Unveiling the role of the lone electron pair in sesquioxides at high pressure: compressibility of beta-Sb2O3 dagger

Sans, Juan Ángel; Manjón, F. J.; Pereira, André Luis de Jesús; Ruiz-Fuertes, J.; Popescu, Catalina; Muñoz, Alfonso; Rodríguez-Hernández, P.; Pellicer-Porres, J.; Cuenca-Gotor, V. P.; Contreras-García, Julia; Ibáñez Insa, Jordi; Monteseguro, V.

doi:http://dx.doi.org/10.13039/501100000780

Unveiling the role of the lone electron pair in sesquioxides at high pressure: compressibility of beta-Sb2O3 dagger

Sans, Juan Ángel,Manjón, F. J.,Pereira, André Luis de Jesús,Ruiz-Fuertes, J.,Popescu, Catalina,Muñoz, Alfonso,Rodríguez-Hernández, P.,Pellicer-Porres, J.,Cuenca-Gotor, V. P.,Contreras-García, Julia,Ibáñez Insa, Jordi,Monteseguro, V.

Publisher: Royal Society of Chemistry (UK)
DOI: http://dx.doi.org/10.13039/501100000780
Repository: digital.csic.es
Language: en

Abstract

This research was partially supported by the MINECO (FIS2017-83295-P, MAT2016-75586-C4-1/2/3-P, PGC2018- 097520-A-100, RED and PID2019-106383GB-41/42/43), by the MALTA-CONSOLIDER TEAM network (RED2018-102612-T) and by the EU-FEDER. JAS acknowledges the Ramon y Cajal fellowship (RYC-2015-17482) for financial support. VM thanks the Juan de la Cierva Program (FJCI-2016-27291) and Beatriz Galindo Fellowship (BG20/00077) for financial support. We also thank the ALBA (2016091901 experiment) and DIAMOND light source (CY22223 experiment) for providing beamtime, and Mark Warren, Sarah Barnett and Dominik Daisenberger for their help in the single-crystal X-ray diffraction experiment under pressure.

Full text

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