scieee AI-readable full text Open interactive document viewer

Environmental process improvement of tire end-of-life treatment via pyrolysis through life cycle assessment

Faruss, Tim

Abstract

End-of-life tire waste streams depict a global issue and can be recycled at the moment through retreating or reusing within limits. Thus, the current state-of-the-art technology to treat and recover energy from end-of-life tires represents incineration, which is associated with high environmental impacts. Thermal recycling via pyrolysis is a promising end-of-life treatment technology to recover material and energy from end-of-life tires to potentially reduce the environmental impacts. A life cycle assessment (LCA) is required to quantify additional environmental impacts and to relate potential environmental benefits from pyrolysis products for the end-of-life technology. In current literature, the LCA modeling of pyrolysis as an end-of-life tire treatment process uses insufficient system boundaries or life cycle data (1), focuses on the comparison of pyrolysis to end-of-life treatment technologies (2), and process improvements that could reduce environmental impacts are not sufficiently considered (3).To address the gaps, the objective of the study is to show the sustainable improvement potential of the pyrolysis process as a tire end-of-life treatment technology through a comprehensive environmental assessment through LCA. For the case study of the pyrolysis process, we want to show the environmental potential for an end-of-life technology in a sensitivity analysis regarding process design and crucial process parameters. We identify hot-spots within the pyrolysis end-of-life treatment process system that led to high environmental impacts. Additionally, we perform a potential analysis for the environmental impacts of the pyrolysis process regarding future scenarios for energy and process systems. In a broader context, we want to show a general methodology for an environmental improvement of current end-of-life treatment technologies. The results of the environmental assessment should serve as an indicator for the elastomer industry and in particular tire manufacturers for the development of end-of-life treatment technologies.

Full text

Environmental process improvement of tire end-of-life treatment via pyrolysis through life cycle assessment Tim Farussa, Jan Hartmanna, Niklas von der Assena Contact data Tim Faruss RWTH Aachen University Institute of Technical Thermodynamics Schinkelstr. 8, 52062 Aachen, Germany E-Mail: [email protected]th-aachen.de Phone: + 49 241 80 95376 Further Steps Motivation & Goal Environmental Process Improvement Affiliation a) Institute of Technical Thermodynamics, RWTH Aachen University, Aachen, Germany Let’s Discuss… System boundary of EoL treatment via pyrolysis Contribution of Gobal Warming Impact (GWI) Environmental Process Improvement through LCA GWI reduction by pyrolysis Method Assumptions regarding modeling the pyrolysis process Scenarios regarding the product usage of end-of-life tire pyrolysis Decarbonization measures for the pyrolysis process Development of physical pyrolysis model for flexible operation Analysis of sector coupling via product usage Analysis of potential burden shifts towards the impact categories •Scope 1 emission from CHP constitute the largest GWI share •Electricity has largest impact on the GWI of the pyrolysis treatment Pyrolysis lowers the climate change impact of end-of-life tire treatment by 77.3% •Employ method of life cycle assessment (LCA) to quantify environmental impacts [3] •Pyrolysis process modeled based on literature data [4] •Net negative climate change impact essential to minimize emissions over product life cycle •Carbon black has most significant impact on reduction potential of environmental impact Operation improvement over GWI of electricity supply Pyrolysis GWI Reduction with Avoided Burden ? Abbreviations: •EoL: end-of-life •CHP: combined heat and power •LCA: life cycle assessment •GWI: global warming impact Credits from Product usage decisive for reduction End-of-Life (EoL) tires cause severe environmental impacts [1] Energy recovery through incineration is not compatible with a circular economy Pyrolysis can reduce impacts and enable closed-loop material cycles [2] Further reduce the environmental impacts of the pyrolysis treatment Tire Shredding Pyrolysis CHP Unit Oil Treatment Carbon Black Heat & Electricity Oil gate-to-grave Coke Treatment EoL Tire Avoided production process from products Oil, gas, carbon black Gas Functional Unit Avoided Burden Excluded in Scenario I Acknowledgements We gratefully acknowledge the financial support from the German Federal Ministry for Education and Research (BMBF) for funding the Graduate Cluster AUFBRUCH (grant number 031B1170). References [1] Sienkiewicz et al. (2017). Environmentally friendly polymer-rubber composites obtained from waste tyres: A review. Journal of Cleaner Production. [2] Valentini & Pegoretti (2022). End-of-life options of tyres. A review. Advanced Industrial and Engineering Polymer Research. [3] DIN EN ISO 14040 (2021). Environmental management —Life cycle assessment —Principles and framework (ISO 14040:2006 + Amd 1:2020); German version EN ISO 14040:2006 + A1:2020. [4] Maga et al. (2023). A comparative life cycle assessment of tyre recycling using pyrolysis compared to conventional end-of-life pathways. Resources, Conservation & Recycling. Process Level Energy & Resources Scope 1 & Scope 2+3 Emissions What happens with the by-products?