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Comparison of transcriptional and translational changes caused by long-term menadione exposure in Aspergillus nidulans

Pusztahelyi, Tünde; Klement, Éva; Szájli, Emília; Klem, József; Miskei, Márton; Karányi, Zsolt; Emri, Tamás; Kovács, Szilvia; Orosz, Gyula; Kovács, Kornél L.; Medzihradszky-Fölkl, Katalin; Prade, Rolf A.; Pócsi, István

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1 2Compa ison o ansc ip ional and ansla ional changes caused by long- e m 3menadione exposu e in Aspe gillus nidulans 4Tünde Pusz ahelyi a, ⇑ , É a Klemen b , Emilia Szajli b , Józse Klem c,d , Má on Miskei e, , 5Zsol Ka ányi g , Tamás Em i a , Szil ia Ko ács a , Gyula O osz d , Ko nél L. Ko ács d , Ka alin F. Medzih adszky b,h , 6Rol A. P ade i , Is án Pócsi a, ⇑⇑ 7 a Depa men o Mic obial Bio echnology and Cell Biology, Facul y o Science and Technology, Uni e si y o Deb ecen, Egye em é 1, H-4032 Deb ecen, Hunga y 8 b P o eomics Resea ch G oup, Ins i u e o Biochemis y, Biological Resea ch Cen e , Hunga ian Academy o Sciences, Temes á i k . 62, H-6726 Szeged, Hunga y 9 c Ins i u e o Biophysics, Biological Resea ch Cen e , Hunga ian Academy o Sciences, Temes á i k . 62, H-6726 Szeged, Hunga y 10 d Depa men o Bio echnology, Uni e si y o Szeged, Közép aso 52, H-6726 Szeged, Hunga y 11 e Depa men o Ho icul u al Sciences and Plan Bio echnology, Facul y o Ag icul u e, Cen e o Ag icul u al Sciences, Uni e si y o Deb ecen, Egye em é 1, H-4032 12 Deb ecen, Hunga y 13 Mycology G oup o he Hunga ian Academy o Sciences, Ins i u e o Plan P o ec ion, Szen Is án Uni e si y, Pá e Ká oly u ca. 1, H-2100 Gödöll} o, Hunga y 14 g Depa men o Medicine, Facul y o Medicine, Uni e si y o Deb ecen, P.O. Box 19, H-4012 Deb ecen, Hunga y 15 h Depa men o Pha maceu ical Chemis y, Uni e si y o Cali o nia San F ancisco, San F ancisco, CA 94158, USA 16 i Depa men o Biochemis y and Molecula Biology, Oklahoma S a e Uni e si y, 348E Noble Resea ch Cen e , S illwa e , OK 74078, USA 17 19 a icle in o 20 A icle his o y: 21 Recei ed 22 Feb ua y 2010 22 Accep ed 19 Augus 2010 23 A ailable online xxxx 24 Keywo ds: 25 Fungi 26 Aspe gillus (Eme icella)nidulans 27 Oxida i e s ess 28 Menadione 29 P o eomics 30 Genomics 31 32 abs ac 33 Unde long- e m oxida i e s ess caused by menadione sodium bisulfi e, genome-wide ansc ip ional 34 and p o eome-wide ansla ional changes we e compa ed in Aspe gillus nidulans ege a i e cells. The 35 compa ison o p o eomic and DNA mic oa ay exp ession da a demons a ed ha global gene exp ession 36 changes eco ded wi h ei he flip-flop o dend ime cDNA labeling echniques suppo ed p o eome 37 changes mode a ely wi h 40% and 34% coincidence coe ficien s, espec i ely. Enzyme le els in he glyco- 38 ly ic pa hway we e al e na ing, which was a di ec consequence o fluc ua ing gene exp ession pa e ns. 39 Su p isingly, enzymes in he i amin B2 and B6 biosyn he ic pa hways we e ep essed concomi an ly 40 wi h he ep ession o some p o ein olding chape ones and nuclea anspo elemen s. Unde long- e m 41 oxida i e s ess, he pe oxide-de oxi ying pe oxi edoxins and cy och ome c pe oxidase we e eplaced by 42 hio edoxin educ ase, a ni o educ ase and a fla ohemoglobin, and p o ein deg ada ion became p edom- 43 inan o elimina e damaged p o eins. 44 Ó2010 Published by Else ie Inc. 45 46 47 48 1. In oduc ion 49 Inae obico ganisms eac i eoxygenspecies (ROS)a egene a ed 50 con inuously as side p oduc s o espi a ion (Li e al., 2009). ROS in- 51 clude hyd ogen pe oxide (H 2 O 2 ), supe oxide anion (O  2 ) and hyd o- 52 xyl adicals (HO  ). In addi ion o hei impo an signaling unc ions 53 in di e se cellula p ocesses (La a-O íz e al., 2003; Cano-Domin- 54 guez e al., 2008), ROS a e also cy o oxic in p oka yo ic and euka y- 55 o ic o ganisms. No su p isingly, significan e o s a e made by he 56 O 2 -exposed cells o elimina e ha m ul ROS h ough a wide a ay o 57 bo h enzyma ic and non-enzyma ic p ocesses (Pócsi e al., 2004; Li 58 e al., 2009). Highe concen a ions o ROS ha may o igina e om 59 exogenous sou ces o due o in acellula enzyme ac i i ies may 60 cause aging and e en ini ia e apop o ic cell dea h (Pe one e al., 61 2008; Scheckhube e al., 2009). ROS gene a ed a low concen a- 62 ions can igge an adap i e s ess esponse ha makes he cells 63 esis an o le hal concen a ions o hese oxic oxygen de i a i es 64 (Collinson and Dawes, 1992; Jamieson, 1992; Li e al., 2008a). 65 Gene exp ession and p o eome su eys ha e iden ified nume - 66 ous genes and gene p oduc s induced o ep essed in esponse o 67 oxidan s in yeas s and filamen ous ungi (Godon e al., 1998; Gasch 68 e al., 2000; Chen e al., 2003, 2008; Kim e al., 2006, 2007a). 69 Applica ions o ROS gene a ing agen s, employed a suble hal doses 70 in Aspe gillus nidulans (Pócsi e al., 2005) and Saccha omyces ce e i- 71 siae (Gasch e al., 2000; Tho pe e al., 2004), e ealed significan 72 di e ences in gene exp ession depending on ea u ed chemical, 73 he concen a ions o he applied agen s and he p oduced ROS. 1087-1845/$ - see on ma e Ó2010 Published by Else ie Inc. doi:10.1016/j. gb.2010.08.006 Abb e ia ions: GSH, glu a hione; GSSG, glu a hione disulfide; ROS, eac i e oxygen species; MSB, menadione sodium bisulfi e. ⇑ Co esponding au ho . Add ess: Depa men o Mic obial Bio echnology and Cell Biology, Facul y o Science and Technology, Uni e si y o Deb ecen, P.O. Box 63, H-4010 Deb ecen, Hunga y. ⇑⇑ Co esponding au ho . Add ess: Depa men o Mic obial Bio echnology and Cell Biology, Facul y o Science and Technology, Uni e si y o Deb ecen, P.O. Box 63, H-4010 Deb ecen, Hunga y. E-mail add esses: [email p o ec ed] (T. Pusz ahelyi), [email p o ec ed] (I. Pócsi). Fungal Gene ics and Biology xxx (2010) xxx–xxx Con en s lis s a ailable a ScienceDi ec Fungal Gene ics and Biology jou nal homepage: www.else ie .com/loca e/y gbi YFGBI 2267 No. o Pages 12, Model 5G 30 Augus 2010 Please ci e his a icle in p ess as: Pusz ahelyi, T., e al. Compa ison o ansc ip ional and ansla ional changes caused by long- e m menadione exposu e in Aspe gillus nidulans. Fungal Gene . Biol. (2010), doi:10.1016/j. gb.2010.08.006 74 Pócsi e al. (2005) ca ied ou genome-le el gene exp ession da a 75 analysis on he oxida i e s ess esponse o A. nidulans, and hey 76 ound ha 2499 o he 3533 unique PCR-amplified gene p obes 77 p in ed on an EST-based DNA mic oa ay we e a ec ed by a leas 78 one o he oxida i e s ess gene a ing agen s diamide, H 2 O 2 and 79 menadione sodium bisulfi e (MSB). 80 Unde he expe imen al condi ions used by Pócsi e al. (2005), 81 diamide, which is a hiol oxidizing compound, caused a quick 82 change in he glu a hione/glu a hione disulfide (GSH/GSSG) edox 83 s a us o he cells wi hou influencing in acellula ROS concen a- 84 ions. On he o he hand, he inc eased pe oxide and supe oxide 85 concen a ions obse able unde H 2 O 2 and MSB exposu es could 86 no be sepa a ed om GSH/GSSG edox imbalances a any s esso 87 concen a ion es ed. The dis u bance o he GSH/GSSG edox bal- 88 ance unde H 2 O 2 and MSB- ea men s was explained by he ela- 89 i ely weak ca alase p oduc ion o A. nidulans, which bu dened 90 he GSH-dependen enzyma ic and non-enzyma ic ROS elimina- 91 ion pa hways (Pócsi e al., 2005). 92 The physiological e ec s o MSB a e no limi ed o he cyclic gen- 93 e a ion o O  2 because hese anions des oy 4Fe-4S p o eins, which 94 leads o he o ma iono dele e iousOH  adicals,and hede oxifica- 95 ion o MSB ca alyzed by glu a hione S- ans e ase also a ec s di- 96 ec ly he GSH pool o he cells (Toledano e al., 2003; Pócsi e al., 97 2004). In addi ion, menadione can chemically modi y (a yla e) cell 98 componen s and enhance memb ane fluidi y (She ze e al., 99 1992).MSBis he e o e likely oini ia emixedoxida i e/non-oxida- 100 i e s ess when employed a high (abo e 0.2 mmol l 1 ) concen a- 101 ions and o sho pe iods o ime in ungal cul u es (Pócsi e al., 102 2005).I is ema kable ha ashi omamixed- ypes ess esponse 103 owa ds a pu e oxida i e s ess esponse was obse ed unde long- 104 e m (6–9 h) exposu es o A. nidulans cul u es o MSB, when he 105 in acellula accumula ion o ROSand he dec ease in he GSH/GSSG 106 a io we e equally significan , and nume ous genes subjec ed o 107 supe oxide, pe oxide o GSH/GSSG-dependen ansc ip ional egu- 108 la ion we e esponding o oxida i e s ess (Pócsi e al., 2005). 109 A e comple ing he analysis o he da a ob ained om genome- 110 wide gene exp ession expe imen s, we add essed he ques ion o 111 whe he he la ge-scale and significan ansc ip ional changes 112 caused by MSB- ea men s would also esul in a p o eome signifi- 113 can ly di e en om ha o uns essed cul u es. Kim e al. (2008) 114 e iewed p o eomic da a collec ed in he Aspe gillii up o he yea o 115 2008 and epo ed only a combined o al o 28 cell su ace, 102 116 sec e ed and 139 in acellula p o eins ha ha e been iden ified in 117 10 di e en s udies. Taking in o conside a ion he p ac ical signifi- 118 canceo heseindus iallyandmedicallyimpo an ungiand he ac 119 ha mos o hem a e ully sequenced and hei genome anno a ions 120 ha e eached an ad anced le el (Wo man e al., 2009) hese num- 121 be s a e qui e modes . Because no p o eome s udy has been ca ied 122 ou ye in oxida i e s ess-exposed Aspe gillii, we would also ha e 123 liked o augmen ou p o eome-le el knowledge on he oxida i e 124 s ess de ense sys em o hese Euascomyce es (Miskei e al., 2009). 125 To compile da a o all he equi emen s, in his s udy we 126 mapped he in acellula soluble p o eome o A. nidulans ege a- 127 i e cells exposed o high-dose (0.8 mmol l 1 ) MSB o long ime 128 pe iods (6 h). T ansla ional changes igge ed by oxida i e s ess 129 we e compa ed o genome-wide ansc ip ional changes eco ded 130 using EST-DNA-mic oa ays and flip-flop and dend ime cDNA 131 popula ion labeling echniques unde he same expe imen al con- 132 di ions (Pócsi e al., 2005). 133 2. Ma e ials and me hods 134 2.1. S ain, cul u e condi ions 135 Aspe gillus nidulans FGSC 26 (biA1, eA1) was used h oughou 136 his s udy and was a gi o S. Rosén (Uni e si y o Lund, Sweden). 137 Vege a i e mycelium was cul i a ed in minimal ni a e medium 138 and was exposed o 0.8 mmol l 1 MSB o 6 h as desc ibed be o e 139 by Pócsi e al. (2005). MSB- ea ed mycelia we e washed wi h 140 ice-cold phospha e-bu e ed saline (0.9% w/ NaCl in 0.1 mol l 1 141 phospha e bu e , pH 7.4) and dis illed wa e , and we e s o ed o- 142 zen a 20 °C in lysis bu e (20 mmol l 1 T is–HCl, pH 7.6, 143 10 mmol l 1 NaCl, 0.5 mmol l 1 deoxychola e) o p o eomics s ud- 144 ies. In DNA mic oa ay expe imen s, mycelial sample p epa a ion 145 and s o age we e pe o med as p e iously (Pócsi e al., 2005). 146 2.2. P o eomics s udies 147 In acellula soluble p o ein sample p epa a ion was ca ied ou 148 acco ding o Nandakuma and Ma en (2002) wi h some modifica- 149 ions. F ozen mycelia we e dis up ed wi h X-p ess (AB Biox, 150 Ge many), and he endogenous p o eases we e inac i a ed by 151 40 l lml 1 P o easeInhibi o Cock ail(Sigma–Ald ich).Thecelldeb- 152 issuspensionwas cen i uged (6000 g, 4 °C,10 min),and he supe - 153 na an was ea ed s epwise by 7 l lml 1 RNase/DNase/Mg mix 154 (0.25 mg ml 1 RNase, 0.5 mg ml 1 DNase, 50 mmol l 1 MgCl 2 ; 155 0°C; 5 min) and an equal olume o 20% TCA (0 °C; 30 min). P ecip- 156 i a ed p o eins we e sepa a ed by cen i uga ion (6000 g, 4 °C, 157 20 min), and he pelle s we e washed wice wi h ice-cold ace one 158 and we e ai -d ied a oom empe a u e. 159 In wo-dimensional polyac ylamide gel elec opho esis (2D- 160 PAGE), p o ein samples (p o ein con en s we e se o 300 l g, de e - 161 mined by he Non-In e e ing P o ein Assay Ki o Calbiochem) we e 162 applied on o 17 cm immobilized pH g adien (IPG) s ips (pH 5–8, 163 Bio-Rad) by passi e ehyd a ion o 12 h in a solu ion con aining 164 7 mol l 1 u ea, 2 mol l 1 hiou ea, 2% (w/ ) CHAPS, 50 mmol l 1 165 DTT and 0.5% ampholy e (Bio-Ly e 3/10 Ampholy e). Isoelec ic 166 ocusing(IEF)waspe o medinaP o eanIEFCell(Bio-Rad)applying 167 he ollowing ol agese ings:0–250 V o 20 min,250–10,000 V o 168 2.5 h and, in he final phase, 10,000 V o 8 h. The ea e , he IPG 169 s ips we e consecu i ely incuba ed in solu ions A and B o 170 20 mineach ime o educeandalkyla e hep o eins.Solu ionAcon- 171 ained 50 mmol l 1 T is/HCl, pH 8.8, 6 mol l 1 u ea, 30% ( / ) glyc- 172 e ol, 5% (w/ ) SDS and 2% (w/ ) DTT, when in solu ion B DTT was 173 eplaced by 6% (w/ ) iodoace amide. The second dimension o 2D- 174 PAGE was pe o med on 10–14% g adien SDS polyac ylamide gels 175 using he P o ean II xi Mul i-Cell (Bio-Rad). Gels we e s ained wi h 176 Ru henium II T is (Rabilloud e al., 2001; Lamanda e al., 2004) and 177 Coomassie B illian Blue. 178 Images o he 2D-PAGE gels we e gene a ed using a Ve saDoc 179 4000 imaging sys em (Bio-Rad), and he analysis o he 2D-images 180 was pe o med wi h he PDQues so wa e (Bio-Rad). P o ein sam- 181 ples coming om h ee independen expe imen s o each g ow h 182 condi ion we e analyzed in sepa a e 2D-PAGE uns, and he signi - 183 icances o he di e ences in he densi ome ic da a gained in MSB- 184 ea ed and con ol samples o indi idual p o eins we e es ima ed 185 by he S uden ’s - es . 186 P o ein spo s wi h significan ly highe op ical densi ies han 187 hei coun e pa s in ei he he s ess-exposed o he con ol cul- 188 u es we e cu om 2D-PAGE gels, diced, and hen we e insed wi h 189 25 mmol l 1 NH 4 HCO 3 {p epa ed in 50% ( / ) ace oni ile/wa e } o 190 emo e SDS and Coomassie B illian Blue. The p o eins in he spo s 191 we e diges ed wi h side-chain-p o ec ed po cine ypsin (P omega, 192 Madison, WI, USA; 25 mmol l 1 NH 4 HCO 3, 37 °C, 4 h), and he mass 193 spec ome ic analysis o he yp ic diges s was pe o med by on- 194 line LC/MSMS using a 3D ion ap (LCQ Flee , The mo Fishe Scien- 195 ific GmbH, B emen, Ge many) connec ed wi h a nanoHPLC sys em 196 (Mic oP o, Eldex, USA) and an au osample (Endu ance, Sunch om, 197 Ge many). Pep ide ac iona ions we e pe o med using a 3 l m 198 A lan is™ dcC 18 column (75 l m100 mm; Wa e s, Mil o d, MA, 199 USA), equilib a ed in 10% ( / ) aqueous solu ion o ace oni ile, 200 which con ained 0.1% o mic acid. A e sample injec ion, he 2T. Pusz ahelyi e al./Fungal Gene ics and Biology xxx (2010) xxx–xxx YFGBI 2267 No. o Pages 12, Model 5G 30 Augus 2010 Please ci e his a icle in p ess as: Pusz ahelyi, T., e al. Compa ison o ansc ip ional and ansla ional changes caused by long- e m menadione exposu e in Aspe gillus nidulans. Fungal Gene . Biol. (2010), doi:10.1016/j. gb.2010.08.006 201 concen a iono ace oni ile was inc eased o50%o e 40 min (0.1% 202 o mic acid, 300 nl min 1 flow a e). The mass spec ome e was 203 ope a ed in iple play mode: su ey scans we e ollowed by a 6- 204 Da-zoom scan and CID analysis on he mos abundan ion in he su - 205 ey. Singly cha ged ions we e excluded om he p ecu so selec- 206 ion; and dynamic exclusion was enabled. The MS/MS da a we e 207 p ocessed wi h Masco Dis ille ( e sion 2.1.1.0.) wi h peak picking 208 pa ame e s ecommended o ion ap da a. 209 The gene a ed peak-lis s we e submi ed o da abase sea ches 210 wi h Masco (in-house se e 2.2.04.) agains he Na ional Cen e 211 o Bio echnology In o ma ion (NCBI; www.ncbi.nlm.nih.go /) 212 non- edundan da abase ( elease 09-26-2007; 55,19,594 se- 213 quences). Sea ch pa ame e s we e se o 0.6 Da mass accu acy o 214 he p ecu so ion and 1.0 Da o he agmen ions. Only yp ic 215 clea ages we e conside ed and one missed clea age was pe mi ed. 216 Ca bamidome hyla ion o Cys- esidues was conside ed as fixed 217 modifica ion, while me hionine oxida ion, p o ein N-ace yla ion 218 andpy oglu amicacid o ma ion omN- e minalGln esidueswe e 219 ega ded as a iable modifica ions. The cu -o sco e, de e mined by 220 Masco using a 0.05significance h eshold(p60.05),was54.Tofind 221 he exac ORF ID codes and he unc ions o he p o eins, he se- 222 quences iden ified om he yp ic diges s we e analyzed wi h he 223 blas psea chp og amo Al schule al. (1997)in heAspe gillus Gen- 224 ome Da abase (www.b oad.mi .edu/). Whene e ‘‘hypo he ical p o- 225 eins” wi h no p edic ed unc ion we e iden ified, homology sea ch 226 was also ca ied ou ia ansla ed ORF que y e sus p o eins in NCBI 227 BLAST. Homology da a we e fil e ed acco ding o he 1E-40 expec a- 228 ion alue (E) cu o c i e ia. 229 Unless o he wise indica ed, p o eins wi h a leas ou iden i- 230 fied pep ides and wi h significan homologies equal o o abo e 231 he cu -o sco e 54, and/o wi h an a leas 20% p o ein sequence 232 co e age (Raman e al., 2005) a e p esen ed in his wo k. In he 233 high and low molecula mass anges, some p o eins wi h a leas 234 wo iden ified pep ides and lowe sequence co e age we e also ac- 235 cep ed. On he basis o Aspe gillus Genome Da abase (www.b oad.- 236 mi .edu/), heo e ical isoelec ic poin (pI) and molecula mass 237 (kDa) we e calcula ed o each p o ein wi h he Compu e pI/kDa 238 ool (Bjellq is e al., 1993, 1994; Gas eige e al., 2005;h p:// 239 ca.expasy.o g/ ools/pi_ ool.h ml). Biochemical pa hway in o ma- 240 ion was ex ac ed om he Kyo o Encyclopedia o Genes and Gen- 241 omes (KEGG; e sion 51.0; elease July 1, 2009; h p:// 242 www.genome.jp/;Kanehisa and Go o, 2000). The unc ional clus- 243 e ing o he p o eins was ca ied ou using he AmiGO Gene On ol- 244 ogy Da abase (h p://amigo.geneon ology.o g/cgi-bin/amigo/ 245 go.cgi; elease Augus 27, 2009; Ca bon e al., 2009). FUN genes 246 we e analyzed o pu a i e domains in he Conse ed Domain 247 Da abase o he NCBI (Ma chle -Baue e al., 2005;h p:// 248 www.ncbi.nlm.nih.go /si es/en ez?db=cdd). 249 2.3. Genomics s udie 250 Double p in ed EST-based DNA chips (3533 unique PCR-ampli- 251 fied p obes p in ed in 2 4073 spo s; Pócsi e al., 2005) we e used 252 o moni o changes in cDNA popula ions p epa ed om mRNA 253 pools isola ed om MSB-exposed and un ea ed con ol cul u es. 254 The ull desc ip ion o gene p obes including PCR p ime s, Okla- 255 homa S a e Uni e si y con ig IDs (OSU con ig IDs; PipeOnline 256 [h p://bioin o.oks a e.edu/pipeonline/]) and B oad Ins i u e (Cam- 257 b idge, MA, USA) ORF IDs (B oad Ins i u e Aspe gillus nidulans Da a- 258 base, h p://www.b oad.mi .edu/anno a ion/ ungi/aspe gillus/) a e 259 gi en a NCBI Gene Exp ession Omnibus (NCBI GEO; h p:// 260 www.ncbi.nlm.nih.go /geo/) on Pla o ms GPL1752 and GPL1756. 261 Fluo escence labeling o he cDNA popula ions was ca ied ou 262 ollowing he ‘‘flip-flop” p o ocol o Hedge e al. (2000), whe e 263 Cy5-dUTP and Cy3-dUTP a e inco po a ed in o he cDNAs du ing 264 he e e se- ansc ip ion o he mRNA pools ex ac ed om 265 s ess-exposed and con ol cul u es, espec i ely (‘‘flip”), o ice 266 e sa (‘‘flop”). A e hyb idizing he cDNA pools on o he mic o- 267 a ays (Hegde e al., 2000; Pócsi e al., 2005), gene exp ession le els 268 cha ac e ized by fluo escence in ensi ies we e ead wi h a GenePix 269 4000B mic oa ay scanne (Axon Ins umen s), and he in ensi y 270 a ios we e calcula ed wi h GenePix P o 3.0 so wa e (Pócsi e al., 271 2005). 272 De ec ed spo s wi h alse eadings we e fil e ed ou manually, 273 and da a poin s wi h backg ound mean +1 SD highe han he spo 274 in ensi y means o bo h dyes we e also dis ega ded (Pócsi e al., 275 2005). Following ha , he backg ound-co ec ed a ios and log 2 a- 276 ios (M) o spo in ensi ies we e calcula ed, and he M alues we e 277 subjec ed o LOESS- ype block-by-block no maliza ion (Leung and 278 Ca alie i, 2003) using SAS o Windows, e sion 8 (SAS Ins i u e 279 Inc., Ca y, NC, USA) so wa e. In u he da a p ocessing, no mal- 280 ized log 2 a ios (M 0 ) we e analyzed. Only gene p obes wi h M 0 al- 281 ues abo e o below he [+1; 1] M 0 h esholds alue (‘ wo old 282 ule’; Schena e al., 1996) we e conside ed o espond o MSB- ig- 283 ge ed oxida i e s ess. All DNA mic oa ay da a we e deposi ed in 284 NCBI GEO (h p://www.ncbi.nlm.nih.go /geo/index.cgi) on Pla - 285 o m GPL1752 in Folde GSE4713 (flip-flop da abase). 286 3. Resul s and discussion 287 3.1. mRNA and p o ein abundances in oxida i e s ess-exposed 288 A. nidulans 289 Compa ing p o ein concen a ions and mRNA exp ession le els 290 is a an ad anced le el in yeas esea ch bu lagging in filamen ous 291 ungi including he Aspe gillii (Kim e al., 2008). Yeas -based models 292 a e o p ima y impo ance when he easons o he poo co ela- 293 ions be ween mRNA and p o ein le els ypically ound in euka y- 294 o ic cells a e s udied and discussed (Gygi e al., 1999; de Nobel 295 e al., 2001; G eenbaum e al., 2003; Beye e al., 2004; B ockmann 296 e al., 2007; Schmid e al., 2007; Tulle e al., 2007; de G oo e al., 297 2007). The co ela ion depends on bo h he cellula localiza ion 298 and he physiological unc ion o he p o eins (G eenbaum e al., 299 2003; Beye e al., 2004; Schmid e al., 2007; de Godoy e al., 300 2008;Rossignole al.,2009),andisinfluencedbymanycomplex ac- 301 o s including ansla ional ac i i y (B ockmann e al., 2007), p o- 302 ein hal -li es (Beye e al., 2004; Belle e al., 2006) as well as 303 na u al and manu ac u ed sys ema ic noise (G eenbaum e al., 304 2003). I is impo an o no e ha da a gained by ORF (EST) based 305 DNA mic oa ays may be dis o ed o some ex en by c oss-hyb id- 306 iza ions(Iwahashie al.,2007),whichmay also influence he con o - 307 mi y o he p o eome and ansc ip ome da a. 308 Simila o gene al and specific s ess esponses, which a e well- 309 desc ibed a he le el o ansc ip ion, pos - ansc ip ional gene al 310 and specific s ess esponses also exis in yeas (B ockmann e al., 311 2007). Many s ess- esponsi e genes a e subjec ed o he pos - an- 312 sc ip ional egula ion mechanism ‘‘ ansla ion on demand” (Beye 313 e al., 2004; B ockmann e al., 2007), which is c ucially impo an 314 when adap ing o an en i onmen al s ess ha equi es a quick cel- 315 lula esponse (B ockmann e al., 2007). As a consequence, changes 316 in he exp ession o mRNA popula ions do no necessa ily co ela e 317 wi h he le els o he ansla ed p o eins and ice e sa (Beye e al., 318 2004; Kolkman e al., 2006; Tulle e al., 2007). In gene al, ansc ip- 319 ion ac o sandsignalinggenesa e egula edmainlypos - ansc ip- 320 ionally (B ockmann e al., 2007) while many elemen s o he 321 biosyn he ic pa hways a e con olled ansc ip ionally (B o e al., 322 2003; Washbu n e al., 2003; Rossignol e al., 2009). 323 Because he applicabili y o yeas -based models in he desc ip- 324 ion o Aspe gillus s ess esponse sys ems was limi ed (Miskei 325 e al., 2009) ou p ima y goal was o gain in o ma ion on he 326 co ela ion be ween p o ein and mRNA abundances in oxida i e 327 s ess-exposed A. nidulans cells. T. Pusz ahelyi e al./ Fungal Gene ics and Biology xxx (2010) xxx–xxx 3 YFGBI 2267 No. o Pages 12, Model 5G 30 Augus 2010 Please ci e his a icle in p ess as: Pusz ahelyi, T., e al. Compa ison o ansc ip ional and ansla ional changes caused by long- e m menadione exposu e in Aspe gillus nidulans. Fungal Gene . Biol. (2010), doi:10.1016/j. gb.2010.08.006 328 P o eome analysis o MSB-exposed (6 h) A. nidulans cul u es e- 329 ealed 82 s ess- ela ed in acellula p o eins unde going signifi- 330 can changes (Fig. 1;Supplemen a y 1). Ou o hose, 17 p o eins 331 we e de ec ed in mo e han one spo and fi e o hem we e iden- 332 ified in ep essed and induced o ms as well (Supplemen a y 1; 333 Table 1). A su ey o he li e a u e and he Aspe gillus S ess Da a- 334 base (h p://193.6.155.82/Aspe gillusS ess/;Miskei e al., 2009) 335 e ealed ha me ely 19 o he p o eins had been ela ed o any 336 kind o s ess esponse hus a (e.g. oxida i e, hea , osmo ic s ess, 337 un olded p o ein esponse; Supplemen a y 2). DNA mic oa ay 338 da abases gained wi h flip-flop ( his s udy) and dend ime (Pócsi 339 e al., 2005) cDNA labeling echniques p o ided us wi h ansc ip- 340 ion da a o he genes encoding 42 o he 82 iden ified s ess- e- 341 sponse p o eins (Supplemen a y 3). We ound bo h flip-flop and 342 dend ime mic oa ay da a o he g ea majo i y o hese genes 343 (38 o he 42), and he DNA chips used in hese s udies con ained 344 mo e han one di e en PCR-amplified p obes o 17 s ess- ela ed 345 genes (Supplemen a y 3). 346 When he co ela ion be ween ansc ip ome and p o eome 347 da ase s was examined, coincidence be ween p o ein le els and 348 gene exp essions was ound wi h 6 h MSB- ea ed p o eome (P) 349 and 6 h ea ed ansc ip ome samples. Coincidence le els wi h 350 flip-flop-labeled (F) and dend ime -labeled (D6) ansc ip ome 351 da ase s we e 40% and 34% (Fig. 2, Panels P–F and P-D6, II + RR), 352 espec i ely. These coincidence coe ficien s we e in good acco - 353 dance wi h p e ious obse a ions co ela ing mRNAs wi h p o ein 354 abundance (Tian e al., 2004; Nie e al., 2006; B ockmann e al., 355 2007). Poo coincidence coe ficien s (14–17%) we e ound compa - 356 ing 6 h MSB- ea ed p o eome and 0.5–3 h dend ime da a (Fig. 2, 357 Panels P-D0.5, P-D1 and P-D3, II + RR). This may be a consequence 358 o he ela i ely slowly accumula ing oxida i e s ess in MSB-ex- 359 posed A. nidulans cells (Pócsi e al., 2005). The con o mi y be ween 360 p o eome and ansc ip ome da a was 29% when p o eome was 361 compa ed o pooled dend ime da a (Fig. 2, Panel P-D0.5–6, 362 II + RR), and he lowes pe cen age (3%) o opposi e p o eome 363 and ansc ip ome changes was eco ded wi h 3 and 6 h ansc ip - 364 omes (Fig. 2, Panels P-D3 and P-D6, IR + RI). The pe cen age o p o- 365 eome changes no eflec ed in he a ia ions o he ansc ip ome 366 was highe in he dend ime -based DNA mic oa ay hyb idiza ions 367 (54–79%; Fig. 2, Panels P-D0.5, P-D1, P-D3 and P-D6, IO + RO) han 368 in he flip-flop-based DNA mic oa ay hyb idiza ion (33%, Fig. 2, 369 Panel P–F, IO + RO). 370 An al e na ing p o ein exp ession pa e n was obse ed o he 371 glycoly ic pa hway enzymes AcuG ( ep essed), FbaA (induced), 372 GpdA ( ep essed), PgkA (induced), EnoA ( ep essed), PkiA (in- 373 duced) a e 6 h MSB- ea men s (Fig. 3). As shown be o e by Pócsi 374 e al. (2005), he exp essions o he glycoly ic pa hway genes acuG, 375 baA,gpdA and pkiA we e fluc ua ing (pe iodically ep essed and 376 induced) as a unc ion o he MSB-exposu e ime (Supplemen a y 377 3,Fig. 4A). Theo e ically, an al e na ing p o ein exp ession pa e n 378 may a ise in a me abolic pa hway when ansc ip ional and ans- 379 la ional changes a e synch onous o he indi idual genes and gene 380 p oduc s bu he equencies o hese fluc ua ions a e ma kedly 381 di e en (Pócsi e al., 2005). A simila phenomenon has al eady 382 been obse ed unde li hium ea men s o budding yeas cells, 383 when e e y second gene, namely PGM2 (pgmB o holog), FBP1 384 (acuG o holog), TDH1 (gpdA o holog) and GPM2, PYK2 (pkiA o ho- 385 log), was up- egula ed in he glycoly ic pa hway (B o e al., 2003). 386 Anae obiosis also a ec ed gene exp essions and p o ein p oduc- 387 ions in qui e di e en ways in he glycoly ic pa hway o S. ce e i- 388 siae because mos o he gene exp essions emained unchanged 389 bu he quan i ies o a significan numbe o gene p oduc s in- 390 c eased conside ably (de G oo e al., 2007). 391 Opinions on he egula ion o glycoly ic p o eins a e dissen ing. 392 These p o eins may be unde ansc ip ional egula ion because 393 genes in he unc ional ca ego ies ‘‘me abolism,” ‘‘ene gy,” and 394 ‘‘p o ein syn hesis” exhibi he s onges co ela ion be ween 395 mRNA and p o ein le els in yeas s (Beye e al., 2004), and a mod- 396 e a e co ela ion be ween glycoly ic pa hway mRNA and p o ein 397 le els has been eco ded by Schmid e al. (2007). On he o he 398 hand, pos - ansc ip ional modula ions may also play an impo an 399 ole in he egula ion o he glycoly ic pa hway enzymes (de G oo 400 e al., 2007), and he specific ac i i ies o he me abolic enzymes 401 may also influence he obse ed p o ein le els (Schmid e al., 402 2007). Based on ou s udy, fluc ua ing mRNA and al e na ing p o- 403 ein exp ession le els sugges a ema kably flexible egula ion o 404 he glycoly ic pa hway enzymes in s ess-exposed A. nidulans. 405 I is wo h no ing ha gene exp ession fluc ua ions a e no lim- 406 i ed o glycoly ic pa hway genes as demons a ed by DNA mic o- 407 a ay expe imen s (Table 1;Supplemen a y 3;Pócsi e al., 2005), 408 No he n blo hyb idiza ions (Pócsi e al., 2005) and eal- ime e- 409 e se- ansc ip ion polyme ase chain eac ion assays (Supplemen- 410 a y 4), and such fluc ua ing gene exp ession pa e ns may also 411 explain, a leas in pa , he obse ed asynch ony o he ansc ip- 412 ome and p o eome da a (Fig. 2). 413 Ne e heless, o some genes and hei p o ein p oduc s an- 414 sc ip ional and ansla ional changes we e in good acco dance 415 (Supplemen a y 3), and he gene exp essions we e ei he consis- 416 en ly induced (e.g. genes encoding a pu a i e glu a hione S- ans- 417 e ase and a FUN p o ein o holog o A. umiga us AFUA_2G09530) 418 o ep essed (e.g. hsp70 and ungA;Table 1;Fig. 4B). S ess- e- 419 sponse genes wi h minimal a ia ions in hei mRNA exp ession 420 le els a e induc ion like Gs (Fig. 4B) we e egula ed mainly a 421 ansc ip ional le el and he p o ein concen a ions ended o be 422 less ‘‘noisy” in yeas (B ockmann e al., 2007). As a consequence, 423 mRNA le els co ela ed well wi h p o ein concen a ions in hese 424 cases (G eenbaum e al., 2003; Schmid e al., 2007). 425 3.2. S ess- esponsi e p o eins in MSB- ea ed A. nidulans 426 Analyzing he p o eins desc ibed wi h he GO e m ‘ esponse o 427 s ess’, he induced T xR hio edoxin educ ase, a fla ohemop o- 428 ein (ANID_07169.1) and a ni o educ ase (ANID_02343.1) e- 429 placed he ep essed pu a i e o holog o budding yeas ’s 430 mi ochond ial Ccp1 cy och ome C pe oxidase and he ep essed 431 pe oxi edoxins in he cen e o he oxida i e s ess de ense sys em 432 o MSB-exposed A. nidulans (Table 1;Fig. 3;Supplemen a y 2). The 433 appea ance o a fla ohemop o ein among he induced p o eins 434 may be indica i e o de eloping ni osa i e s ess in MSB- ea ed 435 A. nidulans mycelia simila o budding yeas cells (Table 1;Liu 436 e al., 2000; Te Biesebeke e al., 2009). In S. ce e isiae, bo h MSB 437 and H 2 O 2 ea men s ha e been shown o gene a e ni osa i e 438 s ess (Almeida e al., 2007; Oso io e al., 2007). 439 GSH is he cen e piece o he an ioxida i e de ense sys em in al- 440 mos all euka yo ic cells, including ungi. GSH is p esen in high 441 concen a ions in li ing cells, and is he majo ese oi o educed 442 non-p o ein sul u (Pócsi e al., 2004). In MSB-exposed A. nidulans 443 mycelium, he GSH concen a ion d ops and a numbe o GSH-bio- 444 syn he ic and GSH- egene a ing enzymes a e induced o main ain 445 a physiologically ele an GSH/GSSG balance (Pócsi e al., 2005). 446 The induc ion o isofla one educ ase is an indica o o he limi ed 447 a ailabili y o GSH in maize (Pe ucco e al., 1996) and, no su p is- 448 ingly, i s o holog (ANID_08815.1) was also induced in MSB- ea- 449 ed A. nidulans (Table 1), when he GSH/GSSG a io is 450 significan ly dec eased (Pócsi e al., 2005). Induced glu a hione-S- 451 ans e ases (Gs 3 and a pu a i e Gs ) we e also connec ed o he 452 oxida i e s ess esponse (Table 1) because hese enzymes a e e- 453 qui ed o p o ec euka yo ic cells om pe oxide-induced cell dea h 454 (Pócsi e al., 2005) and he dele e ious e ec s o menadione i sel 455 (Em i e al., 1999). 456 Unde long- e m, ch onic oxida i e s ess, glucose and ammo- 457 nia up ake a e educed in ungi (Em i e al., 1997; Oso io e al., 4T. Pusz ahelyi e al./ Fungal Gene ics and Biology xxx (2010) xxx–xxx YFGBI 2267 No. o Pages 12, Model 5G 30 Augus 2010 Please ci e his a icle in p ess as: Pusz ahelyi, T., e al. Compa ison o ansc ip ional and ansla ional changes caused by long- e m menadione exposu e in Aspe gillus nidulans. Fungal Gene . Biol. (2010), doi:10.1016/j. gb.2010.08.006 458 2004; Li e al., 2008a) and, he e o e, cells ha e o cope wi h glu- 459 cose and ni ogen sho ages as well, in addi ion o he neu aliza- 460 ion o ROS and he main enance o he GSH/GSSG and NADP + / 461 NADPH edox balances (Zadzinski e al., 1998; Pócsi e al., 2005; 462 Li e al., 2008b). The app op ia e s ess- esponsi e egula ion o 463 he ca bon and ni ogen me abolic pa hways is o ca dinal impo - 464 ance in he oxida i e s ess de ense o s ess-exposed cells. 465 In good ag eemen wi h his, a ious enzymes o ca bon me ab- 466 olism cha ac e ized wi h he main GO e ms ‘‘hexose me abolism” 467 (inco po a ing glycolysis, gluconeogenesis, pen ose phospha e 468 shun ), ‘‘TCA cycle”, ‘‘alcohol me abolism” as well as ‘‘ca boxylic 469 acid me abolism”, ‘‘manni ol me abolism” and ‘‘amino acid me ab- 470 olism” we e ound o be s ess- esponsi e (Table 1). In he glyco- 471 ly ic pa hway, he main ATP-p oduce PkiA py u a e kinase and 472 PgkA 3-phosphoglyce a e kinase we e induced oge he wi h FbaA 473 uc ose 1,6-bisphospha e aldolase (Table 1,Fig. 3). I is impo an 474 o no e ha Pgk1p 3-phosphoglyce a e kinase and Fba1p uc ose 475 1,6-bisphospha e aldolase we e also up- egula ed in menadione- 6704 6201 5301 6104 5102 7303 2304 8404 5502 7507 8605 6706 4003 4501 3611 8408 7104 2102 4403 5403 2406 4705 8702 6502 4001 8303 5504 7706 3305 2602 4803 4503 8701 1108 2104 2505 5711 6402 7003 5508 9201 8206 7508 6005 7004 8411 3206 1103 3401 pH5 pH8 B 4608 6703 7305 4406 6711 7304 4704 3711 6724 8325 3610 7510 2506 3618 1803 6806 3513 6515 5507 5401 6409 2703 4807 6208 4505 4802 3509 8208 1310 2612 5807 8309 1114 3403 7111 7205 2107 5202 6603 3209 5216 4509 pH5 pH8 A Fig. 1. 2D-PAGE sepa a ion and iden ifica ion o in acellula soluble s ess- esponsi e p o eins in MSB-exposed A. nidulans ege a i e cul u es. Pa s A and B ep esen uns essed con ol and MSB- ea ed A. nidulans FGSC 26 cul u es, espec i ely. Spo s wi h significan ly induced (Pa B) o ep essed (Pa A) p o eins a e localized wi h a ows and ma ked wi h spo ID (also lis ed in Supplemen a y 1). Only one o h ee independen uns is shown. T. Pusz ahelyi e al./ Fungal Gene ics and Biology xxx (2010) xxx–xxx 5 YFGBI 2267 No. o Pages 12, Model 5G 30 Augus 2010 Please ci e his a icle in p ess as: Pusz ahelyi, T., e al. Compa ison o ansc ip ional and ansla ional changes caused by long- e m menadione exposu e in Aspe gillus nidulans. Fungal Gene . Biol. (2010), doi:10.1016/j. gb.2010.08.006 Table 1 Oxida i e s ess- esponsi e p o eins in MSB-exposed Aspe gillus nidulans. Func ions a A. nidulans locus ID b P o eomics c Genomics c Flip- flop 6h Dend ime 0.5 h Dend ime 1h Dend ime 3h Dend ime 6h Dend ime 0.5–6 h Response o s ess 1-Cys pe oxi edoxin, pu a i e ANID_10223.1 R Pe oxi edoxin P xA ANID_08692.1 R cy och ome c pe oxidase Ccp1 ANID_10220.1 R Fla ohemop o ein ANID_07169.1 I I R R A A Ni o educ ase ANID_02343.1 I Thio edoxin educ ase T xR ANID_03581.1 I Glu a hione S- ans e ase Gs B ANID_06024.1 I I I 0 0 I I Glu a hione S- ans e ase Gs 3 ANID_10273.1 I 0 Hexose me abolism UDP-glucose-4-epime ase GalGb ANID_04727.1 R Phosphoglucomu ase PgmB ANID_02867.1 R R 0 0 F uc ose-1,6-bisphospha ase AcuG ANID_05604.1 R I I 0 I 0 I F uc ose 1,6-bisphospha e aldolase FbaA ANID_02875.1 I 0 0 0 0 0 0 Glyce aldehyde-3-phospha e dehyd ogenase GpdA ANID_08041.1 R I 0 0 0 0 0 3-Phosphoglyce a e kinase PgkA ANID_01246.1 I Enolase EnoA (AcuN) ANID_05746.1 R Py u a e kinase PkiA ANID_05210.1 I I 0 R I I A Glucose-6-phospha e 1-dehyd ogenase GsdA ANID_02981.1 I I 0 I 0 I Ribose 5-phospha e isome ase ANID_05907.1 I I 0 R 0 I A T anske olase ANID_09180.1 R T ansaldolase PppA ANID_00240.1 I R 0 R 0 R R T ica boxylic acid cycle Aconi ase AcoA ANID_05525.1 R 0 0 0 0 0 0 Hypo he ical p o ein simila o isoci a e dehyd ogenase subuni 2 IdpA ANID_01003.1 I 0 0 0 0 0 0 Mi ochond ial mala e dehyd ogenase MdhA ANID_06717.1 R Mala e dehyd ogenase, MdhC ANID_06499.1 R 0 0 0 0 0 0 Alcohol me abolism Aldehyde dehyd ogenase AldA ANID_00554.1 R 0 I R 0 0 A Zinc-con aining alcohol dehyd ogenase ANID_02351.1 I Alcohol dehyd ogenase ANID_08406.1 I Ca boxylic acid me abolism Py u a e deca boxylase PdcA ANID_04888.1 R A 0 R 0 R R NAD-dependen o ma e dehyd ogenase AciA ANID_06525.1 R 0 0 0 R R Manni ol me abolism Manni ol 2-dehyd ogenase ANID_07590.1 I I R 0 0 0 R Cellula amino acid me abolism A gininosuccina e syn he ase ANID_01883.1 R Fuma ylace oace a e hyd olase FahA ANID_01896.1 R Alanine ansaminase ANID_01923.1 A L -o ni hine amino ans e ase O aA ANID_01810.1 I R O ni hine ca bamoyl ans e ase A gB ANID_04409.1 R I 0 0 0 0 Dihyd oxy-acid dehyd a ase ANID_06346.1 I Cys a hionine be a-syn hase MecA ANID_05820.1 I 3-Phosphose ine amino ans e ase ANID_10298.1 R NADP-specific glu ama e dehyd ogenase GdhA ANID_04376.1 A Glu amine syn he ase GlnA ANID_04159.1 R I R 0 0 R Choline oxidase (CodA), pu a i e ANID_01429.1 I Phospha idyl syn hase [Aspe gillus umiga us A 293] NCBI ANID_05564.1 I I 0 I I 0 I Glucose–me hanol–choline oxido educ ase ANID_08547.1 R Cellula lipid me abolism Myo-inosi ol-1-phospha e syn hase ANID_07625.1 I I R 0 0 0 A Ace yl-CoA ace yl ans e ase, pu a i e ANID_01409.1 R Ribofla in biosyn hesis 6,7-Dime hyl-8- ibi yl-lumazine syn hase RiboG ANID_10718.1 R R R 0 0 R R GTP cyclohyd olase II ANID_10981.1 R R Cy oskele on o ganiza ion Hypo he ical p o ein simila o fimb in FimA ANID_05803.1 I 0 0 0 0 0 0 Chi in biosyn hesis UDP-N-ace ylglucosamine py ophospho ylase UngA ANID_09094.1 R 0 R 0 0 R R Nucleo ide sal age Adenine phospho ibosyl ans e ase 1 ANID_09083.1 R Gene a ion o p ecu so me aboli es and ene gy Ubiquinol–cy och ome c educ ase i on–sul u subuni ANID_02306.1 I Ino ganic py ophospha ase IppA ANID_02968.1 R 6T. Pusz ahelyi e al./ Fungal Gene ics and Biology xxx (2010) xxx–xxx YFGBI 2267 No. o Pages 12, Model 5G 30 Augus 2010 Please ci e his a icle in p ess as: Pusz ahelyi, T., e al. Compa ison o ansc ip ional and ansla ional changes caused by long- e m menadione exposu e in Aspe gillus nidulans. Fungal Gene . Biol. (2010), doi:10.1016/j. gb.2010.08.006 476 exposed S. ce e isiae cells (Kim e al., 2007a). As demons a ed by 477 Pócsi e al. (2005), he exp ession o some genes encoding glyco- 478 ly ic enzymes was esponsi e o GSH/GSSG edox imbalance, e.g. 479 FbaA was ep essed conside ably, and his migh esul in he 480 in acellula accumula ion o uc ose-1,6-bisphospha e, a mi o- 481 chond ion-p o ec an me aboli e (Pócsi e al., 2005). The p o eome 482 da a challenged his hypo hesis because FbaA was clea ly induced 483 in MSB-exposed cul u es (Table 1). 484 In he Aspe gillus S ess Da abase (Miskei e al., 2009), GsdA 485 glucose-6-phospha e 1-dehyd ogenase, AcuG uc ose-1,6-bis- 486 phospha ase and GalGb UDP-glucose-4-epime ase om hexose 487 me abolic enzymes a e indica ed as s ess- ela ed p o eins (Sup- 488 plemen a y 2). Mo eo e , some da a published ea lie on GpdA 489 glyce aldehyde-3-phospha e dehyd ogenase, EnoA enolase and 490 hei yeas o hologs unde lined he impo ance o hese enzymes 491 in e sa ile s ess esponses. Fo example, ungal glyce aldehyde- 492 3-phospha e dehyd ogenases we e epo ed o pa icipa e in 493 osmoadap a ion (Kim e al., 2007b), in ci ic acid s ess (Law ence 494 e al., 2004), as well as in he esponse o concanamycin (Melin 495 e al., 2002) o ampho e icin B (Yu e al., 2007) ea men s, and 496 enolases a e also well-known pa icipan s in a ious s ess e- 497 sponses (Hu e al., 2003; Re e e -B ancha e al., 2004; En elis 498 e al., 2006; Kwon e al., 2009; Pandey e al., 2009). GAPDH, he 499 budding yeas o holog o GpdA, was a a ge o ex ensi e p o eol- 500 ysis unde ex ended (200 min) H 2 O 2 ea men , unde wen S-ni - 501 osyla ion and en e ed o he nucleus whe e i induced apop osis 502 (Almeida e al., 2007). 503 A sa is ac o y NADPH p oduc ion is o pi o al impo ance in he 504 main enance o he GSH, glu a edoxin and hio edoxin-dependen 505 elemen s o he an ioxidan de ense sys em (Juhnke e al., 1996). In 506 compliance wi h he NADPH equi emen o he s ess-exposed 507 cells, he main NADPH-p oduce enzymes GsdA and isoci a e 508 dehyd ogenase we e induced. 509 As a as he ni ogen me abolism is conside ed, wo key en- 510 zymes o ‘‘cellula amino acid me abolism” we e also iden ified; 511 GdhA NADP-specific glu ama e dehyd ogenase was ound in h ee Table 1 (con inued) Func ions a A. nidulans locus ID b P o eomics c Genomics c Flip- flop 6h Dend ime 0.5 h Dend ime 1h Dend ime 3h Dend ime 6h Dend ime 0.5–6 h Signal ansduc ion G-p o ein complex be a subuni CpcB ANID_04163.1 A 0 R I 0 0 A T ansla ion Hypo he ical p o ein simila o elonga ion ac o EF-Tu ANID_01084.1 I Elonga ion ac o 2 ANID_06330.1 R T ansla ion elonga ion ac o eEF-1B gamma subuni El A ANID_09304.1 I His idyl– RNA syn he ase ANID_00046.1 I I 0 0 R R Aspa yl– RNA syn he ase Dps1 ANID_04550.1 R R 0 I R A P o oplas sec e ed p o ein 2 [Aspe gillus e eus NIH2624]NCBI ANID_00297.1 I RNA binding p o ein [Aspe gillus umiga us A 293] NCBI ANID_05480.1 I I I 0 I I I P o ein olding, in acellula anspo Pep idyl–p olyl cis– ans isome ase D Cp 6 ANID_04583.1 R 0 0 0 Hsp70 ANID_05129.1 R R R 0 0 R R GTP-binding nuclea p o ein ANID_05482.1 R I 0 0 0 0 0 P o ein ca abolism Hypo he ical p o ein simila o p o easome egula o y subuni 8 ANID_05121.1 I P o easome componen P e6 ANID_08054.1 I Unknown biological p ocess Oxido educ ase ANID_00179.1 A Oxido educ ase, hypo he ical ANID_00895.1 A R 0 0 I R A Zinc-binding oxido educ ase ANID_10098.1 I NADH:fla in oxido educ ase/NADH oxidase ANID_05228.1 I NADH-dependen fla in oxido educ ase ANID_06753.1 I Zinc-binding oxido educ ase ToxD ANID_11094.1 I NAD binding Rossmann old oxido educ ase ANID_02208.1 I Isofla one educ ase amily p o ein [Aspe gillus umiga us A 293] NCBI ANID_08815.1 I I 0 0 0 I I Be a-lac amase amily p o ein ANID_05422.1 R R 0 0 0 0 0 Conse ed hypo he ical p o ein wi h homology o me hyl ans e ase [Ajellomyces de ma i idis ER-3] NCBI ANID_02561.1 I NAD dependen epime ase/dehyd a ase ANID_05989.1 R FUN p o eins FUN; e a icopep ide epea domain-con aining p o ein ANID_03987.1 I FUN; UPF0160 domain-con aining p o ein MYG1 ANID_04178.1 R FUN; DUF833 domain-con aining p o ein ANID_06058.1 I 0 0 I I I I FUN; DUF636 domain-con aining p o ein ANID_07594.1 I 0 0 0 FUN ANID_10219.1 I 0 0 0 0 0 0 FUN ANID_10260.1 I 0 R 0 0 R a Pu a i e o e ified physiological unc ions o he s ess- esponse p o eins iden ified in he p o eomics s udies. Physiological unc ions we e ex ac ed om he Aspe gillus Compa a i e Da abase (h p://www.b oadins i u e.o g/anno a ion/genome/aspe gillus_g oup/Mul iHome.h ml), he Cen al Aspe gillus Da a REposi o y CADRE (Mabey e al., 2004;h p://www.cad e-genomes.o g.uk/), he Aspe gillus Genome Da abase (h p://www.aspe gillusgenome.o g/), he Gene On ology Da abase (h p://amigo.geneon olo- gy.o g/cgi-bin/amigo/go.cgi) and he Saccha omyces Genome Da abase (SGD, h p://www.yeas genome.o g/). b A. nidulans locus ID om he Aspe gillus Compa a i e Da abase (h p://www.b oadins i u e.o g/anno a ion/genome/aspe gillus_g oup/Mul iHome.h ml). c Le e s I, R, 0 and A s and o ‘‘significan ly induced”, ‘‘significan ly ep essed”, ‘‘no significan induc ion o ep ession” and ‘‘ambi alen change”, espec i ely. Fo u he explana ion o he A ‘‘ambi alen change” ca ego y in ei he he genomics o he p o eomics s udies, see he cap ion o Fig. 2. A summa y o he changes in he gene exp ession le els can be ead in Supplemen a y 3. T. Pusz ahelyi e al./ Fungal Gene ics and Biology xxx (2010) xxx–xxx 7 YFGBI 2267 No. o Pages 12, Model 5G 30 Augus 2010 Please ci e his a icle in p ess as: Pusz ahelyi, T., e al. Compa ison o ansc ip ional and ansla ional changes caused by long- e m menadione exposu e in Aspe gillus nidulans. Fungal Gene . Biol. (2010), doi:10.1016/j. gb.2010.08.006 512 spo s, and he enzyme was induced in wo o hem unde MSB- 513 s ess meanwhile GlnA glu amine syn he ase was ep essed (Table 514 1;Fig. 3;Supplemen a y 2). The pos - ansc ip ional egula ion o 515 budding yeas ’s GDH1 (o holog o GdhA) was obse ed by se e al 516 au ho s (Dang e al., 1996; DeLuna e al., 2001; G i fin e al., 2002; 517 Riego e al., 2002; Kolkman e al., 2006), and he appea ance o 518 mul iple GdhA spo s (bo h induced and ep essed) on he 2D-PAGE 519 gels is in good ag eemen wi h hese obse a ions. Impo an ly, he 520 ansc ip ion o GdhA was ep essed by glucose, induced by ni o- 521 gen limi a ion (Kolkman e al., 2006) and up- egula ed unde hyp- Fig. 2. Compa ison o p o ein and mRNA le els in MSB-exposed A. nidulans. The compa ison was accomplished on s ess- esponse p o eins (P; Table 1) and gene exp ession da abases ob ained wi h dend ime (D) and flip-flop (F) labeling DNA mic oa ay echnology (Supplemen a y 3;Pócsi e al., 2005). D0.5, D1, D3 and D6 s and o mic oa ay da a eco ded unde 0.5, 1, 3 and 6 h exposu es o MSB (Supplemen a y 3;Pócsi e al., 2005). D0.5–6 symbolizes a unified da ase o he 0.5–6 h dend ime DNA mic oa ay expe imen s. Ma ks I, R, 0 and A s and o ‘‘significan ly induced”, ‘‘significan ly ep essed”, ‘‘no significan induc ion o ep ession” and ‘‘ambi alen change”, espec i ely. The ‘‘ambi alen change” g oup included genes wi h ambiguous o e en opposi e ansc ip ional changes eco ded on di e en PCR-amplified gene p obes a he same MSB- exposu e ime o wi h opposi e ansc ip ional changes eco ded on he same gene p obe a di e en MSB-exposu e imes. In p o eomic expe imen s, he ‘‘ambi alen change” g oup included s ess- ela ed p o eins wi h opposi e changes in hei quan i ies eco ded in sepa a e p o ein spo s. 8T. Pusz ahelyi e al./ Fungal Gene ics and Biology xxx (2010) xxx–xxx YFGBI 2267 No. o Pages 12, Model 5G 30 Augus 2010 Please ci e his a icle in p ess as: Pusz ahelyi, T., e al. Compa ison o ansc ip ional and ansla ional changes caused by long- e m menadione exposu e in Aspe gillus nidulans. Fungal Gene . Biol. (2010), doi:10.1016/j. gb.2010.08.006 522 oxic condi ions (Shimizu e al., 2009). Changes in he S. ce e isiae 523 GLN1 glu amine syn he ase (o holog o GlnA) ansc ip and p o- 524 ein le els showed poo co ela ions in la ge-scale s udies (G i fin 525 e al., 2002; Washbu n e al., 2003), and opposi e ansc ip ional 526 changes we e also obse ed by us o GlnA in flip-flop (induc ion) 527 and dend ime ( ep ession) DNA mic oa ay expe imen s while 528 he p o ein le el was significan ly dec eased (Table 1). 529 The sul u con aining amino acid biosyn he ic pa hways we e 530 ep esen ed solely by MecA cys a hionine b-syn hase among he 531 s ess-induced p o eins (Table 1;Supplemen a y 2). MecA ca a- 532 lyzes he homocys eine/cys a hionine con e sion and, hence, plays 533 an impo an ole in he biosyn hesis o cys eine, one o he h ee 534 amino acids building up GSH (Pócsi e al., 2004). Cys eine can also 535 be syn hesized in an al e na i e pa hway, which includes cys eine 536 syn hase (cysB, ANID_08057.1) and cysB was up- egula ed unde 537 he MSB- ea men s (Pócsi e al., 2005). The e o e, bo h cys eine 538 biosyn he ic pa hways may ope a e in oxida i e s ess-exposed 539 A. nidulans hyphae. I is impo an o no e ha he cys a hionine 540 pa hway as well as GSH p oduc ion we e highly induced unde 541 cadmium s ess in yeas (Vido e al., 2001; Mendoza-Cóza l e al., 542 2005; Baudouin-Co nu and Laba e, 2006) and in Blas ocladiella 543 eme sonii (Geo g and Gomes, 2007). In he la e species, only he 544 cys a hionine pa hway ope a es. 545 Two enzymes in he u ea cycle, A gB o ni hine ca bamoyl ans- 546 e ase and a ginosuccina e syn he ase, we e ep essed in he 547 o ni hine–ci ulline- L -a ginosuccina e biocon e sion pa hway, 548 howe e , O aA L -o ni hine amino ans e ase was induced, and his 549 may esul in he accumula ion o o ni hine and a subsequen in- 550 c ease in he glu ama e biosyn hesis. Because he TCA cycle was 551 ep essed a mala e dehyd ogenase and AcoA aconi ase (Table 1; 552 Fig. 3), he glu ama e equi emen o he GSH biosyn hesis may 553 be me by he O aA pa hway. 554 Ace yl-CoA C-ace yl ans e ase (ANID_01409.1), which is classi- 555 fied unde he GO e m ‘‘ a y acid me abolism” bu can be linked 556 o a ious me abolic pa hways including he syn hesis and deg a- 557 da ion o ke on bodies, aline, leucine, isoleucine, he deg ada ion 558 o lysine, he me abolisms o py u a e and yp ophan, was e- 559 p essed. Myo-inosi ol-1-phospha e syn hase in he biosyn hesis 560 o inosi ol phospholipids (Reynolds, 2009) and CodA, a pu a i e 561 choline oxidase in he biosyn hesis o he osmop o ec an glycine 562 be aine (Pa k and Gande , 1998; Bu g and Fe ais, 2008) we e in- 563 duced oge he wi h a phospha idyl syn hase (ANID_05564.1). 564 Unexpec ed da a we e ob ained on biosyn heses o i amins be- 565 cause wo enzymes, RiboG 6,7-dime hyl-8- ibi yl-lumazine syn- 566 hase and GTP cyclohyd olase II, bo h in he ibofla in ( i amin 567 B2) biosyn he ic pa hway, we e s ongly ep essed oge he wi h 568 3-phosphose ine amino ans e ase, which is linked o he syn he- 569 ses o glycine, se ine and h eonine bu also plays a ole in he bio- 570 syn hesis o py idoxine ( i amin B6). Ribofla in p o ec s cells om 571 oxida i e inju ies (Sugiyama, 1991; Pe umal e al., 2005), and MSB- Fig. 3. Me abolic unc ion and schema ic cellula localiza ion o MSB-s ess- esponsi e A. nidulans p o eins. P o eins wi h pu a i e unc ions a e summa ized in Table 1 and a e labeled he e wi h hei locus IDs. Symbols s,d,hand jindica e inc eased p o ein, dec eased p o ein, inc eased mRNA and dec eased mRNA le els, espec i ely (Table 1; Supplemen a y 3;Pócsi e al., 2005). Ques ion ma ks e e o ‘ambi alen ’ changes in p o ein le els (Table 1;Fig. 2). Dashed lines indica e mul i-s ep me abolic pa hways. Please no e he ema kably al e na ing p o ein induc ion and ep ession pa e n obse able in he glycoly ic me abolic pa hway be ween he AcuG and PkiA enzymes. T. Pusz ahelyi e al./ Fungal Gene ics and Biology xxx (2010) xxx–xxx 9 YFGBI 2267 No. o Pages 12, Model 5G 30 Augus 2010 Please ci e his a icle in p ess as: Pusz ahelyi, T., e al. Compa ison o ansc ip ional and ansla ional changes caused by long- e m menadione exposu e in Aspe gillus nidulans. Fungal Gene . Biol. (2010), doi:10.1016/j. gb.2010.08.006