Steel heat treating: Mathematical modelling and numerical simulation of a problem arising in the automotive industry
Abstract
We describe a mathematical model for the industrial heating and cooling processes of a steel workpiece representing the steering rack of an automobile. The goal of steel heat treating is to provide a hardened surface on critical parts of the workpiece while keeping the rest soft and ductile in order to reduce fatigue. The high hardness is due to the phase transformation of steel accompanying the rapid cooling. This work takes into account both heating-cooling stage and viscoplastic model. Once the general mathematical formulation is derived, we can perform some numerical simulations.
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Advances in Science, Technology and Engineering Systems Journal Vol. 2, No. 5, 55-62 (2017) www.astesj.com Proceedings of International Conference on Applied Mathematics (ICAM’2017), Taza, Morocco ASTES Journal ISSN: 2415-6698 Steel heat treating: mathematical modelling and numerical simulation of a problem arising in the automotive industry Jos´ e Manuel D´ ıaz Moreno1, Concepci´ on Garc´ ıa V´ azquez1, Mar´ ıa Teresa Gonz´ alez Montesinos2, Francisco Orteg´ on Gallego*,1, Giuseppe Viglialoro3 1Departamento de Matem´ aticas, Facultad de Ciencias, Universidad de C´ adiz, 11510 Puerto Real, SPAIN, [email protected], [email protected], fr[email protected]. 2Departamento de Matem´ atica Aplicada I, ETS de Ingenier´ ıa Inform´ atica, Universidad de Sevilla, 41012 Sevilla, SPAIN, [email protected]. 3Dipartimento di Matematica ed Informatica, Universit` a degli Studi di Cagliari, viale Merello 92 – 09123 Cagliari, ITALY, [email protected]. A R T I C L E I N F O A B S T R A C T Article history: Received: 10 June, 2017 Accepted: 15 July, 2017 Online: 10 December, 2017 We describe a mathematical model for the industrial heating and cooling processes of a steel workpiece representing the steering rack of an automobile. The goal of steel heat treating is to provide a hardened surface on critical parts of the workpiece while keeping the rest soft and ductile in order to reduce fatigue. The high hardness is due to the phase transformation of steel accompanying the rapid cooling. This work takes into account both heating-cooling stage and viscoplastic model. Once the general mathematical formulation is derived, we can perform some numerical simulations. Keywords : Steel hardening Phase transitions Potential Maxwell equations Numerical Simulations Finite Element Methods 1 Introduction In the automative industry, many workpieces such gears, bearings, racks and pinions, are made of steel. Steel is an alloy of iron and carbon. Generally, industrial steel has a carbon content up to about 2 wt%. Other alloying elements may be present, such as Cr and V in tools steels, or Si, Mn, Ni and Cr in stainless steels. Most structural components in mechanical engineering are made of steel. Certain of these components, such as toothed wheels, bevel gears, pinions and so on, engaged each others in order to transmit some kind of (rotational or longitudinal) movement. In this situation, the contact surfaces of these components are particularly stressed. The goal of heat treating of steel is to attain a satisfactory hardness. Prior to heat treating, steel is a soft and ductile material. Without a hardening treatment, and due to the surface stresses, the gear teeth will soon get damaged and they will no longer engage correctly. In this work we are interested in the mathematical description of the hardening procedure of a car steering rack (see Figure 1). This particular situation is one of the major concerns in the automotive industry. In this case, the goal is to increase the hardness of the steel along the tooth line and at the same time keeping the rest of the workpiece soft and ductile in order to reduce fatigue. This problem is governed by a nonlinear system of partial differential equations coupled with a certain system of ordinary differential equations. Once the full system is set we perform some numerical simulations. Figure 1: Car steering rack. Solid steel may be present at different phases, namely austenite, martensite, bainite, pearlite and ferrite. The phase diagram of steel is shown in Figure 2. For a given wt% of carbon content up to 2.11, *Corresponding author. Departamento de Matem´ aticas, Facultad de Ciencias, Universidad de C´ adiz, 11510 Puerto Real, SPAIN, [email protected] www.astesj.com 55 https://dx.doi.org/10.25046/aj020510
J. M. D´ ıaz et al. / Advances in Science, Technology and Engineering Systems Journal Vol. 2, No. 5, 55-62 (2017) all steel phases are transformed into austenite provided the temperature has been raised up to a certain range. The minimum austenization temperature (727◦) is attained for a carbon content of 0.77 wt% (eutectoid steel). Upon cooling, the austenite is transformed back into the other phases (see Figure 3), but its distribution depends strongly on the cooling strategy ([4, 12]). Martensite is the hardest constituent in steel, but at the same time is the most brittle, whereas pearlite is the softest and more ductile phase. Martensite derives from austenite and can be obtained only if the cooling rate is high enough. Otherwise, the rest of the steel phases will appear. The hardness of the martensite phase is due to a strong supersaturation of carbon atoms in the iron lattice and to a high density of crystal defects. From the industrial standpoint, heat treating of steel has a collateral problem: hardening is usually accompanied by distortions of the workpiece. The main reasons of these distortions are due to (1) thermal strains, since steel phases undergo different volumetric changes during the heating and cooling processes, and (2) experiments with steel workpieces under applied loading show an irreversible deformation even when the equivalent stress corresponding to the load is in the elastic range. This effect is called transformation induced plasticity. The heating stage is accomplished by an induction-conduction procedure. This technique has been successfully used in industry since the last century. During a time interval, a high frequency current passes through a coil generating an alternating magnetic field which induces eddy currents in the workpiece, which is placed close to the coil. The eddy currents dissipate energy in the workpiece producing the necessary heating. 2 Mathematical modeling We consider the setting corresponding to Figure 4. The domain Ωcrepresents the inductor (made of copper) whereas Ωsstands for the steel workpiece to be hardened. Here, the coil is the domain Ω=Ωs∪Ωc∪ S0. In this way, the workpiece itself takes part of the coil. In order to describe the heating-cooling process, we will distinguish two subintervals forming a partition of [0,T ], namely [0,T ] = [0,Th)∪[Th,Tc], Tc> Th> 0. The first one [0,Th) corresponds to the heating process. All along this time interval, a high frequency electric current is supplied through the conductor which in its turn induces a magnetic field. The combined effect of both conduction and induction gives rise to a production term in the energy balance equation (14), namely b(θ)|At+∇φ|2. This is Joule’s heating which is the principal term in heat production. In our model, we will only consider three steel phase fractions, namely austenite (a), martensite (m), and the rest of phases (r). In this way, we have a+m+r= 1 and 0 ≤a,m,r ≤1 in Ωs×[0,T ]. At the initial time we have r(0) = 1 in Ωs. Upon heating only austenite can be obtained. In particular m= 0 in Ωs×[0,Th] and the transformation to austenite is derived at the expense of the other phase fractions (r). At the instant t=Th, the current is switched off and during the time interval [Th,Tc] the workpiece is severely cooled down by means of aqua-quenching. The heating model The current passing through the set of conductors Ω=Ωc∪Ωs∪S0is modeled by the electric potential difference, ϕ0, applied on the surface Γ2⊂Ωc(see Figure 4). Notice that the applied potential on Γ1is zero. In the sequel, we put Γ=Γ1∪Γ2. The heating model involves the following unknowns: the electric potential, φ; the magnetic vector potential, A= (A1,A2,A3); the stress tensor, σ= (σij)1≤i,j≤3,σij =σji for all 1 ≤i,j ≤3; the displacement field u= (u1,u2,u3); the austenite phase fraction, a; and the temperature, θ. Among them, only Ais defined in the domain Dcontaining the set of conductors Ω. On the other hand, since the inductor and the workpiece are in close contact, both φand θ are defined in Ω. Since phase transitions only occur in the workpiece, we may neglect deformations in Ωc. This implies that σ,uand aare only defined in the workpiece Ωs. Since electromagnetic fields generated by high frequency currents are sinusoidal in time, both the electric potential, φ, and the magnetic potential field, A, take the form ([1, 2, 14, 15]) M(x,t) = ReheiωtM(x)i, where Mis a complex-valued function or vector field, and ω= 2πf is the angular frequency, fbeing the electric current frequency. In general, Malso depends on t, but at a time scale much greater than 1/ω. In this way, we may introduce the complex-valued fields ϕand Aas φ= Re[eiωtϕ(x,t)],A= Re[eiωtA(x,t)].(1) As a far as the numerical simulation of a system like (2)-(15) is concerned, the introduction of the new variables ϕand Ais quite convenient since the time scale describing the evolution of both ϕand Ais much smaller than that of the temperature θ. In the case of steel heat treating, fis about 80 KHz. The heating model reads as follows ([3, 9, 10, 7]): ∇ · (b(θ)∇ϕ) = 0 in ΩTh=Ω×(0,Th),(2) ∂ϕ ∂n = 0 on (∂Ω\Γ)×(0,Th),(3) ϕ= 0 on Γ1×(0,Th), ϕ=ϕ0on Γ2×(0,Th), (4) b0(θ)iωA+∇ × 1 µ∇ × A!−δ∇(∇ · A) =−b0(θ)∇ϕin D×(0,Th),(5) A= 0 on ∂D ×(0,Th),(6) www.astesj.com 56
J. M. D´ ıaz et al. / Advances in Science, Technology and Engineering Systems Journal Vol. 2, No. 5, 55-62 (2017) Temperature ◦C 400 600 800 1000 1200 1400 1600 012345 6 7 Fe % C Fe3C (C) Hypoeutectoide Hypereutectoide α (Fe) Ferrite + Cementite 727 ◦C 1148 ◦C 912 ◦C 1394 ◦C 0.77% (Eutectoid) 2.11% 4.30% Austenite + Cementite Liquid γ+ Liquid γ Austenite Figure 2: Iron-carbide phase diagram. Ferrite Pearlite Bainite Martensite Austenite Ferrite Pearlite Bainite Martensite Heating Cooling Figure 3: Microconstituents of steel. Upon heating, all phases are transformed into austenite, which is transformed back to the other phases during the cooling process. The distribution of the new phases depends strongly on the cooling strategy. A high cooling rate transforms austenite into martensite. A slow cooling rate transforms austenite into pearlite. www.astesj.com 57
J. M. D´ ıaz et al. / Advances in Science, Technology and Engineering Systems Journal Vol. 2, No. 5, 55-62 (2017) Ωs(steel) Ωc(copper) Ωc Γ1Γ2 S0 S0 D Figure 4: Domains D,Ω=Ωs∪Ωc∪S0and the faces Γ1,Γ2⊂Ωc. The inductor Ωcis made of copper. The workpiece contains a toothed part to be hardened by means of the heating-cooling process described below. It is made of a hypoeutectoid steel. The domain is taken as a big enough rectangle containing both the inductor and the rack −∇ · σ=Fin Ωs×(0,Th),(7) σ=Kε(u)−A1(a,m,θ)I −Zt 0 γ(a,m,at,mt,θ)Sdτ,(8) u= 0 on Γ0×(0,Th),(9) σ·n= 0 on (∂Ωs\Γ0)×(0,Th),(10) at=1 τa(θ)(aeq(θ)−a)H(θ−As) in Ωs×(0,Th),(11) a(0) = 0 in Ωs,(12) α(θ,a,m,σ)θt− ∇ · (κ(θ)∇θ) +3 ¯ κq(a,m)θ(∇ · ut−3A2(at,mt,θ)) =b(θ)|At+∇φ|2−ρLaat +A2(at,mt,θ)trσ +γ(a,m,at,mt,θ)|S|2in ΩTh,(13) ∂θ ∂n = 0 on ∂Ω×(0,Th),(14) θ(0) = θ0in Ω.(15) Here, b(θ) is the electrical conductivity (by b(θ) we mean the function (x,t)7→ b(x,θ(x,t)), and also for κ(θ), etc.); ϕ0represents the potential external source. The domain Dcontaining the set of conductors is taken big enough so that the magnetic vector potential Avanishes on its boundary ∂D (in our model, is taken to be a 2D rectangle or a 3D cube). Since both σand aare only defined in Ωs, when they appear in a term referred in Ω, we mean that this term vanishes outside Ωs(for instance, −ρLaatappearing in (13)); b0(x,s) = b(x,s) if x∈Ω,b0(x,s) = 0 elsewhere; µ=µ(x) is the magnetic permeability; δ > 0 is a small constant; Fis a given external force (usually F= 0); K=Kijkl, 1≤i,j,k,l ≤3 is the stiffness tensor. Steel can be considered as an isotropic and homogenous material so that Kijkl =¯ λδijδkl+¯ µ(δikδjl+δilδjk),for all i,j,k,l ∈ {1,2,3} where ¯ λ≥0 and ¯ µ > 0 are the Lam´ e coefficients of steel; ε(u) = 1 2(∇u+∇uT) is the strain tensor; A1(a,m,θ)Imodels the thermal strain, Ibeing the 3×3 unity matrix, whereas A1(a,m,θ) is defined as A1(a,m,θ) = qaa(θ−θa) + qmm(θ−θm) +qr(1 −a−m)(θ−θr), and in its turn qa,qmand qrare the thermal expansion coefficients of the phase fractions a,mand r, respectively, and θa,θmand θrare reference temperatures (notice that during the heating stage is m= 0); Rt 0γ(a,m,at,mt,θ)Sdτgives the model, through the function γ, of the transformation induced plasticity strain tensor, where S=σ−1 3trσIis the deviator of σ, that is, the trace free part of the stress tensor; Γ0is a certain smooth enough part of ∂Ωs;nis the unit outer normal vector to the referred boundary; the functions τa(θ), aeq(θ) are given from experimental data (see Figure 5), and His the Heaviside function; κ(θ) is the thermal conductivity; the functions appearing in (13) are given as follows α(θ,a,m,σ) = ρcε−9¯ κq(a,m)2θ−q(a,m)trσ, where ρand cεare the steel density and the specific heat capacity at constant strain, respectively, ¯ κ= 1 3(3 ¯ λ+ 2 ¯ µ) is the bulk modulus, and q(a,m) is defined as q(a,m) = qaa+qmm+ (1 −a−m)qr; A2(at,mt,θ) = qaat(θ−θa) + qmmt(θ−θm) −qr(at+mt)(θ−θr). Finally, La>0 is the latent heat related to the austenite phase fraction. Notice that, in a more general situation ρ,cεand Lamay also depend on a,mand/or θ. www.astesj.com 58
J. M. D´ ıaz et al. / Advances in Science, Technology and Engineering Systems Journal Vol. 2, No. 5, 55-62 (2017) AsAfθ τa(θ) aeq(θ) Figure 5: Functions aeq and τa. Equations (2) and (5) derive from Maxwell’s equations. In [9], it is assumed the Coulomb gauge condition for the magnetic vector potential, namely, ∇ · A= 0. Here, we do not impose this condition since this makes appear an undesired pressure gradient in the equation for A. In its turn, we include a penalty term in this equation of the form −δ∇(∇ · A). In doing so, both the theoretical analysis and the numerical simulations are simplified. Equation (7) is a quasistatic balance law of momentum and (8) is Hooke’s law. The transformation to austenite from the initial phase r(0) = 1 is described in (11). Finally, equation (13) derives from the balance law of internal energy. As it has been pointed out above, Joule’s heating is the main responsible in heat production. Since γ(a,m,at,mt,θ)|S|2≥0, the contribution of the transformation induced plasticity to the energy balance is also a production term. On the other hand, during the heating stage we have at≥0 so that −ρLaat≤0. This means that the transformation to austenite absorbs energy, which is released during the cooling stage. The cooling model The heating process ends, the high frequency current passing through the coil is switched-offand aquaquenching begins. The quenching is just modeled via the Robin boundary condition given in (25). We put aTh=a(Th), that is, aThis the austenite phase fraction distribution at the final heating instant Thobtained from (11). In the same way, we define θTh=θ(Th). Obviously, these functions will be taken as the initial phase fraction distribution and temperature, respectively, in the cooling model. Here we use the Koistinen-Marburger model ([11, 13]) for the description of the transformation to martensite from austenite. The cooling model reads as follows −∇ · σ=Fin Ωs×(Th,Tc),(16) σ=Kε(u)−A1(a,m,θ)I −Zt 0 γ(a,m,at,mt,θ)Sdτ,(17) u= 0 on Γ0×(Th,Tc),(18) σ·n= 0 on (∂Ωs\Γ0)×(Th,Tc),(19) at=1 τa(θ)(aeq(θ)−a)H(θ−As) in Ωs×(Th,Tc),(20) a(Th) = aThin Ωs,(21) mt=cm(1 −m)H(−θt)H(Ms−θ) in Ωs×(Th,Tc),(22) m(Th) = 0 in Ωs,(23) α(θ,a,m,σ)θt− ∇ · (κ(θ)∇θ) + 3 ¯ κq(a,m)θ(∇ · ut−3A2(at,mt,θ)) =−ρLaat+ρLmmt+A2(at,mt,θ)trσ +γ(a,m,at,mt,θ)|S|2in Ω×(Th,Tc),(24) ∂θ θn =β(x,t)(θ−θe) on ∂Ω×(Th,Tc),(25) θ(Th) = θThin Ω.(26) In (22) cm>0 is a constant value. Also, in (24), Lm>0 is the latent heat related to the martensite phase fraction. The function β(x,t) in (25) is a heat transfer coefficient and is given by β(x,t) = (0 on ∂Ω∩∂Ωc, β0(t) on ∂Ω∩∂Ωs. where β0(t)>0 (usually taken to be constant). Finally, θeis the temperature of the quenchant. The mathematical analysis of a system similar to (16)-(26) can be seen in [3]. In this reference, an existence result is shown assuming that the data are smooth enough and Tc−This sufficiently small. Dh Figure 6: Domain triangulation. The mesh contains 61790 triangles and 30946 vertices. www.astesj.com 59
J. M. D´ ıaz et al. / Advances in Science, Technology and Engineering Systems Journal Vol. 2, No. 5, 55-62 (2017) 3 Numerical simulation Using the Freefem++ package ([8]), we have performed some numerical simulations for the approximation of the solution to the systems (2)-(15) and (16)- (26). We want to describe the hardening treatment of a car steering rack during the heating-cooling process. The goal is to produce martensite along the tooth line together with a thin layer in its neighborhood inside the steel workpiece ([5, 6]). Dh Figure 7: Domain triangulation. Element density near three teeth. Figure 4 shows the open sets D,Ω=Ωs∪Ωc∪S and the faces Γ1and Γ2(they appear stick together in this figure) which intervene in the setting of the problem. The workpiece contains a toothed part to be hardened by means of the heating-cooling process described above. It is made of a hypoeutectoid steel. The open set D\¯ Ωis air. The magnetic permeability µ in (5) is then given by µ(x) = µ0if x∈D\¯ Ω, 0.99995µ0if x∈Ωc, 2.24 ×103µ0if x∈Ωs, where µ0= 4π×10−7(N/A2) is the magnetic constant (vacuum permeability). The martensite phase can only derive from the austenite phase. Thus we need to transform first the critical part to be hardened (the tooth line) into austenite. For our hypoeutectoid steel, austenite only exists in a temperature range close to the interval [1050,1670] (in K). During the first stage, the workpiece is heated up by conduction and induction (Joule’s heating) which renders the tooth line up to the desired temperature. In order to transform the austenite into martensite, we must cool it down at a very high rate. This second stage is accomplished by aquaquenching. In this simulation, the final time of the heating process is Th= 5.5 seconds and the cooling process extends also for 5.5 seconds, that is Tc= 11. We have used the finite elements method for the space approximation and a Crank-Nicolson scheme for the time discretization. Figures 6 and 7 show the triangulation of Din our numerical simulations. We have used P2-Lagrange approximation for ϕ,Aand θ and P1for aand m. In Figure 8 we can see the temperature distribution of the rack along the tooth line at different instants of the the heating-cooling process. The initial temperature is θ0= 300K. At t= 5.5 the heating process ends and the computed temperature shows that the temperature along the rack tooth line lies in the interval [1050,1670] (K). t= 1s t= 3s t= 5.5s t= 6s t= 7s Figure 8: Temperature evolution at instants t= 1, t= 3, t= 5.5 (end of the heating stage, aqua-quenching begins), t= 6 and t= 7 seconds, respectively. At t= 5.5s the temperature along the tooth part has reached the austenization level in this part of the rack. The temperature is measured in Kelvin. t= 5.5s (left), t= 6.5s (right), t= 7s (left), t= 8s (right) t= 9s (left) and t= 11s (right). Figure 9: Transformation of the austenite phase fraction during the aquaquenching at time instants t=5.5, 6.5, 7, 8, 9, and 11 seconds, respectively. www.astesj.com 60
J. M. D´ ıaz et al. / Advances in Science, Technology and Engineering Systems Journal Vol. 2, No. 5, 55-62 (2017) Figure 9 shows the austenite evolution from the beginning of the cooling stage. Blue corresponds to 0% while red is 100%. We observe that martensite starts to appear, approximatively, one second after the beginning of the cooling stage. At the final instant, all the amount of austenite has been transformed into martensite as it is shown in Figure 10 . t= 5.5s (left), t= 6.5s (right), t= 7s (left), t= 8s (right) t= 9s (left) and t= 11s (right). Figure 10: Transformation of the martensite phase fraction from austenite during the aquaquenching at time instants t=5.5, 6.5, 7, 8, 9, and 11 seconds, respectively. Figure 11 shows the austenization along the tooth line at the end of the heating process T= 5.5 seconds. Figure 12 shows the final distribution of martensite from austenite along the rack tooth line through the cooling stage t= 11 seconds. We have good agreement versus the experimental results obtained in the industrial process. During the heating-cooling process, the workpiece is deformed so that an industrial rectification is needed (or otherwise the rack would be useless). Figures 13 and 14 shows the different deformations undergone by the workpiece. Figure 11: Heating process. Austenite at t= 5.5 along the rack tooth line. Figure 12: Cooling process. Martensite transformation at the final stage of the cooling process t= 11 seconds. Figure 13: Distorted mesh (with a scale factor of 10) after the heating stage. The austenite transformation along the tooth line changes the original profile. Figure 14: Distorted mesh (with a scale factor of 10) after the cooling stage. The original configuration is partially recovered. Due to the plasticity effect and the lack of the upper supports, the rack bends down. www.astesj.com 61
J. M. D´ ıaz et al. / Advances in Science, Technology and Engineering Systems Journal Vol. 2, No. 5, 55-62 (2017) Conflict of Interest The authors declare no conflict of interest. Acknowledgments This research was partially supported by Ministerio de Educaci´ on y Ciencia under grants MTM2010-16401 and TEC2014-54357-C2-2R with the participation of FEDER, and Consejer´ ıa de Educaci´ on y Ciencia de la Junta de Andaluc´ ıa, research group FQM–315. References [1] A. Berm ´ udez, J. Bull´ on, F. Pena and P. Salgado, “A numerical method for transient simulation of metallurgical compound electrodes”, Finite Elem. Anal. Des., 39, 283–299, 2003. https://doi.org/10.1016/S0168-874X(02)00069-0 [2] A. Berm ´ udez, D. G´ omez, M. C. Mu˜ niz and P. Salgado, “Transient numerical simulation of a thermoelectrical problem in cylindrical induction heating furnaces”, Adv. Comput. Math., 26, 39–62, 2007. https://doi.org/10.1007/s10444-005-7470-9 [3] K. Chełminski, D. H¨ omberg and D. Kern, “On a thermomechanical model of phase transitions in steel”, Adv. Math. Sci. Appl., 18, 119–140, 2008. [4] J. R. Davis et al. “ASM Handbook: Heat Treating”, vol. 4, ASM International, USA, 2007. [5] J. M. D´ ıaz Moreno, C. Garc´ ıa V´ azquez, M. T. Gonz´ alez Montesinos and F. Orteg´ on Gallego, “Numerical simulation of a Induction-Conduction Model Arising in Steel Hardening model arising in steel hardening”, Lecture Notes in Engineering and Computer Science, World Congress on Engineering 2009, Volume II, July 2009, 1251–1255. [6] J. M. D´ ıaz Moreno, C. Garc´ ıa V´ azquez, M. T. Gonz´ alez Montesinos, F. Orteg´ on Gallego and G. Viglialoro, “Mathematical modeling of heat treatment for a steering rack including mechanical effects”, J. Numer. Math. 20, no. 3-4, 215–231, 2012. https://doi.org/10.1515/jnum-2012-0011 [7] J. Fuhrmann, D. H¨ omberg and M. Uhle, “Numerical simulation of induction hardening of steel”, COMPEL, 18, No. 3, 482–493, 1999. https://doi.org/10.1108/03321649910275161 [8] F. Hecht, “New development in freeFem++”, J. Numer. Math. 20, no. 3-4, 251–265, 2012. https://doi.org/10.1515/jnum2012-0013 [9] D. H¨ omberg, “A mathematical model for induction hardening including mechanical effects”, Nonlinear Anal.-Real World Appl., 5, 55–90, 2004. https://doi.org/10.1016/S14681218(03)00017-8 [10] D. H¨ omberg and W. Weiss, “PID control of laser surface hardening of steel”, IEEE Trans. Control Syst. Technol., 14, No. 5, 896–904, 2006. https://doi.org/10.1109/TCST.2006.879978 [11] D. P. Koistinen, R. E. Marburger, “A general equation prescribing the extent of the austenite-martensite transformation in pure iron-carbon alloys and plain carbon steels”, Acta Metall., 7, 59–60, 1959. https://doi.org/10.1016/00016160(59)90170-1 [12] G. Krauss, “Steels: Heat Treatment and Processing Principles”, ASM International, USA, 2000. [13] J. B. Leblond and J. Devaux, “A new kinetic model for anisothermal metallurgical transformations in steels including effect of austenite grain size”, Acta Metall., 32, No. 1, 137– 146, 1984. https://doi.org/10.1016/0001-6160(84)90211-6 [14] F. J. Pena Brage, “Contribuci´ on al modelado matem´ atico de algunos problemas en la metalurgia del silicio”, Ph. thesis, Universidade de Santiago de Compostela, 2003. [15] H. M. Yin, “Regularity of weak solution to Maxwell’s equations and applications to microwave heating”, J. Differ. Equ., 200, 137-161, 2004. https://doi.org/10.1016/j.jde.2004.01.010 www.astesj.com 62