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The skating of drops impacting over gas or vapour layers

García-Geijo, P.; Riboux, Guillaume Maurice; Gordillo Arias de Saavedra, José Manuel

Abstract

We report numerical simulations confirming the predictions in Gordillo & Riboux (J. Fluid Mech., vol. 941, 2022, A10), where we elucidated the lubrication mechanism by which a drop of a low-viscosity liquid impacting over a smooth solid substrate skates over a thin gas film that prevents contact with the wall. Moreover, with the purpose of explaining the so-called lift-off mechanism reported in Kolinski et al. (Phys.Rev.Lett., vol. 112, issue 13, 2014, 134501), we extend our previous findings and derive expressions for the time-varying thickness of the gas layer at the region where the distance to the wall is minimum, finding good agreement with the numerical results. In addition, we report that our predictions for the minimum thickness of the gas film separating a falling drop from a wall at room temperature follow closely the experimental values when gas kinetic effects https://doi.org/10.1017/jfm.2024.20 Published online by Cambridge University Press are retained in the analysis, and also report that the analogous equation for the minimum thickness of the vapour layer formed after a drop impacts a superheated wall predicts well the experimental measurements.

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J. Fluid Mech. (2024), ol.980, A35, doi:10.1017/j m.2024.20 The ska ing o d ops impac ing o e gas o apou laye s P. Ga cía- Geijo1,G.Riboux 1and J.M. Go dillo1,† 1Á ea de Mecánica de Fluidos, Depa amen o de Ingenie ía Ae oespacial y Mecánica de Fluidos, Uni e sidad de Se illa, A enida de los Descub imien os s/n, 41092 Se illa, Spain (Recei ed 12 June 2023; e ised 22 Decembe 2023; accep ed 30 Decembe 2023) We epo nume ical simula ions con i ming he p edic ions in Go dillo & Riboux (J. Fluid Mech., ol. 941, 2022, A10), whe e we elucida ed he lub ica ion mechanism by which a d op o a low- iscosi y liquid impac ing o e a smoo h solid subs a e ska es o e a hin gas ilm ha p e en s con ac wi h he wall. Mo eo e , wi h he pu pose o explaining he so-called li -o mechanism epo ed in Kolinski e al. (Phys.Re .Le ., ol. 112, issue 13, 2014, 134501), we ex end ou p e ious indings and de i e exp essions o he ime- a ying hickness o he gas laye a he egion whe e he dis ance o he wall is minimum, inding good ag eemen wi h he nume ical esul s. In addi ion, we epo ha ou p edic ions o he minimum hickness o he gas ilm sepa a ing a alling d op om a wall a oom empe a u e ollow closely he expe imen al alues when gas kine ic e ec s a e e ained in he analysis, and also epo ha he analogous equa ion o he minimum hickness o he apou laye o med a e a d op impac s a supe hea ed wall p edic s well he expe imen al measu emen s. Key wo ds: boiling, d ops 1. In oduc ion The impac o a d op o e a subs a e has been he subjec o in ense esea ch e o s du ing he pas decades as a consequence o i s ele ance in a my iad o na u al and echnological p ocesses;see e.g. Josse and & Tho oddsen (2016). One o he many open ques ions ha emains o be sol ed and has ecei ed subs an ial a en ion in ecen yea s e e s o he desc ip ion and quan i ica ion o he condi ions unde which a d op impac ing a supe hea ed subs a e ska es o e a apou ilm, a phenomenon e e ed o as he dynamic †Email add ess o co espondence: [email p o ec ed] © The Au ho (s), 2024. Published by Camb idge Uni e si y P ess. This is an Open Access a icle, dis ibu ed unde he e ms o he C ea i e Commons A ibu ion licence (h p://c ea i ecommons.o g/ licenses/by/4.0), which pe mi s un es ic ed e-use, dis ibu ion and ep oduc ion, p o ided he o iginal a icle is p ope ly ci ed. 980 A35-1 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess P. Ga cía-Geijo, G. Riboux and J.M. Go dillo Leiden os e ec , which limi s he cooling a e o solids in hea ans e echnological applica ions (T an e al. 2012,2013;Shi o ae al. 2016). Indeed, as a consequence o he smallness o he he mal conduc i i y o gases, he exis ence o a s able apou ilm benea h he d op educes he hea lux and he e o e he cooling capaci y o he liquid ( an Limbeek e al. 2017). The heo e ical and nume ical s udies aimed a desc ibing he e ec o a gas o apou laye on he impac o a d op o e a solid subs a e we e pionee ed by Smi h, Li & Wu (2003)and Ko obkin, Ellis & Smi h (2008), who coupled he equa ions o he in iscid mo ion o a wo-dimensional d op impac ing ei he a wall o a hin liquid laye wi h he lub ica ion equa ions o he gas. La e , Mand e, Mani & B enne (2009), Mani, Mand e & B enne (2010)and Mand e & B enne (2012) made use o he heo e ical and nume ical amewo k al eady in oduced by Smi h e al. (2003)and Ko obkin e al. (2008)wi h he pu pose o de i ing scaling ela ionships o he dimple heigh – namely, he hickness o he pancake-shaped bubble en apped a he cen e o he impac ing d op – and also o he minimum dis ance be ween he d op and he wall, which is a ained no a he axis o symme y, bu a an o -cen e posi ion. The scaling o he dimple heigh deduced by Mand e e al. (2009) in he wo-dimensional case and by Hicks & Pu is (2010) o he mo e ealis ic case o sphe ical d ops was con i med ia expe imen s and also ia nume ical simula ions by Bouwhuis e al. (2012) who, in addi ion, disco e ed a new egime domina ed by capilla i y ha desc ibes he en apmen o bubbles a low impac eloci ies. Le us poin ou he e ha he analysis o he en apmen o a gas pocke benea h a alling liquid mass is analogous o he cushioning e ec o he ai en apped a e a solid impac s a ee su ace, a physical si ua ion ha has been analysed by e.g. Wilson (1989), Ross & Hicks (2019)and Moo e (2021), using Wagne ’s o iginal ideas (Wagne 1932). Again, back in he con ex o d ops alling o e a wall, Duchemin & Josse and (2011) de eloped a bounda y in eg al me hod coupled wi h simpli ied lub ica ion equa ions o he gas low, and epo ed nume ical esul s o he minimum ilm hickness ha did no ollow he p edic ions in Mand e e al. (2009), Mani e al. (2010)and Mand e & B enne (2012). F om he pu ely expe imen al poin o iew, and making use o high-speed imaging echniques, Chand a & A edisian (1991)and Tho oddsen e al. (2005)we e he i s o epo he shape and hickness o he bubble en apped a he cen e o he d op, whe eas Kolinski, Mahade an & Rubins ein (2014b) epo ed expe imen al da a on he ime- a ying minimum ilm hickness, and desc ibed wha hey called he li -o mechanism, which akes place when a d op ska es o e a nanome ic gas ilm, inding ha his e ec depends on he gas o liquid iscosi y a io. Ve y ecen ly, Chan elo & Lohse (2021,2023) ex ended he p e ious expe imen al s udies o he case o supe hea ed subs a es, epo ing measu emen s o he minimum ilm hickness as a unc ion o he impac eloci y and o he subs a e empe a u e, and hey scaled and in e p e ed hei own da a using he ideas in Mand e e al. (2009)and Mand e & B enne (2012). Recen ly, Go dillo & Riboux (2022) p esen ed a physical model based on he idea ha bo h he liquid p essu e g adien and he componen o he liquid eloci y along he angen di ec ion o he wall d i e he gas low wi hin he spa io- empo al egion whe e he dis ance be ween he liquid and he solid is minimum. One o he main esul s o Go dillo & Riboux (2022), who made ex ensi e use o Wagne ’s heo e ical amewo k (Wagne 1932), is ha he classical lub ica ion mechanism, by which he Coue e and Poiseuille low a es a e in balance in he sligh ly con e ging geome y o med be ween he d op and he wall, p e en s he liquid con ac ing he solid p o ided ha he minimum gas laye 980 A35-2 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess The ska ing o d ops impac ing o e gas o apou laye s hickness calcula ed in his way is la ge han he heigh o he subs a e aspe i ies o o he in e acial co uga ions (Kim e al. 2011; Kolinski, Mahade an & Rubins ein 2014a; Chan elo & Lohse 2021). The s udy by Go dillo & Riboux (2022) p esen esul s ha di e om hose in Mand e e al. (2009), Mand e & B enne (2012)and Chan elo & Lohse (2021,2023), hence one o he main pu poses in his con ibu ion will be o deciphe which o he wo p edic ions o he minimum ilm hickness co esponding o he case o non-hea ed subs a es (i.e. ei he he one gi en in Mand e e al. (2009), Mani e al. (2010)and Mand e & B enne (2012), o he one deduced in Go dillo & Riboux (2022)) is in be e ag eemen wi h nume ical simula ions ca ied ou using Basilisk (Popine 2015) in he limi in which he Knudsen numbe Kn de ined in e ms o he gas ilm hickness is ze o, namely, when gas kine ic e ec s a e absen (Sp i les 2024). I could appea ha he main con ibu ion he e is no hing bu a con i ma ion o al eady published esul s, bu his is no he case. Indeed, he e we will also p o ide a quan i a i e explana ion o he so-called li -o mechanism i s desc ibed by Kolinski e al. (2014b), by which he minimum hickness o he gas ilm inc eases in ime a e he dis ance o he wall has eached a minimum. In spi e o se e al con ibu ions in he li e a u e on he subjec , some o which a e e y ecen (see e.g. Mish a, Rubins ein & Ryc o 2022), we ha e no ound any physical desc ip ion o heo y aimed a explaining and quan i ying he o iginal obse a ions made by Kolinski e al. (2014b). Then he e we deduce equa ions o he ime-dependen wid h o he gas laye whe e he liquid p essu e is maximum, inding ha ou p edic ions ag ee wi h he nume ical esul s,which –as has been poin ed ou in he pa ag aph abo e – ha e been ob ained in he ideal limi in which he Knudsen numbe cha ac e izing he low in he hin gas ilm is ze o. This con ibu ion also con ains a compa ison be ween ou p edic ions and he expe imen s epo ed by de Rui e e al. (2012)and Chan elo & Lohse (2023) o he case o a non-hea ed subs a e, wi h such a compa ison con aining wo undamen al di e ences om he analogous analysis epo ed in Go dillo & Riboux (2022). Indeed, he minimum ilm hickness is calcula ed he e using an equa ion ha has been alida ed p e iously by means o nume ical simula ions ca ied ou in he ideal limi Kn =0. Bu , in addi ion, in o de o compa e wi h expe imen s, we e ain in he algeb aic exp ession o he minimum ilm hickness he e ec o Kn by eplacing he ac ual gas iscosi y wi h he exp ession o he e ec i e gas iscosi y deduced by Zhang & Law (2011). The good ag eemen be ween ou p edic ions –which do no include any kind o adjus ing pa ame e since he only ee cons an will be de e mined using idealized nume ical simula ions – and expe imen s indica e ha , as was poin ed ou al eady by Li (2016)and Chubynsky e al. (2020), gas kine ic e ec s a e essen ial o p edic he dynamics o impac ing d ops ha ska e o e a gas laye ; in addi ion, hese esul s p o ide u he suppo o ou physical desc ip ion which, as i was poin ed ou abo e, di e om he one gi en in Mand e e al. (2009), Mand e & B enne (2012)and Chan elo & Lohse (2021,2023). Mo eo e , he p edic ions in Go dillo & Riboux (2022) o he cases o d ops impac ing a supe hea ed subs a e – namely, a subs a e wi h a empe a u e la ge han he boiling empe a u e o he liquid – will be compa ed wi h he expe imen al da a epo ed by Chan elo & Lohse (2021,2023) once gas kine ic e ec s a e aken in o accoun h ough he exp essions o he e ec i e gas iscosi y and he e ec i e he mal conduc i i y epo ed by Zhang & Law (2011) and Sha ipo , Cumin & Kalempa (2007), espec i ely. Le us poin ou clea ly he e ha i is no he pu pose o his con ibu ion o desc ibe he con ac be ween he liquid and he solid, i.e. he so-called ouchdown p oblem, which 980 A35-3 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess P. Ga cía-Geijo, G. Riboux and J.M. Go dillo Domain 2.1R Pa, Ta Ts 2.1R z0 ρ, μ R U z Figu e 1. Ske ch showing he axisymme ic domain whe e he nume ical simula ions ha e been ca ied ou using Basilisk (Popine 2015); see Appendix A o de ails. He e, and z, espec i ely, indica e he dis ance o he axis o symme y and he dis ance o he wall in a cylind ical coo dina e sys em. The nume ical box is a squa e o leng h 2.1R. emains an open ques ion due o he ac ha ei he he con ac o he ebound o a d op impac ing a solid depends on a numbe o ac o s, such as he subs a e oughness, he p esence o con aminan s a he ee in e ace, asymme ies, an de Waals o ces,o e en elec os a ic e ec s (Kim e al. 2011; Kolinski e al. 2014a; Sp i les 2024), which lead o di e ences on he ins an a which he gas ilm des abilizes unde e y simila expe imen al condi ions;see e.g. Kolinski e al. (2014a)and de Goede e al. (2019). The explana ion o hese di e ences is ou side he scope o his con ibu ion, which is hen ocused in he desc ip ion o hose egimes in which a d op impac ing a solid subs a e, which migh be hea ed abo e he boiling poin o he liquid o no , ska es o e a hin gas ilm, his being a subjec o ecen in e es in he li e a u e (Sp i les 2024). The manusc ip is s uc u ed as ollows.Sec ion 2is de o ed o p esen ing he esul s o nume ical simula ions ca ied ou using Basilisk (Popine 2015). In § 3,we e iew he physical model p esen ed in Go dillo & Riboux (2022), and compa e ou own p edic ions and hose in Mand e & B enne (2012)and Chan elo & Lohse (2023) wi h he nume ical esul s. Taking in o accoun gas kine ic e ec s, in § 4we compa e ou p edic ions o he minimum gas ilm hicknesses wi h he expe imen al alues gi en in de Rui e e al. (2012)and Chan elo & Lohse (2023). Finally, §5summa izes he main esul s in his con ibu ion. 2. Nume ical esul s co esponding o he case o iso he mal subs a es This sec ion is de o ed o p esen ing he esul s o simula ions ca ied ou using Basilisk (Popine 2015) in he nume ical domain depic ed in igu e 1, which shows a d op o adius Ro a liquid wi h densi y ρ, iscosi y μ, and in e acial ension coe icien σ, alling wi h uni o m eloci y Uagains a wall whose empe a u e Tsis equal o ha o he gas, Ts=Ta (iso he mal subs a e);see Appendix A o de ails on he nume ical implemen a ion. Using R,R/Uand ρU2as he cha ac e is ic alues o leng h, ime and p essu e, he nume ical esul s in his sec ion will be exp essed in e ms o he S okes and Webe numbe s de ined as S =ρUR μa ,We =ρU2R σ,(2.1a,b) 980 A35-4 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess The ska ing o d ops impac ing o e gas o apou laye s (a)(b) h/R p/(ρU2) 1.0 3(×10–3) 2 1 0 0 0.1 τ = 5 τ = 8 τ = 12 τ = 20 τ = 40 = aˉ 0.2 0.3 0.4 0 0.2 0.4 /R 0.6 0.8 1.0 0 0.05 0.10 0.15 /R 0.20 0.25 0.30 0.35 0.40 15 10 5 0.8 0.6 0.4 0.2 = 3s R τ = 5 τ = 8 τ = 12 τ = 20 τ = 40 = aˉ Figu e 2. (a) Time-e ol ing shapes o a d op impac ing a wall wi h We =12 and S =2.6×104.Theinse shows he geome y o bo h he gas pocke and he egion, loca ed a /R=√3s(solid line), whe e he d op ska es o e a hin gas laye . No ice ha he adial posi ion whe e he maximum gas p essu e is a ained, =¯a (dashed line), e i ies ¯a≈R√3s.(b) Spa io- empo al e olu ion o he gas p essu e a he wall co esponding o he alues o We and S o (a). The alues o ∂p/∂ a he spa io- empo al egion whe e he gas p essu e is maximum a e calcula ed as he slopes o he solid lines in he igu e. and a ied wi hin he anges 9 ×103≤S ≤4.5×104,4≤We ≤60, while keeping ixed he alues o he a ios ρa/ρ =10−3and μa/μ =1.8×10−2,wi hρaand μaindica ing he gas densi y and iscosi y, espec i ely. Fo simplici y, nei he comp essibili y no gas kine ic e ec s ha e been e ained in he nume ical simula ions,which, as has been poin ed ou abo e, ha e been ca ied ou o he case o iso he mal subs a es. The nume ical esul s depic ed in igu e 2(a) e eal ha as he d op app oaches he wall, a dimple is o med a he axis o symme y, en apping a nea ly cylind ical gas pocke wi h adius ∝√Rhdand hickness hd.Figu e 2 also shows ha he liquid does no ouch he solid bu , ins ead, ska es o e a hin gas ilm whose minimum hickness hmin hdis a ained a ∝√Rhd. The hickness o he en apped bubble, hd, is deduced om he mass balance (Mand e e al. 2009; Bouwhuis e al. 2012) πU(Rhd)∼2πRhd h3 d 12μa pd √Rhd ,(2.2) whe e i has been aken in o accoun ha he gas low a e pe uni leng h induced by he p essu e jump pd=p( =z=0, )−Pais pd∝(h3 d/μa)(pd/√Rhd).Since in a i s app oxima ion he liquid eloci y ield wi hin he d op is i o a ional, he Eule –Be noulli equa ion pa icula ized a =0, z=hdyields (Bouwhuis e al. 2012) pd∼ρ∂φ ∂ ,(2.3) whe e φ∝U√Rhdis he alue o he eloci y po en ial a =0 c ea ed by a disk o adius √Rhdmo ing in o he liquid wi h a eloci y U;see e.g. Pe e s, an de Mee & Go dillo (2013). Then since he dimple is o med in a cha ac e is ic ime hd/U, he p essu e jump deduced om (2.3) eads pd∝ρU2√R/hd, om which, using (2.2), we ob ain hd∝RS −2/3;(2.4) 980 A35-5 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess P. Ga cía-Geijo, G. Riboux and J.M. Go dillo (a)(b) (c)(d) p/(ρU2) h/R 0 0 3(×10–3) 15 12 9 6 3 2 1 0.05 0.10 0.15 0.20 0.25 0 p/(ρU2) 15 12 9 6 3 0 p/(ρU2) 15 12 9 6 3 0.05 0.10 0.15 0.20 0.25 0.05 0.10 /R 0.15 0.20 0.25 00.05 0.10 /R 0.15 0.20 0.300.25 τ = 20 = aˉ (hmin)/R = 3s R Figu e 3. (a) Gas laye hickness h( )/Ra τ=20 o We =12 and S =2.6×104. The adial posi ion whe e he minimum ai ilm hickness is a ained, (hmin)/R(do ed e ical line), he adial posi ion whe e he maximum p essu e is eached, /R=¯a/R(dashed e ical line), and he we ing adius, /R=√3s(solid e ical line), a e indica ed. Values o he gas p essu e jump a he wall o he ollowing ins an s o ime: (b) τ=12, (c)τ=15, and (d)τ=20. hen he dimple is o med in a cha ac e is ic ime gi en by  d∝hd U→ dU R∝hd R∝S −2/3.(2.5) Hence, aking he o igin o imes a he ins an when he d op would con ac he subs a e i he gas we e no p esen , and de ining he dimensionless imes sand τas s= U R,τ=S 2/3s=S 2/3 U R,(2.6a,b) he esul in (2.5) indica es ha he dimple is o med a he ins an o ime τ=τ∗,wi h τ∗≈12 (Go dillo & Riboux 2022). Figu e 2(b) shows he spa io- empo al e olu ion o he gas p essu e a he wall i.e. a z=0. Fo a ixed alue o τ, he esul s in igu e 2(b) e eal ha he gas p essu e inc eases adially, eaching a maximum a an o -cen e posi ion ha mo es owa ds la ge alues o as ime p og esses. In addi ion, igu e 2 shows ha he maximum gas p essu e a he wall, and also he alues o he local p essu e g adien a he adial posi ion whe e he maximum p essu e is loca ed, inc ease wi h τ, eaching a maximum a τ=τ∗≈12. Mo eo e , he esul s in igu e 3 e eal ha he maximum gas p essu e and he maximum p essu e g adien , calcula ed as he slope o he lines depic ed in igu e 2(b), a e eached a he adial posi ion =a(s)=R√3s,(2.7) namely, a he adius o he ci cula egion ha is we ed by a d op impac ing wi h eloci y Uo e a wall, a esul ha was checked ca e ully agains expe imen s and was deduced in Riboux & Go dillo (2014) in he con ex o d op impac using Wagne ’s 980 A35-6 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess The ska ing o d ops impac ing o e gas o apou laye s 0 0.5 hmin/R 1.0 1.5 10 20 30 40 τ 0 0.5 hm/R 1.0 1.5 10 20 30 40 P e-impac We = 12, S = 1.2 × 104 We = 4, S = 3 × 104 We = 12, S = 2.6 × 104 We = 22, S = 2.1 × 104 We = 36, S = 2.6 × 104 We = 48, S = 1.8 × 104 We = 48, S = 3.6 × 104 We = 60, S = 1.8 × 104 τ (×10–3) (×10–3) (a)(b) Figu e 4. Time e olu ion o (a) he minimum gas laye hickness hmin,and(b) he hickness o he gas laye measu ed a /R=√3s,hm=h( =R√3s), co esponding o he alues o We and S indica ed in he legend. The p e-impac s age τ<12 is highligh ed in blue. heo e ical amewo k (Wagne 1932). Indeed, Wagne ’s heo y, which has been known o nea ly a cen u y in he con ex o wa e en y p oblems, pe mi s us o deduce he esul in(2.7) in a qui e s aigh o wa d manne ; see also Wilson (1989), whe e (2.7) was deduced in he con ex o ship slamming. Reade s in e es ed in he igo ous applica ion o Wagne ’s heo y (Wagne 1932) o di e en physical phenomena using ma ched asymp o ic echniques a e di ec ed o Ko obkin & Pukhnacho (1988), Wilson (1989), Howison, Ockendon & Wilson (1991), Scolan & Ko obkin (2001), Oli e (2002), Ko obkin & Scolan (2006)and Moo e (2014). The esul s in igu e 3 also sugges ha in spi e o he minimum gas ilm hickness hmin(τ) is no a ained a he adial posi ion whe e he maximum gas p essu e is eached, namely, hm(τ) /=hmin(τ ),wi h hm(τ) =h( =a(s)), (2.8) hm(τ) ≈hmin(τ);see igu e 2(a). This esul is app ecia ed mo e clea ly in igu e 4, which p o ides he alues o hm(τ) and hmin(τ) o di e en alues o he Webe and S okes numbe s explo ed in his s udy. Indeed, igu e 4 e eals ha hmin(τ) =hm(τ ) o he ins an s o ime (highligh ed in blue in igu e 4)τ≤τ∗, and also ha hm(τ) > hmin(τ ) o τ>τ ∗. Due o he ac ha he alues o he maximum gas p essu e, he maximum p essu e g adien and also he minimum o hm(τ) a e a ained a τ=τ∗, he ins an s o ime τ<τ ∗will be e med, in wha ollows, as p e-impac s age, whe eas hose co esponding o τ>τ ∗will be e e ed he e as pos -impac s age; see also he ime-e ol ing dimple shapes included as an inse o igu e 2(a). Hence he e we will conside ha he ‘impac ’ akes place when he maximum p essu e is a ained a τ=τ∗,so, using he esul in (2.6a,b)–(2.7), his e en is localized a he adial posi ion =R√3τ∗S −2/3≈6RS −1/3; he e o e he minimum hickness o he gas ilm is a ained a he dimensionless ins an τ=τ∗≈12 and a he dimensionless adial posi ion /R≈6S −1/3. The di ision o he impac p ocess in o wo well-de ined s ages is c ucial o unde s anding he di e ences be ween he p esen analysis and he p edic ions in Mand e & B enne (2012)and Chan elo & Lohse (2021,2023), who desc ibe he ins an s p e ious o he ‘impac ’, namely, he p e-impac s age aking place o τ<τ ∗. In con as , he p edic ions in Go dillo & Riboux (2022) we e deduced wi h he pu pose o desc ibing bo h he impac and he pos -impac s ages, and he e o e should be applicable o quan i y he di e en e en s aking place o τ≥τ∗. 980 A35-7 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess P. Ga cía-Geijo, G. Riboux and J.M. Go dillo 3.0 0 1 2 ||u /U|| = 5 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 ( – a¯)/h ¯a z/z(1) 3.0 0 1 2 3.5 4.0 4.5 5.0 5.5 6.02.0 2.5 z/z(1) (a) (b) Figu e 5. Radial componen o he dimensionless gas eloci y ield, u /U, ep esen ed in he ame o e e ence mo ing wi h he we ing eloci y Vmgi enin(3.3) o h ee di e en alues o ( −¯a)/¯ haand wo di e en ins an s o ime: (a)τ=20 and (b)τ=40. He e, ¯a≈R√3sindica es he adial posi ion whe e he maximum gas p essu e is a ained (see igu e 3)and¯ ha=2/(9π)¯a3≈ha,m,wi hha,mgi en in (3.4). He e, We =12, S =2.60 ×104, whe eas z(1)indica es he e ical coo dina e o he in e ace a he minimum alue o ( −¯a)/¯ ha ep esen ed in he igu e. The nex sec ion is de o ed o checking which o he p edic ions o he minimum ilm hickness – ei he he ones deduced in Mand e & B enne (2012) o hose in Go dillo & Riboux (2022)– a e in be e ag eemen wi h he nume ical esul s. 3. Modelling he impac o d ops o e iso he mal subs a es 3.1. Re iew o p e ious esul s The p edic ions in Mand e & B enne (2012), la e ex ended by Chan elo & Lohse (2021,2023) o he case o supe hea ed subs a es, a e based on he ollowing idea: he minimum gas ilm hickness is a ained when a sel -simila solu ion desc ibing he p e-impac s age a he egion whe e he dis ance o he wall is minimum, ails o p edic he low o τ≥τ∗because he capilla y and con ec i e e ms in he momen um equa ion, ini ially neglec ed, become o he o de o he dominan e ms in he app oxima e solu ion. Hence, as a as we unde s and, he esul s in Mand e e al. (2009), Mand e & B enne (2012)and Chan elo & Lohse (2021,2023) ha e been deduced using an a gumen ha nei he desc ibes no iden i ies he physical mechanism ha p e en s he con ac be ween he liquid and he wall. In con as , he physical model in Go dillo & Riboux (2022) desc ibes he lub ica ed impac o a d op o e a wall o ins an s o ime τ≥τ∗. The physical idea behind he p edic ions in Go dillo & Riboux (2022) elies on he well-known lub ica ion mechanism depic ed in igu e 5, whe e he gas eloci y ield calcula ed nume ically along he egion whe e he gas p essu e is maximum, is ep esen ed in a ame o e e ence mo ing wi h he we ing eloci y a which he local maximum p essu e p opaga es adially ou wa ds, 980 A35-8 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess The ska ing o d ops impac ing o e gas o apou laye s namely (see igu es 2 and 3) Vm(s)=da d =U 23 s,(3.1) whe e he subsc ip mis used o deno e he alues o quan i ies pa icula ized a =a(s); see (2.7). Figu e 5 shows ha in he mo ing ame o e e ence, he gas eloci y ield can be exp essed as he supe posi ion o he Poiseuille (pa abolic) eloci y p o ile induced by he a ou able p essu e g adien poin ing adially ou wa ds, owa ds he a mosphe e (see igu e 2b), plus he Coue e (linea ) eloci y p o ile caused by he ela i e mo ion be ween he poin o maximum p essu e and he wall, which is di ec ed owa ds he axis o symme y. No ice ha he poin o maximum p essu e is a ained a he adial posi ion whe e he liquid in e acial eloci y in he labo a o y ame o e e ence equals he eloci y o he mo ing ame o e e ence; see e.g. Wagne (1932)and Go dillo & Riboux (2022). Hence, o he case o iso he mal subs a es, he dis ance be ween he d op and he wall a =a(s)du ing he ins an s close o he one o which he minimum ilm hickness is a ained, can be quan i ied h ough he equa ion (Go dillo & Riboux 2022) −h3 m 12μa ∂p ∂ −Vmhm 2≈0.(3.2) Non-con inuum e ec s, which could ha e been e ained in (3.2) by conside ing alues o he slip leng hs a he in e ace and a he wall di e en om ze o (see e.g. Duchemin & Josse and (2012)and Riboux & Go dillo (2014)), will be conside ed in § 4using he app oach de ailed in Li (2016) in his nume ical s udy o he head-on collision o d ops. This app oxima ion consis s in modi ying he alue o he ac ual iscosi y by using he equa ion o he e ec i e iscosi y deduced in Zhang & Law (2011), which depends explici ly on he Knudsen numbe de ined in e ms o he gas ilm hickness. While gas kine ic e ec s need o be e ained in o de o compa e ou p edic ions wi h expe imen s, an de Waals e ec s can be neglec ed sa ely in he modelling because hese o ces become ele an only when hm20 nm (Sp i les 2024), namely, o alues o he gas ilm hicknesses ha a e well below hose measu ed expe imen ally by de Rui e e al. (2012) o he case o iso he mal impac s, and by Chan elo & Lohse (2021,2023) o he case o d ops impac ing he wall in he dynamic Leiden os egime. No ice ha (3.2) exp esses ha he alue o he Poiseuille low a e pe uni leng h induced by he la ge p essu e g adien gene a ed a ound =a(s)(see igu e 3) needs o be balanced by he Coue e low because, o he wise, he gas benea h he egion whe e he p essu e is maximum would low adially ou wa ds, emp ying his olume, and consequen ly he liquid would make con ac wi h he wall. In o de o deduce an equa ion o hm, he nex s ep ha we ollowed in Go dillo & Riboux (2022) was o make use o he ac ha he e ical in e acial eloci ies du ing τ≥τ∗a e much smalle han he impac eloci y,i.e.(1/U)∂h/∂ 1, and also ha he gas ilm is slende , ∂h/∂ 1. In his way, since he Reynolds numbe e i ies Re =S μa/μ 1, and hence he p oduc ion o o ici y a he gas–liquid in e ace is con ined wi hin small bounda y laye s, he liquid eloci y and p essu e ields can be app oxima ed by he i o a ional alues calcula ed using Wagne ’s heo e ical amewo k Wagne (1932). A his poin , no ice ha he condi ion (1/U)∂h/∂ 1 also implies ha dhm/d Vmhm–wi h indica ing he cha ac e is ic leng h along which hm a ies,o he o de o ∼hm– due o he ac ha >hmand also because Vm∝US 1/3U, his being he eason why he e m dhm/d has been neglec ed in he mass balance (3.2). 980 A35-9 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess P. Ga cía-Geijo, G. Riboux and J.M. Go dillo in Go dillo & Riboux (2022) ha he hea lux ac oss he liquid he mal bounda y laye can be neglec ed o he pa icula case o he expe imen s epo ed in Chan elo & Lohse (2021,2023). The e o e, he equa ion analogous o (3.2) o he case o d ops impac ing o e supe hea ed subs a es eads −h3 m 12μ ∂p ∂ −Vmhm 2≈k T ρ L  hm ,(4.2) whe e we ha e made use o (4.1). The subs i u ion o (3.3)–(3.6)in o(4.2) yields he ollowing equa ion o hm/R: y−1+1 6 μa μ y=β∗,(4.3) wi h y=S 2(/R) Vm Uhm R2 and β∗=βρ ρ μ μa,whe e β=k T μ L.(4.4) Consequen ly, hm R=2yS −1Vm U−1 R1/2 ,(4.5) wi h y=3μ μa1+1+2β∗ 3μa μ .(4.6) The subs i u ion o (4.6) and o ei he (3.4)o (3.8)in o(4.5)p o ides he same exp essions as hose gi en in (3.17), which a e hen alid o desc ibe he ska ing o d ops o e ei he a gas o a apou laye , he only di e ence being ha y=6 o he case o iso he mal impac s, whe eas yis gi en by (4.4)and(4.6) o he cases o d ops impac ing a subs a e in he dynamic Leiden os egime. Hence ou physical desc ip ion di e s subs an ially om ha o Chan elo & Lohse (2021,2023), who deduce di e en equa ions depending on whe he he subs a e is supe hea ed o no , he e o e he iso he mal case canno be eco e ed using hei esul s co esponding o supe hea ed subs a es in he limi in which he p oduc ion o apou ends o ze o. The ecen e iew on he subjec by Sp i les (2024)s a es clea ly ha gas kine ic e ec s canno be neglec ed in he desc ip ion o he head-on collision o d ops (Li 2016)o in he impac o d ops on a subs a e (Riboux & Go dillo 2014; Chubynsky e al. 2020)i he alue o he Knudsen numbe , de ined as Kn =λ hm ,(4.7) wi h λdeno ing he mean ee pa h o he gas, becomes Kn 0.1, which is he case o in e es he e. Indeed, he ypical alues o he gas ilm hickness in he expe imen s epo ed by de Rui e e al. (2012) and Chan elo & Lohse (2021,2023) a y be ween 103 980 A35-16 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess The ska ing o d ops impac ing o e gas o apou laye s and 102nanome es, whe eas he alues o he mean ee pa h o ai and e hanol a no mal condi ions a e, espec i ely, λa≈69 nm and λe h ≈50 nm.(4.8a,b) Then, in o de o accoun o gas kine ic e ec s, we de ine an e ec i e gas iscosi y μ∗(Kn)(Sp i les 2024) and make use o he exp ession deduced by Zhang & Law (2011), employed success ully by Li (2016) in his s udy o he head-on collision o d ops: μ∗=μ 1+6.0966 Kn +0.9650 Kn2+0.6967 Kn3,(4.9) whe e μ e e s o he alue o he ac ual gas iscosi y. No ice ha o hecaseo d ops impac ing a non-hea ed subs a e, μ in (4.6) e e s o he e ec i e ai iscosi y, namely, μ =μ∗ a(see (4.9)), whe eas he Knudsen numbe de ined in (4.7) is calcula ed using he alue o he mean ee pa h gi en by λ=λa Pa Pa+pm ,(4.10) wi h λaand pmgi en, espec i ely, in (4.8a,b)and(3.5). Fo he case o d ops impac ing a supe hea ed subs a e, μ =μ∗ e h and λ=λe h Pa Pa+pm 273 +0.5(Tb+Ts) Ta ,(4.11) wi h Ta=298 K, and Tb=78 and Ts e e o he alues in Celsius o he boiling empe a u e o e hanol and o he subs a e empe a u e, espec i ely. Fo he case o d ops impac ing a supe hea ed subs a e, he e we also include gas kine ic e ec s in he hea ans e om he wall in o he liquid, making use o he e ec i e hea conduc i i y o he apou gi en by (Sha ipo e al. 2007) k∗ =k 1+3.91 Kn.(4.12) As poin ed ou in he In oduc ion, an de Waals e ec s a e no e ained in he analysis because in all he expe imen al esul s epo ed by de Rui e e al. (2012)and Chan elo & Lohse (2021,2023), he gas ilm hickness is well abo e 20 nm, which is he leng h scale below which hese o ces become ele an (Sp i les 2024). 4.2. Compa ison wi h expe imen s The compa ison wi h he nume ical esul s in §3con i ms ou physical desc ip ion,andi is now ou pu pose in his subsec ion o check whe he ou esul s, once gas kine ic e ec s a e aken in o conside a ion, can also be used o p edic he expe imen al da a epo ed by de Rui e e al. (2012) and Chan elo & Lohse (2021,2023) o d ops impac ing o e ei he iso he mal o supe hea ed subs a es. The equa ions gi en in (4.6)and(3.17) can be used o p edic he minimum gas ilm hickness o a bi a y alues o Ts. Howe e , he uni ied desc ip ion o he ska ing o a d op o e a gas o apou ilm p o ided by (4.6)and(3.17) also equi es us o in oduce he e ec o he apou p oduced a he dimple on he ins an o ime τ∗a which he cen al bubble is o med, i.e. a he ins an when he minimum ilm hickness is a ained a ≈RS −1/3√3τ∗. 980 A35-17 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess P. Ga cía-Geijo, G. Riboux and J.M. Go dillo Then, o he case o supe hea ed subs a es, he e m on he le -hand side o he mass conse a ion equa ion (2.2) needs o be modi ied in o de o ake in o accoun he e apo a ion o he liquid. Consequen ly, in his case, he low a e ha needs o be e acua ed adially ou wa ds om he axis o symme y is π(Rhd)(U+k T/(ρ hdL)). The e o e, exp essing hd/R=τ∗S −2/3and ollowing he same s eps as hose de ailed in §3, he mass balance (2.2)p o ides he ollowing equa ion o τ∗(Go dillo & Riboux 2022): τ∗5/2=12.43/2τ∗+β∗S −1/3,(4.13) wi h β∗de ined in (4.4). No ice ha (4.13) eco e s he alue o τ∗≈12 co esponding o he case o iso he mal subs a es, o which β∗=0. Be o e compa ing ou p edic ions wi h he expe imen al alues p o ided in de Rui e e al. (2012) and Chan elo & Lohse (2021,2023), i is i s necessa y o exp ess he eal empe a u e-dependen ma e ial p ope ies o he gas and o he apou as unc ions o he subs a e empe a u e. This is done he e using he Py hon ou ines p o ided as supplemen a y ma e ial a ailable a h ps://doi.o g/10.1017/j m.2024.20, which implemen (3.17), (4.6)and (4.7)–(4.12) and make use o he alues σ=22 ×10−3Nm −1o σ=17 ×10−3Nm −1 o he in e acial ension coe icien o e hanol a ei he oom o boiling empe a u e, wi h hese alues aken om www.ddbs .com. No ice ha all he ma e ial p ope ies a e quan i ied a he mean empe a u e (Tb+Ts)/2as de ailed in Go dillo & Riboux (2022),and his is e lec ed in he Py hon ou ines p o ided as supplemen a y ma e ial. Le us poin ou he e ha we ha e no conside ed he e ec o Ma angoni s esses in ou physical model because he liquid loca ed a a dis ance hm om he wall is e apo a ing along a egion o leng h , he e o e he in e acial empe a u e emains cons an and equal o he boiling empe a u e o he liquid a he egion o in e es he e, namely, whe e he minimum ilm hickness is a ained. Figu e 8 e eals ha he minimum gas ilm hickness can be p edic ed using he equa ions co esponding o he capilla y o ine ial limi s in (3.17)and (4.4)–(4.12)wi h ela i e e o s ∼30%. Fo he case o iso he mal subs a es, he p edic ed alue o he minimum ilm heigh has been calcula ed in igu e 8 e aining gas kine ic e ec s and using he capilla y limi in (3.17)wi hA=3.5, namely, he alue deduced om igu e 6 o he case o d ops impac ing a wall a oom empe a u e in he ideal case Kn =0. Hence o he case o subs a es a oom empe a u e, we conclude ha he expe imen al da a can be app oxima ed using he equa ion (see (3.17)) hm R≈3.5×6μ∗ a μa2/3 122/3We−1/3S −10/9,(4.14) wi h μ∗ a=μ∗de ined in (4.9). Figu e 8 also compa es he expe imen al measu emen s in Chan elo & Lohse (2021,2023) wi h ou p edic ions. In his case, since he apou laye p e en s con ac be ween he liquid and he wall, a ansi ion be ween he capilla y and ine ial egimes in (3.17) is obse ed when he impac eloci y inc eases. In his case, he equa ions o he minimum ilm hickness used in he compa isons o igu e 8 a e (see (3.17)) hm R≈2.3y2/3τ∗2/3We−1/3S −10/9(4.15) 980 A35-18 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess The ska ing o d ops impac ing o e gas o apou laye s 0.2 0.3 0.4 0.6 U (m s–1) 1.0 0 0.5 1.0 1.5 2.0 2.5 3.0 123456 0.1 0.3 0.4 0.6 1.0 0.2 0.3 0.4 0.6 hm (µm)hm (µm) hm/h h hm/h h 1.0 0 0.5 1.0 1.5 2.0 2.5 3.0 123456 0.1 0.3 0.4 0.6 1.0 ξ (τ∗/12.4) Ts = 105 °C Ts = Ta, DeR Ts = 295 °C, B = 1.25 Ts = 295 °C, B = 1.70 Ts = 295 °C, B = 1.15 Ts = 295 °C, B = 1.70 Ts = Ta, C&L Ts = 144 °C Ts = 178 °C Ts = 230 °C Ts = 270 °C Ts = 295 °C (a)(b) (c)(d) Figu e 8. (a) Compa ison be ween he p edic ions gi en in (4.14)–(4.16) and he alues o he minimum hickness o he ai o apou laye s measu ed by de Rui e e al. (2012) (DeR) and Chan elo & Lohse (2023) (C&L) o di e en alues o he impac eloci y Uand o di e en alues o he subs a e empe a u e Ts. He e, he alues o he e ec i e gas iscosi y and he e ec i e gas conduc i i y ha e been modi ied aking in o accoun kine ic e ec s h ough (4.7)–(4.12). Solid lines ep esen he p edic ions o hmco esponding o he capilla y egime, whe eas he p edic ions o hmin he ine ial egime a e ep esen ed using dashed lines. (b) Compa ison be ween he p edic ed and measu ed alues o hmin (a) as a unc ion o ξ.(c) The expe imen al da a a e compa ed he e only wi h he p edic ions gi en by (4.16). In his case, he alue o he p e ac o is 1.15 ins ead o 1.25. (d) Compa ison be ween he p edic ed and measu ed alues o hmin (c) as a unc ion o ξ.The dashed ho izon al lines in (b,d) a e placed a 1 ±0.3. and hm R≈1.25τ∗S −7/6y1/2(4.16) o he capilla y and ine ial egimes, espec i ely. In (4.15)–(4.16), yis gi en by (4.6), τ∗has been calcula ed using (4.13), and gas kine ic e ec s ha e been quan i ied h ough (4.7)–(4.12). The alue o he p e ac o in (4.15), co esponding o he capilla y limi in (3.17), di e s om ha in (4.14). This could be due o he di e ences in he local geome y o he in e ace o ≈a; indeed, he expe imen s in igu e 3 o Chan elo & Lohse (2021) show ha he cu a u e o he in e ace nea ≈a o he case o Leiden os d ops inc eases wi h Ts(see also Kolinski e al. 2014b), a ac implying ha he p e ac o a ec ing in (4.5) o he case o supe hea ed subs a es should be smalle han o he case o iso he mal impac s. No ice also ha since he local cu a u e is e y much dependen on whe he he subs a e is supe hea ed o no , i could also be he case ha deRui e e al. (2012)and Chan elo & Lohse (2023)p o ide he expe imen al alues o hmin(τ =12) o he case o iso he mal subs a es, whe eas Chan elo & Lohse (2021,2023)p o ide hm(τ ≈12) o he case o supe hea ed subs a es; in ha case, he alue o he cons an in (4.15) would be e y simila o he one in (3.19). Figu es 8(c,d) 980 A35-19 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess P. Ga cía-Geijo, G. Riboux and J.M. Go dillo also show a compa ison be ween he p edic ed and measu ed minimum ilm hicknesses unde he app oxima ion ollowed in Go dillo & Riboux (2022), whe e we conside ed ha he minimum ilm hickness could be p edic ed using he ine ial app oxima ion gi en in (4.16). In his case, igu es 8(c,d)show ha he expe imen al measu emen s by Chan elo & Lohse (2021,2023) can be p edic ed easonably well, wi h ela i e e o s ±30 %, using a alue1.15 o he p e ac o in (4.16), which is e y simila o ha deduced om igu e 6. No ice also ha igu e 8 also includes he p edic ed minimum ilm hickness co esponding o he la ges empe a u e, Ts=295 ◦C, when he alue o he p e ac o in (4.16)is a ied om 1.25 o 1.7. A possible eason why an inc ease in he alue o he p e ac o imp o es he compa ison wi h he expe imen al da a o he case o he highes subs a e empe a u e could be he ac ha he slende app oxima ion unde which (3.17)a ededuced b eaks o su icien ly la ge alues o Ts. Indeed, he pa ame e exp essing he a io be ween he minimum ilm hickness and he leng h along which he p essu e g adien s in he liquid ake place, namely, hm ha,m≈y1/2S −1/6,(4.17) whe e we ha e made use o (3.4)and(4.16), could become la ge han uni y o subs a e empe a u es Tsexceeding he h eshold alue gi en by he condi ion (see (4.17)) y2S 2/3⇒k (Ts−Tb) μ Lρ ρ S 2/3,(4.18) whe e use o (4.6) has been made. The esul s depic ed in igu e 9 e eal ha , indeed, he spa ial egion whe e he maximum p essu e g adien is a ained is clea ly no slende o he la ge alue o Tsbecause he ilm hickness is la ge han he leng h along which he liquid p essu e g adien akes place. In hese cases, since hm≈ha,m, he capilla y p essu e is ∼σhm/h2 a,m∼σ/ha,m, wi h his alue being simila o he liquid o e p essu e pmgi en in (3.5) because pm σ/ha,m∼We S −1/3,(4.19) which happens o be o o de uni y o he expe imen s co esponding o he la ges empe a u es epo ed by Chan elo & Lohse (2023). Then he loss o slende ness o he la ges alue o Tsimplies la ge capilla y p essu es because hmis no much smalle han ha,m, a ac also implying ha he alues o he gas p essu e g adien a e smalle han hose co esponding o he slende limi in which (3.17) ha e been deduced. A educ ion in he p essu e g adien implies la ge alues o hm(see (4.2)), and his ac could be behind he esul depic ed in igu e 8 o he case Ts=295 ◦C. Le us also poin ou ha he disc epancies be ween he p edic ions and expe imen al measu emen s o he case Ts=295 ◦C could also be o igina ed as a consequence o limi a ions in he empo al esolu ion o he expe imen s ca ied ou by Chan elo & Lohse (2023) o he highes impac eloci ies. 5. Conclusions In his con ibu ion, we ha e p esen ed nume ical simula ions alida ing he p edic ions in Go dillo & Riboux (2022), whe e we desc ibed he lub ica ion mechanism by which a d op alling o e a subs a e ska es o e a gas o apou laye . Wi h he pu pose o explaining and quan i ying he li -o mechanism epo ed empi ically by Kolinski e al. (2014b)and 980 A35-20 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess The ska ing o d ops impac ing o e gas o apou laye s 0.2 0 0.5 1.0 1.5 2.0 0.3 0.4 0.6 U (m s –1 ) 1.0 hm/ha,m Figu e 9. Ra io be ween he measu ed minimum ilm hickness and he leng h ha,mgi enin(3.4) along which p essu e g adien s ake place. The meanings o he symbols a e he same as in igu e 8. in es iga ed nume ically by Mish a e al. (2022), we ha e ex ended ou p e ious esul s and ha e p o ided equa ions, including he alues o he p e ac o s, ha ep oduce closely he ime e olu ion o he minimum ilm hickness calcula ed nume ically. Mo eo e , wi h he pu pose o compa ing ou esul s wi h he measu ed alues o he gas o apou ilm hicknesses, we ha e included gas kine ic e ec s in he algeb aic equa ions o he minimum hickness o he gas laye , inding ha ou p edic ions, up o p e ac o s, a e in good ag eemen wi h he esul s epo ed by de Rui e e al. (2012)and Chan elo & Lohse (2021,2023). Supplemen a y ma e ial. Supplemen a y ma e ial is a ailable a h ps://doi.o g/10.1017/j m.2024.20. Acknowledgemen s. J.M.G. hanks P. Chan elo and D. Lohse o ui ul discussions. Funding. This wo k has been suppo ed by he g an PID2020-115655GB-C21, inanced by he Spanish MCIN/AEI/10.13039/501100011033, and all he simula ions we e un on he High Pe omance Compu ing clus e p o ided by he Cen o In o má ico Cien í ico de Andalucía (CICA). Decla a ion o in e es s. The au ho s epo no con lic o in e es . Au ho ORCIDs. P. Ga cía-Geijo h ps://o cid.o g/0000-0001-8608-4804; G. Riboux h ps://o cid.o g/0000-0003-2395-1653; J.M. Go dillo h ps://o cid.o g/0000-0003-1431-3780. Au ho con ibu ions. P.G.-G. ca ied ou he nume ical simula ions and analysed he da a, G.R. analysed he da a and pa ly w o e he pape , and J.M.G. designed he esea ch and he heo y, and w o e he pape . All au ho s e iewed he esul s and app o ed he inal e sion o he manusc ip . Appendix A. Nume ical simula ions The nume ical esul s in § 2, which ha e been calcula ed using he ee so wa e Basilisk (Popine 2015), ex ending he ideas in he codes by Sanjay (2022)and Zhang e al. (2022), simula e he axisymme ic impac o a d op o adius Rini ially cen ed a z=1.006R, alling wi h a uni o m eloci y Uo e an impe meable ho izon al subs a e. The nume ical esul s ha e been ob ained by imposing symme y condi ions a he axis, he impene abili y and no-slip bounda y condi ions a he wall limi ing he compu a ional domain depic ed in igu e 1,and ou low bounda y condi ions a he wo emaining 980 A35-21 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess P. Ga cía-Geijo, G. Riboux and J.M. Go dillo 0.360 0.25 0 0.05 0.10 0.15 0.20 0.30 0.35 0.40 0.361 /R /R /R h/R h/R 0.362 0 0 0.5 1.0 1.5 2.0 12 1 2 3(×10–3) (a) (b)(c) Figu e 10. Each black do ep esen s he e ex o a nume ical cell, whe eas he in e ace is plo ed using a blue solid line. (a) The nume ical domain is di ided in o egions wi h di e en disc e iza ion le els: ed box, h/R<0.1and /R<1.0, wi h cell sizes Δ≥R/1950; yellow box, h/R<0.01 and /R<√3s+0.15, wi h cell sizes Δ≥R/31208. Fo he es o he nume ical domain, Δ≥R/975. (b) A close iew o he egion a ound he ad ancing on . (c) De ailed iew o he spa ial egion a ound he we ing adius =√3s( ed dashed line). He e, We =12, S =2.60 ×104and τ=0.0435 ≈38 S −2/3. bounda ies, whe e bo h he p essu e and he g adien o no mal eloci ies a e se o ze o. We ha e checked ha he nume ical esul s a e una ec ed by he dimensions o he compu a ional domain. We ha e made use o an adap i e Ca esian mesh, which e ines he solu ion bo h a he in e ace and a he egions wi h he la ges eloci y g adien s. The ole ances o he olume ac ion ield, o he eloci y ield and o he cu a u e a e se o 10−3,10 −2and 10−6, espec i ely, and he maximum le el o g id e inemen is de ined in each o he di e en egions in o which he compu a ional domain has been di ided; indeed, he g id size is Δ≥R/975 o z>0.1, bu Δ≥R/31208 nea he wall, whe e he eloci y and p essu e g adien s each he la ges alues;see he igu e 10 cap ion o de ails. Mo eo e , we ha e ca ied ou a sensi i i y analysis in o de o e i y ha he esul s epo ed a e independen o he g id size; indeed, igu e 11 shows ha he alues o he p essu e, he 980 A35-22 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess The ska ing o d ops impac ing o e gas o apou laye s τ 0 1000 2000 (∂p/∂ )/(ρU2/R)p/(ρU2) 3000 4000 5000 6000 10 20 30 40 R/Δ 0 1000 2000 3000 4000 5000 6000 0.5 1.00 1.5 2.52.0 3.53.0 0 5 10 15 20 25 5 10 15 20 10 20 30 40 00.5 1.00 1.5 2.52.0 3.53.0 (×104) (×104) hmin/R 00 1 2 3 4 5 6 0.5 1.0 1.5 15 10 5 29 de Rui e Δ = R/31208 Δ = R/15604 Δ = R/8192 Δ = R/4096 Δ = R/1024 Δ = R/256 30 τ S 2/3 31 2.0 10 20 30 40 00.5 1.00 1.5 2.52.0 3.53.0 (×104) (×10–3) (×10–4) (×10–3) (a) (b) (c) (d) (e) ( ) Figu e 11. Plo s o (a)hmin/R(τ),(b)p/(ρU2)(τ),and(c) ime e olu ion o (∂p/∂ )R/(ρU2)(τ ) a he spa io- empo al egion whe e he gas p essu e is maximum o di e en alues o he disc e iza ion le el Δ. The nume ical esul s ha e been calcula ed o We =4andS =3×104, which co espond o he alues o he dimensionless pa ame e s cha ac e izing a wa e d op o adius R=1.05 mm impac ing a wall wi h eloci y U=0.52 m s−1 epo ed by de Rui e e al. (2012). The nume ical esul s a e compa ed wi h he expe imen al measu emen s in de Rui e e al. (2012)in heinse o (a). The alues o Δin he legend indica e he minimum g id size. Nume ical alues a τ∗≈12 a e gi en o (d)hm/R,(e)p/(ρU2)and ( )(∂p/∂ )R/(ρU2)as unc ions o R/Δ,wi hΔindica ing he minimum g id size. p essu e g adien and he minimum gas ilm hickness become independen o he g id size and con e ge owa ds well-de ined alues. Figu e 11 also shows ha ou nume ical esul s ep oduce, wi h small ela i e e o s, he expe imen al alue o he minimum gas ilm hickness epo ed by de Rui e e al. (2012),and able 1 epo s he minimum numbe o cells in he zdi ec ion used o compu e he gas eloci y ield wi hin he lub ica ion laye ; see also igu es 16 and 17. 980 A35-23 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess P. Ga cía-Geijo, G. Riboux and J.M. Go dillo We S Size 43.03 ×10415 12 1.20 ×10423 12 2.60 ×10411 22 2.12 ×10410 36 2.60 ×1047 48 1.84 ×1049 48 3.60 ×1045 60 1.80 ×1049 Table 1. Minimum numbe o nume ical cells used o desc ibe he low in he lub ica ion laye a he adial posi ion whe e he hickness o he gas ilm is minimum. In consequence, he numbe o cells in he zdi ec ion o he es o he adial posi ions and ins an s o imes is la ge han he alues p o ided in he able. 0.010 0.015 0.020 0.025 0.030 36 We = 4, S = 3 × 104 We = 12, S = 1.2 × 104 We = 12, S = 2.6 × 104 We = 22, S = 2.1 × 104 We = 36, S = 2.6 × 104 We = 48, S = 1.2 × 104 We = 48, S = 1.8 × 104 We = 48, S = 3.6 × 104 We = 48, S = 4.5 × 104 We = 60, S = 1.8 × 104 10 12 –1 20 30 40 τ pm S –2/3 Figu e 12. Compa ison be ween he maximum liquid p essu e p edic ed in (3.5) and he maximum gas p essu e a he wall o di e en ins an s o ime and di e en alues o he Webe and S okes numbe s. The dashed line indica es he ansi ion a τ∗=12 be ween he p e-impac and pos -impac s ages. Appendix B. Compa ison be ween he p edic ed and calcula ed alues o he gas p essu e and he gas p essu e g adien In his con ibu ion, we do no es ic ou sel es o alida e ou physical model wi h he esul s shown in igu es 6 and 7; indeed, no ice he e ha he equa ions o he minimum gas ilm hickness hmha e been deduced h ough (3.2), which depends on he alue o he local p essu e g adien a he spa io- empo al egion whe e he p essu e is maximum. Hence ou p edic ions o hma e linked o he co ec ness o he app oxima ions o he ime-dependen alues o bo h he p essu e and he p essu e g adien gi en, espec i ely, in (3.5)and(3.17). This is he eason why igu e 12 compa es he esul in (3.5)wi h he nume ical alues o he maximum gas p essu e a he wall. No ice ha he ag eemen be ween p edic ions and he nume ical esul s imp o es o inc easing alues o We due o he ac ha he nume ical alues o he gas p essu e depic ed in igu e 12 a e he esul o sub ac ing he capilla y p essu e om he alue o he maximum liquid p essu e p edic ed by (3.5). Mo eo e , igu e 13 shows he ime e olu ion o he p essu e g adien a 980 A35-24 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess The ska ing o d ops impac ing o e gas o apou laye s 0 3 6 10 12 20 30 40 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 0.5 1.0 1.5 2.0 ξ τ 0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 0.2 0.4 0.8 0.6 1.0 ξ Πc ∗Πi ∗ (×10–3) 102 103 104 105 (×10–4) –∂p/∂ We = 12, S = 1.2 × 104 We = 12, S = 2.6 × 104 We = 22, S = 2.1 × 104 We = 36, S = 2.6 × 104 We = 48, S = 1.2 × 104 We = 48, S = 1.8 × 104 We = 48, S = 3.6 × 104 We = 48, S = 4.5 × 104 We = 60, S = 1.8 × 104 (a) (b)(c) Figu e 13. (a) Values o he p essu e g adien a he spa io- empo al egion whe e he p essu e is maximum o he ange o We and S conside ed in his s udy. The p essu e g adien has been calcula ed as he slope o he lines angen o he gas p essu e dis ibu ion a he wall; see igu e 2.(b) The alues o he maximum p essu e g adien s, a ained a τ=τ∗≈12, can be p edic ed well o all alues o ξ using he exp ession o −∂p/∂ in (3.17) co esponding o he capilla y scaling. (c) The alues o he p essu e g adien a τ=τ∗≈12 can be p edic ed well o ξ4 using he exp ession o −∂p/∂ in (3.17) co esponding o he ine ial scaling. He e, Π∗ i=Πi(τ∗)=(−∂p/∂ )(τ∗)S −5/3/(ρU2/R)and Π∗ c= Πc(τ∗)=(−∂p/∂ )(τ∗)We−2/3S −14/9/(ρU2/R). he egion whe e he p essu e is maximum. In bo h his igu e and igu e 14, he nume ical alues o he p essu e g adien ha e been calcula ed as illus a ed in igu e 2, namely, as he slope o he lines angen o he gas p essu e dis ibu ion a he wall. The esul s in igu es 13(b,c) show ha he maximum alues o he p essu e g adien s depic ed in igu e 13(a) can be p edic ed using he equa ions o −∂p/∂ gi en in (3.17) pa icula ized a he ins an τ=τ∗≈12. Mo eo e , igu e 14 alida es u he he p edic ions gi en in (3.17) o he ime- a ying alues o he p essu e g adien a he spa io- empo al egion whe e he p essu e is maximum. Indeed, igu e 14(a) shows ha he nume ical alues co esponding o he smalle alues o We ollow he capilla y scaling o −∂p/∂ p o ided in (3.17), whe eas igu e 14(b) con i ms ha he alues o he calcula ed p essu e g adien o We ≥36 a e well cap u ed, specially o he la ge alues o τ, by he equa ion co esponding o he ine ial limi gi en in (3.17), as expec ed om he ac ha he ansi ion om he capilla y o he ine ial egimes is con olled by he alue o he pa ame e ¯ ξ=τξ;see(3.15)–(3.16). 980 A35-25 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess P. Ga cía-Geijo, G. Riboux and J.M. Go dillo ZHANG,B.,SANJAY,V.,SHI,S.,ZHAO,Y.,LV,C.,FENG, X.-Q. & LOHSE, D. 2022 Impac o ces o wa e d ops alling on supe hyd ophobic su aces. Phys. Re . Le . 129, 104501. ZHANG,P.&LAW, C.K. 2011 An analysis o head-on d ople collision wi h la ge de o ma ion in gaseous medium. Phys. Fluids 23 (4), 042102. 980 A35-32 h ps://doi.o g/10.1017/j m.2024.20 Published online by Camb idge Uni e si y P ess