and the corresponding stress–strain curves
are shown in Fig. 7.
The results reveal that in general, the characteristic strength pa-
rameters (E, Rp0.2 and Rm) increase with decreasing building angle,
and there are no significant differences between specimens from walls
and towers, except for the 45orientation, which is considered to be
a result of the rotated scan strategy (see Fig. 1) and will be further
investigated in following sections. The percentage elongation after
Table 4
Results from resonance method according to ASTM E1876 [42].
04590
Spec. 1 Spec. 2 Spec. 1 Spec. 2 Spec. 1 Spec. 2
E GPa Tower −− −− −− −− −− −−
Wall 225 −− 206 −− 180 −−
fracture (A) and reduction of area (Z) show no dependency on build
orientation. The percentage elongation after fracture (A) is calculated
by carefully fitting back together the broken pieces after fracture and
measuring the gauge length. It should be highlighted that despite the
slight difference between the stress–strain curves for 90specimens,
overall, the tensile tests display a low scatter. By comparing the stress–
strain curves, it also becomes clear that each direction has slightly
different yield behavior, characterized by the transition from purely
elastic to plastic deformation. The 0direction exhibits the sharpest
transition behavior, whereas the 90specimens display a more diffused
transition behavior.
For the resonance method [42] three specimens were cut out from
one of the AM walls with three different inclinations towards the
build plate. The dynamic Young’s moduli were then calculated from
the fundamental flexural resonance frequencies obtained from in-plane
and out-of-plane flexure and were then averaged. The measurement
uncertainty for the dynamic method is around 1%, as previously deter-
mined using other materials by inter-laboratory studies. The measured
dynamic Young’s moduli are listed in Table 4. The results from tensile
tests and the resonance method will be analyzed and compared in detail
in Section 4.4.
4.2. Defects and residual stresses
Six tensile specimens (Tower 0, Tower 45, Tower 90, Wall 0,
Wall 45and Wall 90) were investigated via μCT and neutron diffrac-
tion to detect the microstructural defects and measure the RSs, since
they can have an impact on the material performance of AM parts [27,
65,66]. Table 5 contains the porosity determined for these six tensile
specimens. The segmented pores in all the specimens were spherical.
Therefore, they are expected to be gas pores. As evident from the very
low porosity, it is safe to assume that for the tested specimens in this
paper, the microstructural defects do not contribute to the mechanical
anisotropy and can, therefore, be omitted in the numerical analysis.
The RSs were also determined in six tensile specimens on three
different planes along the height of each specimen. The RSs in normal
direction (Z) of all investigated specimens are shown in Fig. 8. The
highest RS range, from maximum to minimum, of all measured spec-
imens was 142 MPa with an average error of approximately 20 MPa.
The distribution appears not to be symmetric with respect to the
specimen axis. The RS distributions in the specimens 0,45and
90, all three extracted from one wall, are similar. Minor variations
in the RS magnitudes and distributions are considered to be related
to the varying extraction locations and orientations within the wall.
The specimens extracted from individual towers feature similar RS
distributions and magnitudes to the specimens extracted from the wall.
The RS magnitudes are lower for Tower 0, possibly resulting from
the increased heat-conducting surface with respect to the low build
height or the employed scan strategy, see Section 2.1. The RSs in Tower
90tend to be compressive, which can be a result of an offset for the
stress-free reference, since the RS distribution for this specimen was
acquired during two separate measurements. However, the RS range
and distribution are not influenced by the reference values and are
comparable to the other specimens. The position of the RS profile
dictates the occurrence of compressive or tensile RSs, and it strongly
depends on the stress-free Ref. [67]. The herein determined RS ranges
are low compared to RS ranges of net-shape geometries [50,68,69].
Materials Science & Engineering A 799 (2021) 140154
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A. Charmi et al.
Fig. 7. Experimentally obtained tensile stress–strain curves. The plots (a, b, c, d) display the same results for different stress and strain ranges, which show that the characteristic
strength parameters increase with decreasing building angle. These results also reveal that the stress–strain curves obtained for the Tower 45and Wall 45specimens are shifted
relative to each other. This difference in the material behavior is due to the rotated scan strategy, see Fig. 1. Additionally, it should be noted that the difference between the
stress–strain curves for 90specimens are not due to a rotation of the scan strategy, since the rotation axis coincides with the loading axis, see Fig. 1. Moreover, the most notable
difference is observed for two of the Wall 90specimens (b). After 0.01 strain, the stress–strain curves for a Tower 90and a Wall 90specimen are nearly identical (b, d). Hence,
for the analysis in subsequent sections, the specimens are grouped in 0, Tower 45, Wall 45and 90to account for the effect of the scan strategy.
Table 5
Measured porosity by μCT for six tensile specimens. These results indicate that the anisotropy of LPBF316L specimens is not
affected by the detected gas pores, since the measured porosity is much smaller than 0.01% for all specimens.
Tower 0Tower 45Tower 90Wall 0Wall 45Wall 90
Analyzed volume (mm3) 443.1586 443.7266 442.5135 443.1867 445.1126 444.6265
Volume of pores (mm3) 0.0005 0.0015 0.0009 0.0007 0.0013 0.0010
Number of pores 28 73 42 43 59 57
Porosity <0.01% <0.01% <0.01% <0.01% <0.01% <0.01%
Table 6
Maximum stress range measured in 6 tensile specimens for three orthogonal directions,
see Fig. 4 for the used coordinate system. All values are in MPa.
Tower 0Tower 45Tower 90Wall 0Wall 45Wall 90
Normal direction (Z) 89.98 117.64 142.68 109.5 96.81 107.49
In-plane direction (X) 118.06 84.66 160.78 147.43 106.33 169.34
In-plane direction (Y) 109.3 130.75 149.92 115.31 104.87 159.31
This result can be attributed to mechanical relaxation caused by the ma-
chining of the dogbone geometry of the tensile specimens, as reported
in [49]. Although possible shifts of the RS distribution profile could
occur due to the adopted stress-free reference strategy, the RS ranges
determined within this investigation remain low compared to those
reported for non-machined structures in LPBF316L [50,68,69], see
Table 6. Moreover, it should be highlighted that the tensile specimens
were extracted from walls and towers with different geometries and
thermal histories, which influence the RSs in each specimen. However,
despite the differences in RS profiles, the tensile test results in Fig. 7,
in particular for 0direction, are nearly identical. This behavior is a
strong indication that the RSs are not significantly contributing to the
mechanical anisotropy of the tested specimens. Therefore, the RSs are
omitted during the subsequent numerical analysis.
4.3. Texture analysis
In the present study, the texture is determined using EBSD mea-
surements from three different specimens. The measurements were
designed to ensure that the derived crystallographic texture is as rep-
resentative as possible of all the specimens manufactured. Figs. 9–11
contain the EBSD maps, the extracted crystallographic textures, and the
grain size distribution for five different regions with a total scanned
area of 132 mm2. The measurements from the wall (both from side
and cross-section) each consist of four smaller EBSD maps, which are
joined together during post-processing, see Fig. 9(a,b). Note that the
EBSD data were subjected to the smoothing algorithm in the software
MTEX [55,70] to replace the unindexed measurement points. EBSD
maps in Fig. 9 reveal the unusual morphological texture, which is
heavily influenced by the employed scan strategy. The morphological
texture is recognizable as a checkerboard pattern in the cross-section
measurements. Furthermore, the EBSD maps from the side of the spec-
imens display no sign of melt pool boundaries, which is an indication
for epitaxial grain growth of remelted zones. Moreover, the comparison
between the crystallographic texture extracted from the Tower 90and
the wall, both from side and cross-section, show a three times random
{110} texture in the build direction, which is in line with the findings
in other studies [13,30,71]. It should be noted that the ODFs extracted
from EBSD measurements are dependent on the measurement frame
Materials Science & Engineering A 799 (2021) 140154
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Fig. 8. RSs in the normal direction (Z) measured at different heights. The pictures on the top show RSs in the wall specimens and the pictures on the bottom show RSs in the
tower specimens, both for three inclinations. For the used coordinate system, see Fig. 4. The highest value of measured RS is 137 MPa in Wall 90specimen and the lowest value
is −74 MPa in Tower 90specimen. However, note that the compressive nature of RSs in Tower 90specimen might be due to an offset for the stress-free reference diffraction
values, since the RSs for this specimen were measured during two separate beam times.
and the scan strategy. The ODFs can also be displayed using different
coordinate systems. Changing the measurement frame, the scan strat-
egy, or the coordinate system directly impact the outcome. Hence, all
the ODFs in the pole figures (Fig. 10) are plotted in the same coordinate
system (X, Y, Z)for an easier comparison between the results, see Fig. 1
for all coordinate systems. These five EBSD measurements show that
despite the different geometries, crystallographic and morphological
textures are very comparable in all manufactured specimens.
4.4. Elastic anisotropy
The single-crystal elastic anisotropy of stainless steel 316L can be
described through the elastic tensor C(see Section 3.3), which itself
can be specified with three elastic constants 𝐶11,𝐶12 and 𝐶44. With
these values, it is possible to calculate and predict the anisotropic
elastic behavior in any direction. However, this is only applicable to a
specimen containing a single grain, since these values are only correct
for a single-crystal with a certain crystallographic orientation. The
LPBF316L specimens tested in this paper are polycrystalline, as evident
from the EBSD measurements, see Fig. 9, and the macroscopic elastic
behavior of a polycrystalline specimen is determined by the average
behavior of its grains and heavily influenced by the crystallographic
texture.
To analyze the macroscopic elastic anisotropy of LPBF316L the
Young’s moduli were experimentally measured using both tensile test-
ing and resonance method. The Young’s moduli, which were deter-
mined from eleven tensile tests (see Table 3), were averaged for loading
directions 0, Wall 45, Tower 45and 90and measured to be 215 ±
3GPa, 202 ± 8 GPa, 198 ± 2 GPa and 192 ± 7 GPa, respectively. The
results for Wall 45and Tower 45specimens are averaged separately to
Materials Science & Engineering A 799 (2021) 140154
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A. Charmi et al.
Fig. 9. EBSD measurements from cross-section of wall (a), side of wall (b), cross-section of Tower 90(c), side of Tower 90(d) and side of Tower 45(e). Note that the coordinate
systems (X, Y, Z)and (X,Y,Z)are different, for more details see Fig. 1. The corresponding pole figures are shown in Fig. 10.
account for the influence of the rotated scan strategy during specimen
production, see Figs. 1 and 7. The measured dynamic Young’s moduli
for Wall 0, Wall 45and Wall 90specimens are 225 GPa, 206 GPa and
180 GPa, respectively.
The macroscopic elastic anisotropy was numerically estimated for
all tested directions using the softwares DAMASK [57] and MTEX [55].
The details of the CP model implemented in DAMASK are explained in
Section 3.3. The software MTEX has three built-in methods (Voigt, Hill,
Reuss) for the estimation of the macroscopic elastic behavior. For the
sake of brevity, the reader is referred to [70] for specifics about these
methods and the usage of the software MTEX.
Materials Science & Engineering A 799 (2021) 140154
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A. Charmi et al.
Fig. 10. Pole figures from cross-section of wall (a), side of wall (b), cross-section of Tower 90(c), side of Tower 90(d) and side of Tower 45(e). Note that for an easier
comparison, all pole figures (a, b, c, d, e) are shown in the same coordinate system (X, Y, Z)and not the coordinate system of their corresponding EBSD map in Fig. 9. It is
evident from the results that all specimens have a very similar {110} texture in the build direction.
Fig. 11. Grain size distributions determined from five EBSD measurements, see Fig. 9. The grain size is calculated from the grain area assuming a rectangular grain shape. The
kernel density estimation (KDE) visible in the plot is the average KDE of all five grain size distributions.
For the numerical analysis, the extracted crystallographic textures
from all five EBSD measurements and the single-crystal elastic con-
stants of stainless steel 316L from [62] were used, which are listed in
Table 2. The experimental and numerical results, which are displayed
in Fig. 12, reveal that the Hill estimation approach [70] and the crystal
plasticity model are capable of predicting the elastic anisotropy. The
numerical results for each estimation method displayed in different
colors cover the range between the minimum and maximum value
obtained for all five crystallographic textures as slight variations in
ODFs influence the numerical results. Furthermore, it should be noted
that the observed differences between the results from tensile tests and
resonance method might be due to measurement inaccuracies since the
employed extensometer for the tensile tests was calibrated in the range
of −10% to 50% percent strain and is therefore not perfectly suited
for precise measurements of Young’s moduli. However, despite these
differences, it can be argued that for the tested specimens in this paper,
the crystallographic texture is responsible for the elastic anisotropy
since the directional dependency of the Young’s moduli was captured
by only using the crystallographic texture and single-crystal elastic
constants as inputs for the simulations softwares. These results are
also in line with the findings in [72,73], which showed experimentally
and numerically that the elastic anisotropy of their AM inconel 718
specimens were well reflected by the crystallographic texture.
4.5. Anisotropic yield behavior
The tensile test results revealed both the elastic anisotropy and also
the anisotropic yield behavior of the LPBF316L specimens, see Figs. 7
and 12. In the last section, it was shown that the elastic anisotropy
of the tested specimens is highly correlated with the crystallographic
texture. The CP model was calibrated using only the tensile test results
for the Tower 45and the EBSD measurement from the side of Tower
45specimen, see Figs. 7 and 9. The calibration process was done with
only a single tensile test and one EBSD measurement to demonstrate
the efficiency and reliability of the numerical method. Moreover, the
CP model can be calibrated using any of the tensile test results and
EBSD measurements. The strain range for the calibration process was
between 0and 0.015. The calibrated parameters of the CP model are
listed in Table 7.
The remaining tensile test results and EBSD measurements were
used for the validation and sensitivity analysis of the model. The
Materials Science & Engineering A 799 (2021) 140154
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Fig. 12. Comparison between experimentally measured and numerically estimated Young’s moduli using softwares MTEX (a) and DAMASK (b). Each color, which corresponds to
a different estimation method, renders the range between the minimum and maximum value obtained for five separate extracted crystallographic textures, see Fig. 10.
Fig. 13. Comparison between experimental and numerical results (CP) in the strain range of 0.002 to 0.015. The lines represent the experimental stress–strain curves. The plots
(a, b, c, d) each contain the simulation results for one specific loading direction. The results for Tower 45(b) and Wall 45(c) specimens are displayed separately to account
for the influence of the rotated scan strategy during specimen production. The rotation of the scan strategy does not influence the results for the 90(a) specimens, since the
rotation axis coincides with the loading axis, see Figs. 1 and 7for more details. The simulation results cover the range between minimum and maximum value obtained for all
five extracted crystallographic textures, see Fig. 9.
experimental and simulated true stress–strain behaviors for all loading
directions and crystallographic textures are plotted in Figs. 13 and 14.
The numerical results for each loading direction displayed in different
colors cover the range between the minimum and maximum value ob-
tained for all five experimentally determined crystallographic textures,
see Fig. 10. As evident in Fig. 7 the tensile test results for each loading
direction are very similar. Hence, for easier comparison between the
stress–strain curves, only one single tensile test result is plotted for
each loading direction. These results show an overall good agreement
between the experiments and model prediction.
The maximum deviations between the simulations and experiments
are displayed in Fig. 15 as %-error, which demonstrates the accuracy
of the numerical model. The %-error is below 5% after only 0.004
strain and stays under 3% after 0.025 strain. These variations are
tolerable considering the different sources of measurement error, such
as the difficulties of extracting the crystallographic texture from a 2D
surface area. Different aspects like surface finish, beam shift, and tex-
ture gradients in the material influence the result. Moreover, it should
be highlighted that after the model calibration, the same parameter
set was used for running all other simulations. This means that the
simulation results for textures extracted from the four remaining EBSD
measurements can be further optimized since they were not used during
the calibration process. However, the main goal of this paper is to
demonstrate the sensitivity and reliability of this approach.
Furthermore, it is evident from Fig. 13 that there is a variation in
the yield behavior for each loading direction which leads to a greater
Materials Science & Engineering A 799 (2021) 140154
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A. Charmi et al.
Fig. 14. Experimental and numerical results for all extracted crystallographic textures displayed in the strain range of 0.005 to 0.16, which demonstrate the accuracy of the CP
model outside of its calibration range. Note that the strain range for the calibration process was between 0and 0.015, see Fig. 13.
Fig. 15. Maximum deviation between the experimental and numerical stress–strain curves (Figs. 13 and 14) presented as %-Error.
deviation between the simulations and experiments, most notably at
the beginning of yielding. This behavior might be explained through
different competing deformation mechanisms for each particular load-
ing direction. Nano twinning is sometimes the dominating deformation
mechanism, as reported in related studies [13,17,19,31]. However, in
the currently used CP model only dislocation slip is taken into account.
Concluding the findings in this section, the results strongly indicate
that the crystallographic texture is the main contributing factor to
the anisotropy of LPBF316L, since the CP model was able to accu-
rately capture and predict the anisotropic yield behavior of the tested
specimens.
The findings in this section are based on a micro-mechanical crystal
plasticity model. Due to the high computational cost, such models can
usually only realistically simulate the deformation behavior in small
regions, such as the representative volume elements (RVEs) employed
in this work. However, additively manufactured parts are orders of
magnitude larger than these RVEs. To overcome this constraint, dif-
ferent methods were developed [58,74], which allow these results
to be transferred to the macro-scale. For example, in a virtual-lab
framework [58], the calibrated crystal plasticity model can be used to
simulate the yield behavior for many different loading conditions. The
results of the simulations can in turn be used to calibrate a macroscopic
yield surface and thus, allow the use of finite element softwares for
simulating the deformation behavior of additively manufactured parts
with complex geometries. On a final note, although it is possible to
simulate any desired stress state with a calibrated crystal plasticity
model, more experimental validation is recommended to ensure the
best possible results when simulating complex loading paths. This can
be achieved for example using notched specimens or doing shear or
torsion tests.
5. Conclusions
The mechanical anisotropy of LPBF316L was investigated using
both experimental and numerical methods to determine the underlying
origin. Several important aspects were examined to isolate the main
Materials Science & Engineering A 799 (2021) 140154
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A. Charmi et al.
Table 7
Calibrated material parameters of the CP model.
𝛾0(1/s)𝑛 0(MPa)𝑎 𝜏0(MPa)𝜏(MPa)
1 38 3160 9 263 1130
contributing factor, since the origin of anisotropy in LPBF316L in liter-
ature remains inconclusive and exhibits a broad range of explanations.
1. The mechanical testing showed that the yield strength increased
with decreasing angle of the building direction relative to the
build plate for all tested specimens.
2. EBSD analysis revealed a preferential 110orientation parallel
to the build direction and a checkerboard morphology, which
were a direct result of the layerwise 90rotation of the scan
strategy and were in line with the findings in other studies.
3. The measured porosity in all specimens was much smaller than
0.01%, and the detected defects were spherical. Despite the dif-
ferences in measured RS profiles, the tensile stress–strain curves
for certain loading directions were nearly identical. With these
findings, it was concluded that contrary to the statements in
some publications, the anisotropy of the tested specimens in this
paper is not predominantly controlled by either defects or RSs.
4. Elastic anisotropy was experimentally determined using both
tensile testing and resonance method. Through numerical anal-
ysis, it was shown that the elastic anisotropy was dominated by
crystallographic texture.
5. The anisotropic yield behavior of LPBF316L was modeled using
a CP model. The numerical investigations strongly indicated that
the directional dependency of yield behavior is mainly governed
by the crystallographic texture.
Overall, it can be concluded that the crystallographic texture is the
main contributing factor to the mechanical anisotropy of the tested
LPBF316L specimens. Moreover, the approach presented in this paper
can be employed to accurately capture and predict the mechanical
anisotropy of AM specimens in an efficient manner, since it only
requires a single tensile test and one EBSD measurement.
Funding
The funding of BAM Focus Area Project AGIL, Germany is acknowl-
edged.
CRediT authorship contribution statement
A. Charmi: Conceptualization, Methodology, Formal analysis, Vi-
sualization, Validation, Writing - original draft, Writing - review &
editing. R. Falkenberg: Conceptualization, Supervision, Writing - origi-
nal draft, Writing - review & editing. L. Ávila: Investigation, Resources,
Data curation, Writing - original draft, Writing - review & editing. G.
Mohr: Investigation, Resources, Writing - original draft, Writing - re-
view & editing. K. Sommer: Investigation, Formal analysis, Resources,
Writing - original draft, Writing - review & editing. A. Ulbricht: Inves-
tigation, Resources, Formal analysis, Writing - original draft, Writing
- review & editing. M. Sprengel: Investigation, Resources, Formal
analysis, Writing - original draft, Writing - review & editing. R. Saliwan
Neumann: Investigation, Formal analysis, Resources, Writing - original
draft, Writing - review & editing. B. Skrotzki: Project administration,
Supervision, Funding acquisition, Writing - review & editing. A. Evans:
Investigation, Project administration, Writing - original draft, Writing -
review & editing.
Declaration of competing interest
The authors declare that they have no known competing finan-
cial interests or personal relationships that could have appeared to
influence the work reported in this paper.
Data availability
The raw/processed data required to reproduce these findings cannot
be shared at this time as the data also forms part of an ongoing study.
Acknowledgment
Robert Wimpory of the HZB is acknowledged for support of the
residual stress measurements on the E3 diffractometer.
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