Towards 14C-free liquid scintillator

This is an electronic reprint of the original article. This reprint may differ from the original in pagination and typographic detail. Author(s): Title: Year: Version: Please cite the original version: All material supplied via JYX is protected by copyright and other intellectual property rights, and duplication or sale of all or part of any of the repository collections is not permitted, except that material may be duplicated by you for your research use or educational purposes in electronic or print form. You must obtain permission for any other use. Electronic or print copies may not be offered, whether for sale or otherwise to anyone who is not an authorised user. Towards 14C-free liquid scintillator Enqvist, T.; Barabanov, I. R.; Bezrukov, L. B.; Gangapshev, A. M.; Gavrilyuk, Y. M.; Grishina, V. Yu.; Gurentsov, V. I.; Hissa, J.; Joutsenvaara, J.; Kazalov, V. V.; Krokhaleva, S.; Kutuniva, J.; Kuusiniemi, P.; Kuzminov, V. V.; Kurlovich, A. S.; Loo, Kai; Lubsandorzhiev, B. K.; Lubsandorzhiev, S.; Morgalyuk, V. P.; Novikova, G. Y.; Pshukov, A. M.; Sinev, V. V.; Slupecki, Maciej; Trzaska, Wladyslaw; Umerov, Sh. I.; Veresnikova, A. V.; Virkaj arvi, A.; Yanovich, Y. A.; Zavarzina, V. P. Enqvist, T., Barabanov, I. R., Bezrukov, L. B., Gangapshev, A. M., Gavrilyuk, Y. M., Grishina, V. Y., Gurentsov, V. I., Hissa, J., Joutsenvaara, J., Kazalov, V.V., Krokhaleva, S., Kutuniva, J., Kuusiniemi, P., Kuzminov, V.V., Kurlovich, A. S., Loo, K., Lubsandorzhiev, B. K., Lubsandorzhiev, S., Morgalyuk, V. P., . . . Zavarzina, V. P. (2017). Towards 14C-free liquid scintillator. In Neutrino 2016 : XXVII International Conference on Neutrino Physics and Astrophysics (Article 012098). Institute of Physics Publishing. Journal of Physics: Conference Series, 888. https://doi.org/10.1088/1742-6596/888/1/012098 2017 Journal of Physics: Conference Series PAPER • OPEN ACCESS Towards 14C-free liquid scintillator To cite this article: T Enqvist et al 2017 J. Phys.: Conf. Ser. 888 012098 View the article online for updates and enhancements. Related content Measurement of the liquid scintillator nonlinear energy response to electron Zhang Fei-Hong, Yu Bo-Xiang, Hu Wei et al. - Solar neutrino experiments M C Chen - Aging of LAB-based liquid scintillator in stainless steel containers Chen Hai-Tao, Yu Bo-Xiang, Shan Qing et al. - This content was downloaded from IP address 130.234.74.150 on 10/11/2017 at 13:34 1 Content from this work may be used under the terms of theCreativeCommonsAttribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. Published under licence by IOP Publishing Ltd 1234567890 Neutrino2016 IOP Publishing IOP Conf. Series: Journal of Physics: Conf. Series 888 (2017) 012098 doi :10.1088/1742-6596/888/1/012098 Towards 14C-free liquid scintillator T Enqvist1, I R Barabanov2, L B Bezrukov2, A M Gangapshev2, Y M Gavrilyuk2, V Yu Grishina2,VIGurentsov 2, J Hissa1, J Joutsenvaara1,VVKazalov 2, S Krokhaleva2, J Kutuniva1, P Kuusiniemi1,VVKuzminov 2, A S Kurlovich2,KLoo 3, B K Lubsandorzhiev2, S Lubsandorzhiev2, V P Morgalyuk2, GYNovikova 2,AMPshukov 2,VVSinev 2,MSlupecki3, WHTrzaska 3,ShIUmerov 2,AVVeresnikova 2, A Virkaj¨arvi1, Y A Yanovich2,VPZavarzina 2 1Oulu Southern Institute and Astronomy Research Unit, University of Oulu, Finland 2Institute for Nuclear Research, Russian Academy of Sciences, Moscow, Russia 3Department of Physics, University of Jyv¨askyl¨a, Finland E-mail: [email protected] Abstract. A series of measurements has been started where the 14C concentration is determined from several liquid scintillator samples. A dedicated setup has been designed and constructed with the aim of measuring concentrations smaller than 10−18. Measurements take place in two underground laboratories: in the Baksan Neutrino Observatory, Russia, and in the new Callio Lab in the Pyh¨asalmi mine, Finland. Low-energy neutrino detection with a liquid scintillator requires that the intrinsic 14C concentration in the liquid is extremely low. In the Borexino CTF detector the concentration of 2 ×10−18 has been achieved being the lowest value ever measured. In principle, the older the oil or gas source that the liquid scintillator is derived from and the deeper it situates, the smaller the 14C concentration is supposed to be. This, however, is not generally the case and the concentration is probably due to the U and Th content of the local environment. 1. Introduction The intrinsic 14C concentration in a liquid is the main source of background at very low energies in high-purity liquid scintillation detectors. Previously measured concentration values are shown in Tab. 1 for scintillators based on PC (Pseudocumene; C9H12), PXE (Phenylxylylethane; C16H18) and Dodecane (C12H26). There are no published data for the 14C concentration in the LAB (Linear alkylbenzene; C6H5CnH2n+1,n=10–16) being currently the most favourable liquid scintillator in large-volume detectors (e.g. SNO+ and JUNO). The β-decay end-point energy of 14C is quite low, Q=156 keV, and the counting rate may be often lowered by setting the appropriate threshold energy. However, too high concentration of 14C in the liquid may results in pile-ups of pulses. For example, in the Borexino detector at Gran Sasso, Italy, the trigger rate is largely dominated by the 14C isotope [5] (with the concentration of 2 ×10−18). 2 1234567890 Neutrino2016 IOP Publishing IOP Conf. Series: Journal of Physics: Conf. Series 888 (2017) 012098 doi :10.1088/1742-6596/888/1/012098 Table 1. Results of previous 14C concentration measurements in some liquid scintillators (CTF = Counting Test Facility). 14C concentration (×10−18) Liquid scintillator & fluor Experiment Ref. 1.94 ±0.09 PC + PPO Borexino CTF [1] 9.1 ±0.4 PXE + p-Tp + bis-MSB Borexino CTF [2] 3.98 ±0.94 PC-Dodecane + PPO KamLAND [3] 12.6 ±0.4 PXE + PPO Dedicated setup [4] Based on the analysis of the 14C concentration in liquid scintillators derived from deep oil and gas fields [6], values lower than 10−18 should be achievable if the source is carefully chosen. The contamination from the reaction 14N(n,p)14Cisexpectedtobethemainsourceof14Calso deep underground but now neutrons are emitted by the decay chains of U and Th isotopes. A campaign has been started to measure the 14C concentration in several liquid scintillator samples (based on oil, gas and coal derivatives of different locations) with the aim of finding out concentrations smaller than 10−18. Measurements are being carried out simultaneously, with essentially similar instruments and rock overburden, in two deep underground laboratories: in the Baksan Neutrino Observatory, Russia [7] and in the new Callio Lab laboratory in the Pyh¨asalmi Mine, Finland [8] at the depth over 4100 m.w.e. 2. Experimental details In order to study the 14C concentration in liquid scintillators at the level lower than approximately 10−15, being currently the lower limit achieved by Accelerator Mass Spectrometry (AMS) method [9], a dedicated experimental setup is required. The central part of the detector setup of the present work consists of two low-activity PMTs (3” ET 9302B), two acryllic light guides and a quartz (or acryllic) vessel of 1.6 litres. The vessel and light guides are wrapped with VM2000 reflecting foil. The shielding against γand neutron background is complemented using thick layers (10–15 cm) of copper and lead around the central part. Paraffin layer (approximately 10 cm, as the outer layer) may also be used to thermalize neutrons from the rock. The central part of the setup is planned to be flushed with nitrogen to reduce the background from radon. The DAQ is realized with the DRS4 evaluation board (V5) [10] based on the DRS4 Switched Capacitor Array chip designed at the Paul Scherrer Institute, Villigen, Switzerland. The two PMTs are directly connected to the inputs of the DRS4 board which is connected to the DAQ Laptop via an USB connector. The DRS4 samples the pulse in 1024 bins of the width of 0.2 ns with the maximum sampling speed of 5 GS per second. A 2-channel high-voltage module NHQ 203M of Iseg Spezialelektronik GmbH is used to power the PMTs. 3. Measurements The liquid scintillator samples are purified using Al2O3column and then mixed with ∼3g/of PPO and bubbled with nitrogen to remove oxygen. The purification is currently performed in the room atmosphere. A special purification system where the full process could be performed in a nitrogen atmosphere is in the design phase. The energy calibration is performed with several γ-ray sources using the position of their Compton edges or the full absorption peak at low energies (around 100 keV). Sources currently in use include 57Co, 109Cd, 133Ba, 137Cs and 241Am. Essentially linear calibration curves are expected. 3 1234567890 Neutrino2016 IOP Publishing IOP Conf. Series: Journal of Physics: Conf. Series 888 (2017) 012098 doi :10.1088/1742-6596/888/1/012098 Figure 1. Calibration spectra of one of the ET9302B 3-inch PMTs. The spectra are obtained with voltages of 1100 V (black), 1150 V (red) and 1175 V (blue). The voltage 1150 V results in a gain of 107. The calibration of 3-inch ET9302B photomultiplier tubes has been carried out in a black box with a led light source. An example with three different high-voltage values for one of the tubes is shown in Fig. 1. In the data processing the digitized waveforms are analyzed and the signal shapes are used to reduce αand neutron induced backgrounds. 4. Results There are no final experimental results available yet from Baksan or Pyh¨asalmi measurements for any sample. However, as a preliminary result, a concentration value close to 10−17 has been obtained in the first measurement of a LAB samples of Russian origin. 5. Summary A series of measurements have been started to determine the concentration of 14C in several liquid scintillator samples. The measurements are carried out in two deep underground laboratories: in Baksan, Russia, and in Pyh¨asalmi, Finland. A preliminary result from the first measurement of a sample of Russian origin for the 14C concentration is close to 10−17. References [1] Alimonti G et al., 1989 Phys. Lett. B422 349–58 [2] Back H O et al., 2008 Nucl. Instrum. Methods A585 48–60 [3] Keefer G, 2011 arXiv:1102.23876v1 [physics.ins-det] 18 Feb 2011 [4] Buck C et al., 2012 Instruments and Experimental Techniques 55 34–37 [5] Bellini G et al., 2014 Phys. Rev. D89 112007 [6] Bonvicini G, Harris N and Paolone V, 2003 arXiv:hep-ex/0308025v2 8 Aug 2003 [7] Gavriljuk Ju M et al., 2013 Nucl. Instrum. Methods A729 576–580 [8] Jalas P et al., 2016 Neutrino 2016 Conference, London [9] Fahmi S M, Wacker L, Synal H-A and Szidat S, 2013 Nucl. Instrum. Methods B294 302–327 [10] http://www.psi.ch/drs/documentation